IUPAC name for the given alkane has to be written. Concept Introduction: Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word. Prefix represents the substituent present in the molecule and its position in the root name. Suffix denotes the presence of functional group if any in the molecule. It can be an alkene , alkyne , alcohol, carboxylic acid , alcohol etc. Root word represents the longest continuous carbon skeleton of the organic molecule. To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Question

What is the stepwise mechanism for this reaction?

Answer 1

Question

Chapter 1, Problem 1.52EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

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What is the stepwise mechanism for this reaction?

32. Consider a two-state system in which the low energy level is 300 J mol 1 and the higher energy level is 800 J mol 1, and the temperature is 300 K. Find the population of each level. Hint: Pay attention to your units. A. What is the partition function for this system? B. What are the populations of each level? Now instead, consider a system with energy levels of 0 J mol C. Now what is the partition function? D. And what are the populations of the two levels? E. Finally, repeat the second calculation at 500 K. and 500 J mol 1 at 300 K. F. What do you notice about the populations as you increase the temperature? At what temperature would you expect the states to have equal populations?

30. We will derive the forms of the molecular partition functions for atoms and molecules shortly in class, but the partition function that describes the translational and rotational motion of a homonuclear diatomic molecule is given by Itrans (V,T) = = 2πmkBT h² V grot (T) 4π²IKBT h² Where h is Planck's constant and I is molecular moment of inertia. The overall partition function is qmolec Qtrans qrot. Find the energy, enthalpy, entropy, and Helmholtz free energy for the translational and rotational modes of 1 mole of oxygen molecules and 1 mole of iodine molecules at 50 K and at 300 K and with a volume of 1 m³. Here is some useful data: Moment of inertia: I2 I 7.46 x 10- 45 kg m² 2 O2 I 1.91 x 101 -46 kg m²

Answer 2

Question

Chapter 1, Problem 1.52EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

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Answer 3

Question

Chapter 1, Problem 1.52EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

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Answer 4

Question

Chapter 1, Problem 1.52EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

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Answer 5

Chapter 1, Problem 1.52EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 6

Chapter 1, Problem 1.52EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 7

Chapter 1, Problem 1.52EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 8

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 9

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 10

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 11

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 12

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 13

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 14

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Answer 25

Ch. 1.1 - Prob. 1QQ Ch. 1.1 - Prob. 2QQ Ch. 1.2 - Which of the following statements about the...Ch. 1.2 - Prob. 2QQ Ch. 1.3 - Prob. 1QQ Ch. 1.3 - Prob. 2QQ Ch. 1.4 - Prob. 1QQ Ch. 1.4 - Prob. 2QQ Ch. 1.4 - Prob. 3QQ Ch. 1.5 - Prob. 1QQ

Solution Summary: The author explains the IUPAC name for the given alkane, which consists of three parts in major namely Prefix suffix and root word.

Chapter 1 Solutions