Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Chapter 1, Problem 1.64P
Interpretation Introduction
Interpretation: Time taken by air conditioner to exchange air in the room is to be determined.
Concept introduction: Intensive properties depend on nature of substance but extensive properties depend on amount of substance. Intensive properties are same for specific substance while extensive properties are additive in nature. Volume is an example of extensive property.
Volume is defined as amount of space occupied by substance and it is utilized to measure size in three dimensions.
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Given the equilibrium A2 + B2 ⇌ 2 AB where k1 is the rate coefficient of the forward reaction and k-1 is the rate coefficient of the reverse reaction, with the forward reaction being first-order in A2 and B2, and the reverse reaction being second-order in AB. Equilibrium will be reached later if the relative values of the constants are:(A) k1 high and k-1 high(B) k1 high and k-1 low(C) k1 low and k-1 high(D) k1 low and k-1 low
A 2-step reaction has the following mechanism:
|
1. (fast) R2
R+R
2. (slow) R+Q
K₂ P
k_1
What series does it have?
(A). v=
-
= (k + k1 − k-1)[R2][Q]
(B). v=-k₁[R₂] + k₁[R]² - k₂[R][Q]
(C). v=k₂[R]²[Q]²
(D). v = k[R₂]1/2[Q]
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
Chapter 1 Solutions
Principles of General Chemistry
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