(a) Interpretation: To arrange the bonds in the order of increasing bond length Concept introduction: Bond length or bond distance or inter nuclear distance. The atoms in the molecule are always vibrating with respect to each other and hence it is not possible to determine the distance between the nuclei of the atoms. This distance is called the bond length, is the average distance between the nuclei of the two bonded atoms together by the covalent bond. Bond length is related to bond order, when more electrons participate in the bond formation the bond is shorter. Bond length is also inversely to the bond strength.

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b) Certain cyclic compounds are known to be conformationally similar to carbohydrates, although they are not themselves carbohydrates. One example is Compound C shown below, which could be imagined as adopting four possible conformations. In reality, however, only one of these is particularly stable. Circle the conformation you expect to be the most stable, and provide an explanation to justify your choice. For your explanation to be both convincing and correct, it must contain not only words, but also "cartoon" orbital drawings contrasting the four structures. Compound C Possible conformations (circle one): Дет

Answer 1

Question

Chapter 1, Problem 1.73P

Interpretation Introduction

(a)

Interpretation:

To arrange the bonds in the order of increasing bond length

Concept introduction:

Bond length or bond distance or inter nuclear distance. The atoms in the molecule are always vibrating with respect to each other and hence it is not possible to determine the distance between the nuclei of the atoms. This distance is called the bond length, is the average distance between the nuclei of the two bonded atoms together by the covalent bond. Bond length is related to bond order, when more electrons participate in the bond formation the bond is shorter. Bond length is also inversely to the bond strength.

Interpretation Introduction

(b)

Interpretation:

To arrange the bonds in the order of increasing bond length

Concept introduction:

Bond length or bond distance or inter nuclear distance. The atoms in the molecule are always vibrating with respect to each other and hence it is not possible to determine the distance between the nuclei of the atoms. This distance is called the bond length, is the average distance between the nuclei of the two bonded atoms together by the covalent bond. Bond length is related to bond order, when more electrons participate in the bond formation the bond is shorter. Bond length is also inversely to the bond strength.

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b) Certain cyclic compounds are known to be conformationally similar to carbohydrates, although they are not themselves carbohydrates. One example is Compound C shown below, which could be imagined as adopting four possible conformations. In reality, however, only one of these is particularly stable. Circle the conformation you expect to be the most stable, and provide an explanation to justify your choice. For your explanation to be both convincing and correct, it must contain not only words, but also "cartoon" orbital drawings contrasting the four structures. Compound C Possible conformations (circle one): Дет

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