(a) Interpretation: The orbitals involved in the π bond of carbon and phosphorus in PPh 3 =CH 2 are to be stated. Concept introduction: The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

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Answer 1

Question

Chapter 10, Problem 10.69AP

Interpretation Introduction

(a)

Interpretation:

The orbitals involved in the $π$ bond of carbon and phosphorus in $PPh3=CH2$ are to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Interpretation Introduction

(b)

Interpretation:

The resonance structure for the Wittig reagent is to be drawn.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the given compound is a strong base which reacts rapidly with water is to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

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Answer 2

Question

Chapter 10, Problem 10.69AP

Interpretation Introduction

(a)

Interpretation:

The orbitals involved in the $π$ bond of carbon and phosphorus in $PPh3=CH2$ are to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Interpretation Introduction

(b)

Interpretation:

The resonance structure for the Wittig reagent is to be drawn.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the given compound is a strong base which reacts rapidly with water is to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

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Answer 3

Question

Chapter 10, Problem 10.69AP

Interpretation Introduction

(a)

Interpretation:

The orbitals involved in the $π$ bond of carbon and phosphorus in $PPh3=CH2$ are to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Interpretation Introduction

(b)

Interpretation:

The resonance structure for the Wittig reagent is to be drawn.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the given compound is a strong base which reacts rapidly with water is to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

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Answer 4

Question

Chapter 10, Problem 10.69AP

Interpretation Introduction

(a)

Interpretation:

The orbitals involved in the $π$ bond of carbon and phosphorus in $PPh3=CH2$ are to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Interpretation Introduction

(b)

Interpretation:

The resonance structure for the Wittig reagent is to be drawn.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the given compound is a strong base which reacts rapidly with water is to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

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Answer 5

Chapter 10, Problem 10.69AP

Interpretation Introduction

(a)

Interpretation:

The orbitals involved in the $π$ bond of carbon and phosphorus in $PPh3=CH2$ are to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Interpretation Introduction

(b)

Interpretation:

The resonance structure for the Wittig reagent is to be drawn.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the given compound is a strong base which reacts rapidly with water is to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Answer 6

Chapter 10, Problem 10.69AP

Interpretation Introduction

(a)

Interpretation:

The orbitals involved in the $π$ bond of carbon and phosphorus in $PPh3=CH2$ are to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Answer 7

Chapter 10, Problem 10.69AP

Interpretation Introduction

(a)

Interpretation:

The orbitals involved in the $π$ bond of carbon and phosphorus in $PPh3=CH2$ are to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The resonance structure for the Wittig reagent is to be drawn.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The resonance structure for the Wittig reagent is to be drawn.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The reason as to why the given compound is a strong base which reacts rapidly with water is to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The reason as to why the given compound is a strong base which reacts rapidly with water is to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidenetriphenylphosphine that is phosphorous ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 10 - Prob. 10.1P Ch. 10 - Prob. 10.2P Ch. 10 - Prob. 10.3P Ch. 10 - Prob. 10.4P Ch. 10 - Prob. 10.5P Ch. 10 - Prob. 10.6P Ch. 10 - Prob. 10.7P Ch. 10 - Prob. 10.8P Ch. 10 - Prob. 10.9P Ch. 10 - Prob. 10.10P

Solution Summary: The author explains that the orbitals involved in the bond of carbon and phosphorus are to be stated.

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Chapter 10 Solutions