The name of the branched alkyl group attached to the carbon chains has to be given. Concept Introduction: Alkyl groups are named according to IUPAC nomenclature . The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups. Rule 1: Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group. Rule 2: Base chain that is identified is numbered in a way beginning at the point of attachment. Rule 3: The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

Question

> You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: 1. ☑ CI 2. H3O+ O Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. Explanation Check ? DO 18 Ar B © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility

Answer 1

Question

Chapter 1, Problem 1.81EP

(a)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(b)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(c)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(d)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

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> You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: 1. ☑ CI 2. H3O+ O Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. Explanation Check ? DO 18 Ar B © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility

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Consider a solution of 0.00304 moles of 4-nitrobenzoic acid (pKa = 3.442) dissolved in 25 mL water and titrated with 0.0991 M NaOH. Calculate the pH at the equivalence point

Answer 2

Question

Chapter 1, Problem 1.81EP

(a)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(b)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(c)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(d)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

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Answer 3

Question

Chapter 1, Problem 1.81EP

(a)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(b)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(c)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(d)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

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Answer 4

Question

Chapter 1, Problem 1.81EP

(a)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(b)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(c)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(d)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

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Answer 5

Chapter 1, Problem 1.81EP

(a)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(b)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(c)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(d)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

Answer 6

Chapter 1, Problem 1.81EP

(a)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

Answer 7

Chapter 1, Problem 1.81EP

(a)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The name of the branched alkyl group attached to the carbon chains has to be given.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

Answer 14

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Answer 15

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Answer 25

Ch. 1.1 - Prob. 1QQ Ch. 1.1 - Prob. 2QQ Ch. 1.2 - Which of the following statements about the...Ch. 1.2 - Prob. 2QQ Ch. 1.3 - Prob. 1QQ Ch. 1.3 - Prob. 2QQ Ch. 1.4 - Prob. 1QQ Ch. 1.4 - Prob. 2QQ Ch. 1.4 - Prob. 3QQ Ch. 1.5 - Prob. 1QQ

Solution Summary: The author explains that the name of the branched alkyl group attached to the carbon chains is given according to IUPAC nomenclature.

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Chapter 1 Solutions