
(a)
Interpretation:
The product expected when
Concept introduction:
Alcohols undergo nucleophilic substitution reaction in the presence of halogen acids. The hydroxide group leaves after protonation and halogen group comes in via

Answer to Problem 10.40AP
The product obtained on the reaction of
Explanation of Solution
The product obtained on the reaction of
Figure 1
The
The product obtained on the reaction of
(b)
Interpretation:
The product expected when
Concept introduction:
Primary and secondary alcohols can be oxidized into

Answer to Problem 10.40AP
No product is obtained on the reaction of
Explanation of Solution
The product obtained on the reaction of
Figure 2
No reaction takes place between
No product is obtained on the reaction of
(c)
Interpretation:
The product expected when
Concept introduction:
An

Answer to Problem 10.40AP
The product obtained on the reaction of
Explanation of Solution
The product obtained on the reaction of
Figure 3
The alcohol
The product obtained on the reaction of
(d)
Interpretation:
The product expected when
Concept introduction:
Free radical reaction are the reaction in which the bond between the molecule is broken homolytically due to the presence of light energy. These kind of reactions are generally obtained with alkenes when reacted with halogen in the presence of light or peroxides.

Answer to Problem 10.40AP
No product is obtained when
Explanation of Solution
No reaction product is obtained on the reaction of
No product is obtained when
(e)
Interpretation:
The product expected when
Concept introduction:
Acid-base reaction are among the fastest reaction in the chemistry. Acids and bases reacts vigorously generating heat and water normally. Metals are basic in nature due to the presence of free electrons to donate. Alcohols are both acidic and basic in nature.

Answer to Problem 10.40AP
The product obtained on the reaction of
Explanation of Solution
The product obtained on the reaction of
Figure 4
The alcohol
The product obtained on the reaction of
(f)
Interpretation:
The product expected when
Concept introduction:
The hydroxide group in alcohols is not a good leaving group that can perform a nucleophilic substitution reaction on alcohols to produce more compounds. Hydroxide group is made a good leaving group with the help of some compounds like methanesulfonyl chloride and p-toluenesulfonyl chloride.

Answer to Problem 10.40AP
The product obtained on the reaction of
Explanation of Solution
The product obtained on the reaction of
Figure 5
The reaction of an alcohol with sulfonate derivatives such as methanesulfonyl chloride and p-toluenesulfonyl chloride are done to make hydroxide group and good leaving group. Pyridine being more basic takes up the proton of the hydroxide group make it a good nucleophile at first. This nucleophiles then substitute the chloride group of methanesulfonyl chloride leading to the formation of an ester. Same happens here in this reaction
The product obtained on the reaction of
(g)
Interpretation:
The product expected when the product of part (f) is reacted with
Concept introduction:
An

Answer to Problem 10.40AP
The product expected when the product of part (f) is reacted with
Explanation of Solution
The product obtained in part (f) is
The product obtained on the reaction of
Figure 6
The
The product expected when the product of part (f) is reacted with
(h)
Interpretation:
The product expected when the product of part (e) is reacted with the product of part (a) is to be stated.
Concept introduction:
An

Answer to Problem 10.40AP
The products obtained on the reaction of
Explanation of Solution
The product of part (a) is
The products obtained on the reaction of
Figure 7
The reaction undergoes via
The products obtained on the reaction of
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Chapter 10 Solutions
Organic Chemistry, Ebook And Single-course Homework Access
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- 7. All of the following compounds that are at the same oxidation levelare ___.u. methyl epoxide, v. propyne, w. propanal, x. propene,y. 2,2-dihydroxypropane, z. isopropanol?A. u,v,w,y; B. u,v,w; C. v,w,y,z; D. v, z; E. x,y,z Please include all steps. Thank you!arrow_forward9. Which one of the following substituents is the worst leaving group inan SN2 reaction? A. -NH2; B. -OH; C. –F; D. NH3; E. H2O Please include all steps. Thanks!arrow_forwardUsing the general properties of equilibrium constants At a certain temperature, the equilibrium constant K for the following reaction is 2.5 × 105: CO(g) + H2O(g) CO2(g) + H2(g) Use this information to complete the following table. Suppose a 7.0 L reaction vessel is filled with 1.7 mol of CO and 1.7 mol of H2O. What can you say about the composition of the mixture in the vessel at equilibrium? What is the equilibrium constant for the following reaction? Be sure your answer has the correct number of significant digits. CO2(9)+H2(g) CO(g)+H₂O(g) What is the equilibrium constant for the following reaction? Be sure your answer has the correct number of significant digits. 3 CO(g)+3H2O(g) = 3 CO2(g)+3H2(g) There will be very little CO and H2O. x10 There will be very little CO2 and H2. 000 Neither of the above is true. K = ☐ K = ☐ 18 Ararrow_forward
- 8. When ethane thiol is treated with hydrogen peroxide the product is___.A. ethane disulfide; B. diethyl sulfide; C. ethane sulfoxide; D. ethanesulfate; E. ethyl mercaptan. Please include all steps. Thanks!arrow_forward5. The major product of the three step reaction that takes place when 1-propanol is treated with strong acid is?A. dipropyl ether; B. propene; C. propanal; D. isopropyl propyl ether;E. 1-hexanol Please include all steps. Thank you!arrow_forward6. The formula of the product of the addition of HCN to benzaldehydeis ___.A. C8H7NO; B. C8H6NO; C. C14H11NO; D. C9H9NO; E. C9H8NO Please include all steps. Thank you!arrow_forward
- Predicting the qualitative acid-base properties of salts Consider the following data on some weak acids and weak bases: base acid K K a name formula name formula nitrous acid HNO2 4.5×10 hydroxylamine HONH2 1.1 × 10 8 hypochlorous acid HCIO 8 3.0 × 10 methylamine CH3NH2 | 4.4 × 10¯ 4 Use this data to rank the following solutions in order of increasing pH. In other words, select a '1' next to the solution that will have the lowest pH, a '2' next to the solution that will have the next lowest pH, and so on. 0.1 M KCIO solution PH choose one 0.1 M NaNO2 0.1 M CH3NH3Br 0.1 M NaBr choose one ✓ choose one v ✓ choose one 1 (lowest) ☑ 2 3 4 (highest)arrow_forwardFor this Orgo problem, don't worry about question 3 below it. Please explain your thought process, all your steps, and also include how you would tackle a similar problem. Thank you!arrow_forwardUsing the general properties of equilibrium constants At a certain temperature, the equilibrium constant K for the following reaction is 0.84: H2(g) + 2(g) 2 HI(g) = Use this information to complete the following table. Suppose a 34. L reaction vessel is filled with 0.79 mol of HI. What can you say about the composition of the mixture in the vessel at equilibrium? There will be very little H2 and 12. ☐ x10 There will be very little HI. Neither of the above is true. What is the equilibrium constant for the following reaction? Be sure your answer has the correct number of significant digits. 2 HI(g) H₂(9)+12(9) K = What is the equilibrium constant for the following reaction? Be sure your answer has the correct number of significant digits. 2 H2(g)+212(9) 4 HI(g) K = ☐ ☑arrow_forward
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