
Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Chapter 1, Problem 1.43P
Interpretation Introduction
Interpretation:Rule that states that zeroes are significant should be determined.
Concept introduction:Significant figures refer toeach digit in any number that is used to write specific number to desired accuracy. These figures include all non-zero digits available in number system. More the number of significant figures, higher will be the accuracy and certainty in measurement of particular number.
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Given the equilibrium A2 + B2 ⇌ 2 AB where k1 is the rate coefficient of the forward reaction and k-1 is the rate coefficient of the reverse reaction, with the forward reaction being first-order in A2 and B2, and the reverse reaction being second-order in AB. Equilibrium will be reached later if the relative values of the constants are:(A) k1 high and k-1 high(B) k1 high and k-1 low(C) k1 low and k-1 high(D) k1 low and k-1 low
A 2-step reaction has the following mechanism:
|
1. (fast) R2
R+R
2. (slow) R+Q
K₂ P
k_1
What series does it have?
(A). v=
-
= (k + k1 − k-1)[R2][Q]
(B). v=-k₁[R₂] + k₁[R]² - k₂[R][Q]
(C). v=k₂[R]²[Q]²
(D). v = k[R₂]1/2[Q]
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
Chapter 1 Solutions
Principles of General Chemistry
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