Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Textbook Question
Chapter 1, Problem 1.15P
Write the conversion factor(s) for
(c)
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 1 Solutions
Principles of General Chemistry
Ch. 1 - Scenes A-D represent atomic-scale views of...Ch. 1 - Describe solids, liquids, and gases in terms of...Ch. 1 - Define physical property and chemical property....Ch. 1 - Define physical change and chemical change. State...Ch. 1 - Which of the following is a chemical change?...Ch. 1 - Which of the following changes can be reversed by...Ch. 1 - For each pair, which has higher potential energy?...Ch. 1 - Prob. 1.8PCh. 1 - How ait the key elements of scientific thinking...Ch. 1 - Prob. 1.10P
Ch. 1 - Prob. 1.11PCh. 1 - Prob. 1.12PCh. 1 - Prob. 1.13PCh. 1 - Write the conversion factor(s) for in2tom2 (b)...Ch. 1 - Write the conversion factor(s) for cm/mintoin/ (b)...Ch. 1 - Describe the difference between intensive and...Ch. 1 - Explain the difference between mass and weight....Ch. 1 - For each of the following cases, state whether the...Ch. 1 - Prob. 1.19PCh. 1 - A one-step conversion is sufficient to convert a...Ch. 1 - The average radius of a molecule of lysozyme, an...Ch. 1 - The radius of a barium atom is 2.2210-10 m. What...Ch. 1 - A small hole in the wing of a space shuttle...Ch. 1 - Prob. 1.24PCh. 1 - The average density of Earth is 5.5g/cm3. What is...Ch. 1 - Prob. 1.26PCh. 1 - The volume of a certain bacterial cell is 2.56m3....Ch. 1 - How many cubic meters of milk are in 1qt(946.4mL)?...Ch. 1 - Prob. 1.29PCh. 1 - An empty Erlenmeyer flask weighs 241.3 g. When...Ch. 1 - A small cube of aluminum measures 15.6 mm on a...Ch. 1 - A steek ball-bearing with a circumference of 32.5...Ch. 1 - Perform the following conversions: 68oF (a...Ch. 1 - Perfrom the following conversions: 106oF (the body...Ch. 1 - A 25-0-g sample of each of three unknwon metals is...Ch. 1 - Prob. 1.36PCh. 1 - The distance between two adjacent peaks on a wave...Ch. 1 - Prob. 1.38PCh. 1 - Prob. 1.39PCh. 1 - Prob. 1.40PCh. 1 - Each of the beakers depicted below contains two...Ch. 1 - Prob. 1.42PCh. 1 - Prob. 1.43PCh. 1 - Underline the significant zeros in the folliwng...Ch. 1 - Prob. 1.45PCh. 1 - Carry out the following calculations, making sure...Ch. 1 - Carry out the following calculations, making sure...Ch. 1 - Prob. 1.48PCh. 1 - Write the following numbers in scientific...Ch. 1 - Prob. 1.50PCh. 1 - Prob. 1.51PCh. 1 - Carry out each calculation, paying special...Ch. 1 - Carry out each calculation, paying special...Ch. 1 - Which statements include excat numbers? Angel...Ch. 1 - Which of the following include exact numbers? (a)...Ch. 1 - How long is the metal strip shown below? Be sure...Ch. 1 - These organic solvents are used to clean compact...Ch. 1 - Prob. 1.58PCh. 1 - Prob. 1.59PCh. 1 - Prob. 1.60PCh. 1 - Prob. 1.61PCh. 1 - Prob. 1.62PCh. 1 - Prob. 1.63PCh. 1 - Prob. 1.64PCh. 1 - Prob. 1.65PCh. 1 - Bromine is used to prepare the pesticide methyl...Ch. 1 - Prob. 1.67PCh. 1 - Prob. 1.68PCh. 1 - Prob. 1.69PCh. 1 - Prob. 1.70PCh. 1 - Prob. 1.71PCh. 1 - For the year 2007. worldwide production of...Ch. 1 - Prob. 1.73PCh. 1 - Prob. 1.74PCh. 1 - Prob. 1.75PCh. 1 - Prob. 1.76PCh. 1 - Scenes A and B depict changes in matter at the...Ch. 1 - Prob. 1.78PCh. 1 - Prob. 1.79PCh. 1 - If a temperature scale were based on the freezing...
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- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
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