(a) Interpretation: The structure of seven-carbon tertiary alcohol which yields a single alkene after acid-catalyzed dehydration is to be stated. Concept introduction: The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

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Answer 1

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 10, Problem 10.41AP

Interpretation Introduction

(a)

Interpretation:

The structure of seven-carbon tertiary alcohol which yields a single alkene after acid-catalyzed dehydration is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(b)

Interpretation:

The structure of alcohol that, after acid-catalyzed dehydration yields an alkene and after the ozonolysis followed with (CH3)2S, gives only benzaldehyde is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(c)

Interpretation:

The structure of alcohol that gives the same product when it reacts with KMnO4 as it obtained from the ozonolysis of trans−3,6−dimethyl−4−octene followed by treatment with H2O2 is to be stated.

Concept introduction:

Potassium permanganate (KMnO4) is a useful oxidizing agent, which can oxidize primary alcohol to carboxylic acid in the presence of basic solution but not used in secondary alcohol to ketones because ketones react further with alkaline permanganate solution. The oxidative ozonolysis of alkene also produces a carboxylic acid.

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19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 10, Problem 10.41AP

Interpretation Introduction

(a)

Interpretation:

The structure of seven-carbon tertiary alcohol which yields a single alkene after acid-catalyzed dehydration is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(b)

Interpretation:

The structure of alcohol that, after acid-catalyzed dehydration yields an alkene and after the ozonolysis followed with (CH3)2S, gives only benzaldehyde is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(c)

Interpretation:

The structure of alcohol that gives the same product when it reacts with KMnO4 as it obtained from the ozonolysis of trans−3,6−dimethyl−4−octene followed by treatment with H2O2 is to be stated.

Concept introduction:

Potassium permanganate (KMnO4) is a useful oxidizing agent, which can oxidize primary alcohol to carboxylic acid in the presence of basic solution but not used in secondary alcohol to ketones because ketones react further with alkaline permanganate solution. The oxidative ozonolysis of alkene also produces a carboxylic acid.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 10, Problem 10.41AP

Interpretation Introduction

(a)

Interpretation:

The structure of seven-carbon tertiary alcohol which yields a single alkene after acid-catalyzed dehydration is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(b)

Interpretation:

The structure of alcohol that, after acid-catalyzed dehydration yields an alkene and after the ozonolysis followed with (CH3)2S, gives only benzaldehyde is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(c)

Interpretation:

The structure of alcohol that gives the same product when it reacts with KMnO4 as it obtained from the ozonolysis of trans−3,6−dimethyl−4−octene followed by treatment with H2O2 is to be stated.

Concept introduction:

Potassium permanganate (KMnO4) is a useful oxidizing agent, which can oxidize primary alcohol to carboxylic acid in the presence of basic solution but not used in secondary alcohol to ketones because ketones react further with alkaline permanganate solution. The oxidative ozonolysis of alkene also produces a carboxylic acid.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 10, Problem 10.41AP

Interpretation Introduction

(a)

Interpretation:

The structure of seven-carbon tertiary alcohol which yields a single alkene after acid-catalyzed dehydration is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(b)

Interpretation:

The structure of alcohol that, after acid-catalyzed dehydration yields an alkene and after the ozonolysis followed with (CH3)2S, gives only benzaldehyde is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(c)

Interpretation:

The structure of alcohol that gives the same product when it reacts with KMnO4 as it obtained from the ozonolysis of trans−3,6−dimethyl−4−octene followed by treatment with H2O2 is to be stated.

Concept introduction:

Potassium permanganate (KMnO4) is a useful oxidizing agent, which can oxidize primary alcohol to carboxylic acid in the presence of basic solution but not used in secondary alcohol to ketones because ketones react further with alkaline permanganate solution. The oxidative ozonolysis of alkene also produces a carboxylic acid.

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Answer 5

Chapter 10, Problem 10.41AP

Interpretation Introduction

(a)

Interpretation:

The structure of seven-carbon tertiary alcohol which yields a single alkene after acid-catalyzed dehydration is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(b)

Interpretation:

The structure of alcohol that, after acid-catalyzed dehydration yields an alkene and after the ozonolysis followed with (CH3)2S, gives only benzaldehyde is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(c)

Interpretation:

The structure of alcohol that gives the same product when it reacts with KMnO4 as it obtained from the ozonolysis of trans−3,6−dimethyl−4−octene followed by treatment with H2O2 is to be stated.

Concept introduction:

Potassium permanganate (KMnO4) is a useful oxidizing agent, which can oxidize primary alcohol to carboxylic acid in the presence of basic solution but not used in secondary alcohol to ketones because ketones react further with alkaline permanganate solution. The oxidative ozonolysis of alkene also produces a carboxylic acid.

Answer 6

Chapter 10, Problem 10.41AP

Interpretation Introduction

(a)

Interpretation:

The structure of seven-carbon tertiary alcohol which yields a single alkene after acid-catalyzed dehydration is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Answer 7

Chapter 10, Problem 10.41AP

Interpretation Introduction

(a)

Interpretation:

The structure of seven-carbon tertiary alcohol which yields a single alkene after acid-catalyzed dehydration is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of alcohol that, after acid-catalyzed dehydration yields an alkene and after the ozonolysis followed with (CH3)2S, gives only benzaldehyde is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of alcohol that, after acid-catalyzed dehydration yields an alkene and after the ozonolysis followed with (CH3)2S, gives only benzaldehyde is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of alcohol that gives the same product when it reacts with KMnO4 as it obtained from the ozonolysis of trans−3,6−dimethyl−4−octene followed by treatment with H2O2 is to be stated.

Concept introduction:

Potassium permanganate (KMnO4) is a useful oxidizing agent, which can oxidize primary alcohol to carboxylic acid in the presence of basic solution but not used in secondary alcohol to ketones because ketones react further with alkaline permanganate solution. The oxidative ozonolysis of alkene also produces a carboxylic acid.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of alcohol that gives the same product when it reacts with KMnO4 as it obtained from the ozonolysis of trans−3,6−dimethyl−4−octene followed by treatment with H2O2 is to be stated.

Concept introduction:

Potassium permanganate (KMnO4) is a useful oxidizing agent, which can oxidize primary alcohol to carboxylic acid in the presence of basic solution but not used in secondary alcohol to ketones because ketones react further with alkaline permanganate solution. The oxidative ozonolysis of alkene also produces a carboxylic acid.

Answer 12

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Ch. 10 - Prob. 10.1P Ch. 10 - Prob. 10.2P Ch. 10 - Prob. 10.3P Ch. 10 - Prob. 10.4P Ch. 10 - Prob. 10.5P Ch. 10 - Prob. 10.6P Ch. 10 - Prob. 10.7P Ch. 10 - Prob. 10.8P Ch. 10 - Prob. 10.9P Ch. 10 - Prob. 10.10P

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