Principles of General Chemistry
Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Chapter 1, Problem 1.53P

Carry out each calculation, paying special attention to significant figures, rounding, and units:

  1. ( 4.32 × 10 7 g 4 3 ( 3.1416 ) ( 1.95 × 10 2 cm ) 3 ( The term 4 3 is exact . ) ( 1.84 × 10 2  g ) ( 44.7 m/s ) 2 2 ( The term 2 is exact . ) ( 1.07 × 10 4  mol/L ) 2 ( 3.8 × 10 3 mol/L ) ( 8.35 × 10 5 mol/L ) ( 1.48 × 10 2 mol/L ) 3

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5. Use the MS data to answer the questions on the next page. 14.0 1.4 15.0 8.1 100- MS-IW-5644 26.0 2.8 27.0 6.7 28.0 1.8 29.0 80 4.4 38.0 1.0 39.0 1.5 41.0 1.2 42.0 11.2 43.0 100.0 44.0 4.3 79.0 1.9 80.0 2.6 Relative Intensity 40 81.0 1.9 82.0 2.5 93.0 8.7 20- 95.0 8.2 121.0 2.0 123.0 2.0 136.0 11.8 0 138.0 11.5 20 40 8. 60 a. Br - 0 80 100 120 140 160 180 200 220 m/z Identify the m/z of the base peak and molecular ion. 2 b. Draw structures for each of the following fragments (include electrons and charges): 43.0, 93.0, 95.0, 136.0, and 138.0 m/z. C. Draw a reasonable a-fragmentation mechanism for the fragmentation of the molecular ion to fragment 43.0 m/z. Be sure to include all electrons and formal charges. 6. Using the values provided in Appendix E of your lab manual, calculate the monoisotopic mass for the pyridinium ion (CsH6N) and show your work.
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Stereochemistry: Three possible answers- diastereomers, enantiomers OH CH₂OH I -c=0 21108 1101 41745 HOR CH₂OH IL Но CH₂OH TIL a. Compounds I and III have this relationship with each other: enantiomers b. Compounds II and IV have this relationship with each other: c. Compounds I and II have this relationship with each other: d. *Draw one structure that is a stereoisomer of II, but neither a diastereomer nor an enantiomer. (more than one correct answer)

Chapter 1 Solutions

Principles of General Chemistry

Ch. 1 - Prob. 1.11PCh. 1 - Prob. 1.12PCh. 1 - Prob. 1.13PCh. 1 - Write the conversion factor(s) for in2tom2 (b)...Ch. 1 - Write the conversion factor(s) for cm/mintoin/ (b)...Ch. 1 - Describe the difference between intensive and...Ch. 1 - Explain the difference between mass and weight....Ch. 1 - For each of the following cases, state whether the...Ch. 1 - Prob. 1.19PCh. 1 - A one-step conversion is sufficient to convert a...Ch. 1 - The average radius of a molecule of lysozyme, an...Ch. 1 - The radius of a barium atom is 2.2210-10 m. What...Ch. 1 - A small hole in the wing of a space shuttle...Ch. 1 - Prob. 1.24PCh. 1 - The average density of Earth is 5.5g/cm3. What is...Ch. 1 - Prob. 1.26PCh. 1 - The volume of a certain bacterial cell is 2.56m3....Ch. 1 - How many cubic meters of milk are in 1qt(946.4mL)?...Ch. 1 - Prob. 1.29PCh. 1 - An empty Erlenmeyer flask weighs 241.3 g. When...Ch. 1 - A small cube of aluminum measures 15.6 mm on a...Ch. 1 - A steek ball-bearing with a circumference of 32.5...Ch. 1 - Perform the following conversions: 68oF (a...Ch. 1 - Perfrom the following conversions: 106oF (the body...Ch. 1 - A 25-0-g sample of each of three unknwon metals is...Ch. 1 - Prob. 1.36PCh. 1 - The distance between two adjacent peaks on a wave...Ch. 1 - Prob. 1.38PCh. 1 - Prob. 1.39PCh. 1 - Prob. 1.40PCh. 1 - Each of the beakers depicted below contains two...Ch. 1 - Prob. 1.42PCh. 1 - Prob. 1.43PCh. 1 - Underline the significant zeros in the folliwng...Ch. 1 - Prob. 1.45PCh. 1 - Carry out the following calculations, making sure...Ch. 1 - Carry out the following calculations, making sure...Ch. 1 - Prob. 1.48PCh. 1 - Write the following numbers in scientific...Ch. 1 - Prob. 1.50PCh. 1 - Prob. 1.51PCh. 1 - Carry out each calculation, paying special...Ch. 1 - Carry out each calculation, paying special...Ch. 1 - Which statements include excat numbers? Angel...Ch. 1 - Which of the following include exact numbers? (a)...Ch. 1 - How long is the metal strip shown below? Be sure...Ch. 1 - These organic solvents are used to clean compact...Ch. 1 - Prob. 1.58PCh. 1 - Prob. 1.59PCh. 1 - Prob. 1.60PCh. 1 - Prob. 1.61PCh. 1 - Prob. 1.62PCh. 1 - Prob. 1.63PCh. 1 - Prob. 1.64PCh. 1 - Prob. 1.65PCh. 1 - Bromine is used to prepare the pesticide methyl...Ch. 1 - Prob. 1.67PCh. 1 - Prob. 1.68PCh. 1 - Prob. 1.69PCh. 1 - Prob. 1.70PCh. 1 - Prob. 1.71PCh. 1 - For the year 2007. worldwide production of...Ch. 1 - Prob. 1.73PCh. 1 - Prob. 1.74PCh. 1 - Prob. 1.75PCh. 1 - Prob. 1.76PCh. 1 - Scenes A and B depict changes in matter at the...Ch. 1 - Prob. 1.78PCh. 1 - Prob. 1.79PCh. 1 - If a temperature scale were based on the freezing...
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