Organic Chemistry, Ebook And Single-course Homework Access
Organic Chemistry, Ebook And Single-course Homework Access
6th Edition
ISBN: 9781319085841
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 10, Problem 10.36P
Interpretation Introduction

(a)

Interpretation:

The number of electrons involved in the oxidation of triphenyl phosphine to triphenyl phosphine oxide is to be stated.

Concept introduction:

The oxidation is the process of the increase in the oxidation number of the element. This can be done by addition of oxygen, removal of hydrogen and lose of electrons. The number of electrons involved in the oxidation is equal to the change in the oxidation number of the element.

Interpretation Introduction

(b)

Interpretation:

The resonance structures of triphenylphosphine oxide in which it obeys octet rule are to be stated.

Concept introduction:

Resonance is the phenomena of the delocalization of pi electrons to give extra stability to the molecule. This extra stability comes from the distribution of the energy of the molecule in the resonance structures formed.

Interpretation Introduction

(c)

Interpretation:

Lewis structure for trimethylamine oxide (Me3NO) is to be stated. An explanation as to why bond order of the N—O bond in Me3NO compound different from the bond order of the P—O bond in the trimethylphosphine oxide is to be stated.

Concept introduction:

Lewis structure is the electron dot model of the compound showing each pair of electrons between the two atoms leading to the formation of one covalent bond.

Lewis diagrams follow the octet rule when drawn. That is, the total number of electrons around each can be a maximum of eight.

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The Concept of Aromaticity 21.15 State the number of 2p orbital electrons in each molecule or ion. (a) (b) (e) (f) (c) (d) (h) (i) DA (k) 21.16 Which of the molecules and ions given in Problem 21.15 are aromatic according to the Hückel criteria? Which, if planar, would be antiaromatic? 21.17 Which of the following structures are considered aromatic according to the Hückel criteria? ---0-0 (a) (b) (c) (d) (e) (h) H -H .8.0- 21.18 Which of the molecules and ions from Problem 21.17 have electrons donated by a heteroatom?
1. Show the steps necessary to make 2-methyl-4-nonene using a Wittig reaction. Start with triphenylphosphine and an alkyl halide. After that you may use any other organic or inorganic reagents. 2. Write in the product of this reaction: CH3 CH₂ (C6H5)₂CuLi H₂O+
3. Name this compound properly, including stereochemistry. H₂C H3C CH3 OH 4. Show the step(s) necessary to transform the compound on the left into the acid on the right. Bri CH2 5. Write in the product of this LiAlH4 Br H₂C OH

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