Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Textbook Question
Chapter 1, Problem 1.35P
A 25-0-g sample of each of three unknwon metals is added to 25.0 mL of water in graduated cylinders A, B and C, and the final volumes are depicted in the circles below. Given their densities, identify the metal in each cylinder: zinc
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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
-10
Q: Arrange BCC and Fec
metals, in sequence from the
Fable (Dr. R's slides) and
Calculate Volume and Density.
Aa
BCC
V
52 5
SFCC
None
Chapter 1 Solutions
Principles of General Chemistry
Ch. 1 - Scenes A-D represent atomic-scale views of...Ch. 1 - Describe solids, liquids, and gases in terms of...Ch. 1 - Define physical property and chemical property....Ch. 1 - Define physical change and chemical change. State...Ch. 1 - Which of the following is a chemical change?...Ch. 1 - Which of the following changes can be reversed by...Ch. 1 - For each pair, which has higher potential energy?...Ch. 1 - Prob. 1.8PCh. 1 - How ait the key elements of scientific thinking...Ch. 1 - Prob. 1.10P
Ch. 1 - Prob. 1.11PCh. 1 - Prob. 1.12PCh. 1 - Prob. 1.13PCh. 1 - Write the conversion factor(s) for in2tom2 (b)...Ch. 1 - Write the conversion factor(s) for cm/mintoin/ (b)...Ch. 1 - Describe the difference between intensive and...Ch. 1 - Explain the difference between mass and weight....Ch. 1 - For each of the following cases, state whether the...Ch. 1 - Prob. 1.19PCh. 1 - A one-step conversion is sufficient to convert a...Ch. 1 - The average radius of a molecule of lysozyme, an...Ch. 1 - The radius of a barium atom is 2.2210-10 m. What...Ch. 1 - A small hole in the wing of a space shuttle...Ch. 1 - Prob. 1.24PCh. 1 - The average density of Earth is 5.5g/cm3. What is...Ch. 1 - Prob. 1.26PCh. 1 - The volume of a certain bacterial cell is 2.56m3....Ch. 1 - How many cubic meters of milk are in 1qt(946.4mL)?...Ch. 1 - Prob. 1.29PCh. 1 - An empty Erlenmeyer flask weighs 241.3 g. When...Ch. 1 - A small cube of aluminum measures 15.6 mm on a...Ch. 1 - A steek ball-bearing with a circumference of 32.5...Ch. 1 - Perform the following conversions: 68oF (a...Ch. 1 - Perfrom the following conversions: 106oF (the body...Ch. 1 - A 25-0-g sample of each of three unknwon metals is...Ch. 1 - Prob. 1.36PCh. 1 - The distance between two adjacent peaks on a wave...Ch. 1 - Prob. 1.38PCh. 1 - Prob. 1.39PCh. 1 - Prob. 1.40PCh. 1 - Each of the beakers depicted below contains two...Ch. 1 - Prob. 1.42PCh. 1 - Prob. 1.43PCh. 1 - Underline the significant zeros in the folliwng...Ch. 1 - Prob. 1.45PCh. 1 - Carry out the following calculations, making sure...Ch. 1 - Carry out the following calculations, making sure...Ch. 1 - Prob. 1.48PCh. 1 - Write the following numbers in scientific...Ch. 1 - Prob. 1.50PCh. 1 - Prob. 1.51PCh. 1 - Carry out each calculation, paying special...Ch. 1 - Carry out each calculation, paying special...Ch. 1 - Which statements include excat numbers? Angel...Ch. 1 - Which of the following include exact numbers? (a)...Ch. 1 - How long is the metal strip shown below? Be sure...Ch. 1 - These organic solvents are used to clean compact...Ch. 1 - Prob. 1.58PCh. 1 - Prob. 1.59PCh. 1 - Prob. 1.60PCh. 1 - Prob. 1.61PCh. 1 - Prob. 1.62PCh. 1 - Prob. 1.63PCh. 1 - Prob. 1.64PCh. 1 - Prob. 1.65PCh. 1 - Bromine is used to prepare the pesticide methyl...Ch. 1 - Prob. 1.67PCh. 1 - Prob. 1.68PCh. 1 - Prob. 1.69PCh. 1 - Prob. 1.70PCh. 1 - Prob. 1.71PCh. 1 - For the year 2007. worldwide production of...Ch. 1 - Prob. 1.73PCh. 1 - Prob. 1.74PCh. 1 - Prob. 1.75PCh. 1 - Prob. 1.76PCh. 1 - Scenes A and B depict changes in matter at the...Ch. 1 - Prob. 1.78PCh. 1 - Prob. 1.79PCh. 1 - If a temperature scale were based on the freezing...
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- The emission data in cps displayed in Table 1 is reported to two decimal places by the chemist. However, the instrument output is shown in Table 2. Table 2. Iron emission from ICP-AES Sample Blank Standard Emission, cps 579.503252562 9308340.13122 Unknown Sample 343.232365741 Did the chemist make the correct choice in how they choose to display the data up in Table 1? Choose the best explanation from the choices below. No. Since the instrument calculates 12 digits for all values, they should all be kept and not truncated. Doing so would eliminate significant information. No. Since the instrument calculates 5 decimal places for the standard, all of the values should be limited to the same number. The other decimal places are not significant for the blank and unknown sample. Yes. The way Saman made the standards was limited by the 250-mL volumetric flask. This glassware can report values to 2 decimal places, and this establishes our number of significant figures. Yes. Instrumental data…arrow_forwardSteps and explanation pleasearrow_forwardSteps and explanation to undertand concepts.arrow_forward
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