Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Chapter 1, Problem 1.36P
Interpretation Introduction
Interpretation:The length of animalcules in meters is to be determined.
Concept introduction:Conversion factor is ratio that is widely used to describe relation between two different units. In order to convert one unit into another, original unit is multiplied with proper conversion factor to yield new unit. This is done as mentioned below.
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Given the equilibrium A2 + B2 ⇌ 2 AB where k1 is the rate coefficient of the forward reaction and k-1 is the rate coefficient of the reverse reaction, with the forward reaction being first-order in A2 and B2, and the reverse reaction being second-order in AB. Equilibrium will be reached later if the relative values of the constants are:(A) k1 high and k-1 high(B) k1 high and k-1 low(C) k1 low and k-1 high(D) k1 low and k-1 low
A 2-step reaction has the following mechanism:
|
1. (fast) R2
R+R
2. (slow) R+Q
K₂ P
k_1
What series does it have?
(A). v=
-
= (k + k1 − k-1)[R2][Q]
(B). v=-k₁[R₂] + k₁[R]² - k₂[R][Q]
(C). v=k₂[R]²[Q]²
(D). v = k[R₂]1/2[Q]
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
Chapter 1 Solutions
Principles of General Chemistry
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Ch. 1 - Prob. 1.11PCh. 1 - Prob. 1.12PCh. 1 - Prob. 1.13PCh. 1 - Write the conversion factor(s) for in2tom2 (b)...Ch. 1 - Write the conversion factor(s) for cm/mintoin/ (b)...Ch. 1 - Describe the difference between intensive and...Ch. 1 - Explain the difference between mass and weight....Ch. 1 - For each of the following cases, state whether the...Ch. 1 - Prob. 1.19PCh. 1 - A one-step conversion is sufficient to convert a...Ch. 1 - The average radius of a molecule of lysozyme, an...Ch. 1 - The radius of a barium atom is 2.2210-10 m. What...Ch. 1 - A small hole in the wing of a space shuttle...Ch. 1 - Prob. 1.24PCh. 1 - The average density of Earth is 5.5g/cm3. What is...Ch. 1 - Prob. 1.26PCh. 1 - The volume of a certain bacterial cell is 2.56m3....Ch. 1 - How many cubic meters of milk are in 1qt(946.4mL)?...Ch. 1 - Prob. 1.29PCh. 1 - An empty Erlenmeyer flask weighs 241.3 g. When...Ch. 1 - A small cube of aluminum measures 15.6 mm on a...Ch. 1 - A steek ball-bearing with a circumference of 32.5...Ch. 1 - Perform the following conversions: 68oF (a...Ch. 1 - Perfrom the following conversions: 106oF (the body...Ch. 1 - A 25-0-g sample of each of three unknwon metals is...Ch. 1 - Prob. 1.36PCh. 1 - The distance between two adjacent peaks on a wave...Ch. 1 - Prob. 1.38PCh. 1 - Prob. 1.39PCh. 1 - Prob. 1.40PCh. 1 - Each of the beakers depicted below contains two...Ch. 1 - Prob. 1.42PCh. 1 - Prob. 1.43PCh. 1 - Underline the significant zeros in the folliwng...Ch. 1 - Prob. 1.45PCh. 1 - Carry out the following calculations, making sure...Ch. 1 - Carry out the following calculations, making sure...Ch. 1 - Prob. 1.48PCh. 1 - Write the following numbers in scientific...Ch. 1 - Prob. 1.50PCh. 1 - Prob. 1.51PCh. 1 - Carry out each calculation, paying special...Ch. 1 - Carry out each calculation, paying special...Ch. 1 - Which statements include excat numbers? Angel...Ch. 1 - Which of the following include exact numbers? (a)...Ch. 1 - How long is the metal strip shown below? Be sure...Ch. 1 - These organic solvents are used to clean compact...Ch. 1 - Prob. 1.58PCh. 1 - Prob. 1.59PCh. 1 - Prob. 1.60PCh. 1 - Prob. 1.61PCh. 1 - Prob. 1.62PCh. 1 - Prob. 1.63PCh. 1 - Prob. 1.64PCh. 1 - Prob. 1.65PCh. 1 - Bromine is used to prepare the pesticide methyl...Ch. 1 - Prob. 1.67PCh. 1 - Prob. 1.68PCh. 1 - Prob. 1.69PCh. 1 - Prob. 1.70PCh. 1 - Prob. 1.71PCh. 1 - For the year 2007. worldwide production of...Ch. 1 - Prob. 1.73PCh. 1 - Prob. 1.74PCh. 1 - Prob. 1.75PCh. 1 - Prob. 1.76PCh. 1 - Scenes A and B depict changes in matter at the...Ch. 1 - Prob. 1.78PCh. 1 - Prob. 1.79PCh. 1 - If a temperature scale were based on the freezing...
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