Organic And Biological Chemistry
7th Edition
ISBN: 9781305638686
Author: H. Stephen Stoker
Publisher: Brooks Cole
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Chapter 1.15, Problem 2QQ
Interpretation Introduction
Interpretation:
The one which is not a mixture of cyclic and noncyclic
Concept Introduction:
Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.
Alkanes are linear chain saturated hydrocarbons and cycloalkanes are cyclic carbon chain saturated hydrocarbons. They both occur naturally. One of the major source of alkane and cycloalkanes are natural gas and petroleum.
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A 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 20.0 mL of the base solution, what is the pH of the resulting solution?
For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3)
→
Give the expression for the acceptable rate.
→
→
(A).
d[N205]
dt
==
2k,k₂[N₂O₂]
k₁+k₁₂
(B).
d[N2O5]
=-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³
dt
(C).
d[N2O5]
=-k₁[N₂O] + k [NO] - k₂[NO] [NO]
d[N2O5]
(D).
=
dt
= -k₁[N2O5] - k¸[NO][N₂05]
dt
Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard
the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.
For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3)
→
Give the expression for the acceptable rate.
→
→
(A).
d[N205]
dt
==
2k,k₂[N₂O₂]
k₁+k₁₂
(B).
d[N2O5]
=-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³
dt
(C).
d[N2O5]
=-k₁[N₂O] + k [NO] - k₂[NO] [NO]
d[N2O5]
(D).
=
dt
= -k₁[N2O5] - k¸[NO][N₂05]
dt
Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard
the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.
Chapter 1 Solutions
Organic And Biological Chemistry
Ch. 1.1 - Prob. 1QQCh. 1.1 - Prob. 2QQCh. 1.2 - Which of the following statements about the...Ch. 1.2 - Prob. 2QQCh. 1.3 - Prob. 1QQCh. 1.3 - Prob. 2QQCh. 1.4 - Prob. 1QQCh. 1.4 - Prob. 2QQCh. 1.4 - Prob. 3QQCh. 1.5 - Prob. 1QQ
Ch. 1.5 - Prob. 2QQCh. 1.5 - Prob. 3QQCh. 1.6 - Prob. 1QQCh. 1.6 - Prob. 2QQCh. 1.6 - Prob. 3QQCh. 1.6 - Prob. 4QQCh. 1.7 - Prob. 1QQCh. 1.7 - Prob. 2QQCh. 1.8 - Prob. 1QQCh. 1.8 - Prob. 2QQCh. 1.8 - Prob. 3QQCh. 1.8 - Prob. 4QQCh. 1.8 - Prob. 5QQCh. 1.8 - Prob. 6QQCh. 1.8 - Prob. 7QQCh. 1.9 - Prob. 1QQCh. 1.9 - Prob. 2QQCh. 1.10 - Prob. 1QQCh. 1.10 - Prob. 2QQCh. 1.11 - Prob. 1QQCh. 1.11 - Prob. 2QQCh. 1.11 - Prob. 3QQCh. 1.12 - Prob. 1QQCh. 1.12 - Prob. 2QQCh. 1.12 - Prob. 3QQCh. 1.13 - Prob. 1QQCh. 1.13 - Prob. 2QQCh. 1.13 - Prob. 3QQCh. 1.14 - Prob. 1QQCh. 1.14 - Prob. 2QQCh. 1.14 - Prob. 3QQCh. 1.15 - Prob. 1QQCh. 1.15 - Prob. 2QQCh. 1.16 - Prob. 1QQCh. 1.16 - Prob. 2QQCh. 1.16 - Prob. 3QQCh. 1.17 - Prob. 1QQCh. 1.17 - Prob. 2QQCh. 1.17 - Prob. 3QQCh. 1.17 - Prob. 4QQCh. 1.18 - Prob. 1QQCh. 1.18 - Prob. 2QQCh. 1.18 - Prob. 3QQCh. 1.18 - Prob. 4QQCh. 1 - Prob. 1.1EPCh. 1 - Prob. 1.2EPCh. 1 - Prob. 1.3EPCh. 1 - Prob. 1.4EPCh. 1 - Indicate whether each of the following situations...Ch. 1 - Indicate whether each of the following situations...Ch. 1 - Prob. 1.7EPCh. 1 - Prob. 1.8EPCh. 1 - What is the difference between a saturated...Ch. 1 - What structural feature is present in an...Ch. 1 - Prob. 1.11EPCh. 1 - Prob. 1.12EPCh. 1 - Prob. 1.13EPCh. 1 - Prob. 1.14EPCh. 1 - Prob. 1.15EPCh. 1 - Prob. 1.16EPCh. 1 - Convert the expanded structural formulas in...Ch. 1 - Prob. 1.18EPCh. 1 - Prob. 1.19EPCh. 1 - Prob. 1.20EPCh. 1 - Prob. 1.21EPCh. 1 - Prob. 1.22EPCh. 1 - Prob. 1.23EPCh. 1 - Prob. 1.24EPCh. 1 - Prob. 1.25EPCh. 1 - Prob. 1.26EPCh. 1 - Indicate whether each of the following would be...Ch. 1 - Indicate whether each of the following would be...Ch. 1 - Prob. 1.29EPCh. 1 - Explain why two different straight-chain alkanes...Ch. 1 - With the help of Table 12-1, indicate how many...Ch. 1 - Prob. 1.32EPCh. 1 - How many of the numerous eight-carbon alkane...Ch. 1 - How many of the numerous seven-carbon alkane...Ch. 1 - For each of the following pairs of structures,...Ch. 1 - For each of the following pairs of structures,...Ch. 1 - Convert each of the following linear condensed...Ch. 1 - Prob. 1.38EPCh. 1 - Prob. 1.39EPCh. 1 - Prob. 1.40EPCh. 1 - Prob. 1.41EPCh. 1 - Prob. 1.42EPCh. 1 - Prob. 1.43EPCh. 1 - Prob. 1.44EPCh. 1 - Prob. 1.45EPCh. 1 - Prob. 1.46EPCh. 1 - Prob. 1.47EPCh. 1 - Prob. 1.48EPCh. 1 - Prob. 1.49EPCh. 1 - Prob. 1.50EPCh. 1 - Prob. 1.51EPCh. 1 - Prob. 1.52EPCh. 1 - Draw a condensed structural formula for each of...Ch. 1 - Draw a condensed structural formula for each of...Ch. 1 - Prob. 1.55EPCh. 1 - For each of the alkanes in Problem 12-54,...Ch. 1 - Explain why the name given for each of the...Ch. 1 - Prob. 1.58EPCh. 1 - Indicate whether or not the two alkanes in each of...Ch. 1 - Prob. 1.60EPCh. 1 - How many of the 18 C8 alkane constitutional...Ch. 1 - How many of the nine C7 alkane constitutional...Ch. 1 - Prob. 1.63EPCh. 1 - Prob. 1.64EPCh. 1 - Prob. 1.65EPCh. 1 - Prob. 1.66EPCh. 1 - Do the line-angle structural formulas in each of...Ch. 1 - Do the line-angle structural formulas in each of...Ch. 1 - Convert each of the condensed structural formulas...Ch. 1 - Convert each of the condensed structural formulas...Ch. 1 - Assign an IUPAC name to each of the compounds in...Ch. 1 - Prob. 1.72EPCh. 1 - Prob. 1.73EPCh. 1 - Prob. 1.74EPCh. 1 - For each of the alkane structures in Problem...Ch. 1 - For each of the alkane structures in Problem...Ch. 1 - Prob. 1.77EPCh. 1 - Prob. 1.78EPCh. 1 - Prob. 1.79EPCh. 1 - Prob. 1.80EPCh. 1 - Prob. 1.81EPCh. 1 - Prob. 1.82EPCh. 1 - Draw condensed structural formulas for the...Ch. 1 - Draw condensed structural formulas for the...Ch. 1 - To which carbon atoms in a hexane molecule can...Ch. 1 - Prob. 1.86EPCh. 1 - Prob. 1.87EPCh. 1 - Prob. 1.88EPCh. 1 - Give an acceptable alternate name for each of the...Ch. 1 - Prob. 1.90EPCh. 1 - Prob. 1.91EPCh. 1 - Prob. 1.92EPCh. 1 - Prob. 1.93EPCh. 1 - Prob. 1.94EPCh. 1 - What is the molecular formula for each of the...Ch. 1 - Prob. 1.96EPCh. 1 - Prob. 1.97EPCh. 1 - Prob. 1.98EPCh. 1 - Prob. 1.99EPCh. 1 - How many secondary carbon atoms are present in...Ch. 1 - 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Prob. 1.134EPCh. 1 - Prob. 1.135EPCh. 1 - Assign an IUPAC name to each of the following...Ch. 1 - Prob. 1.137EPCh. 1 - Prob. 1.138EPCh. 1 - Prob. 1.139EPCh. 1 - Prob. 1.140EPCh. 1 - Prob. 1.141EPCh. 1 - Prob. 1.142EPCh. 1 - Prob. 1.143EPCh. 1 - Prob. 1.144EPCh. 1 - Prob. 1.145EPCh. 1 - Prob. 1.146EPCh. 1 - Give the IUPAC names for the eight isomeric...Ch. 1 - Prob. 1.148EP
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