
Concept explainers
a)
Interpretation:Average mass for below sets of measurements is to be identified.
Concept introduction:Any test, trial or tentative procedure that is executed under highly controlled conditions whose purpose is to examine validity of any hypothesis is called an experiment. These are also performed so as to discover unknown things in nature.
The extent to which calculated or measured values are close to standard one is called accuracy.
a)

Answer to Problem 1.58P
Average mass of set I is
Average mass of set II is
Average mass of set III is
Average mass of set IV is
Set I and set II are the most accurate.
Explanation of Solution
The formula to calculate the average mass is as follows:
The value of
The value of
The value of
Substitute the values in above equation to calculate average mass for set I.
The value of
The value of
The value of
Substitute the values in above equation to calculate average mass for set II.
The value of
The value of
The value of
Substitute the values in above equation to calculate average mass for set III.
The value of
The value of
The value of
Substitute the values in above equation to calculate average mass for set IV.
Since set I and set II have values equal to that of standard value
b)
Interpretation:Among below sets of measurements, the most precise set should be determined. Also, whether this set is the most accurate or not should be determined.
Concept introduction:The extent to which calculated or measured values are close to standard one is called accuracy.The closeness of measurements with each other is termed as precision. It determines the extent to which measurements are close to each other.
b)

Explanation of Solution
Precision is determined by range of data. The formula to calculate range is as follows:
The largest value is
The smallest value is
Substitute the values in above equation for range of set I.
The largest value is
The smallest value is
Substitute the values in above equation for range of set II.
The largest value is
The smallest value is
Substitute the values in above equation for range of set III.
The largest value is
The smallest value is
Substitute the values in above equation for range of set IV.
Since range of set III comes out to be the least among all sets of measurements, it is the most precise measurement. But value of its average mass is quite different from that of standard value; it is not the most accurate measurement.
c)
Interpretation:Among below sets of measurements, set that is the most accurate and the most precise should be determined.
Concept introduction:The extent to which calculated or measured values are close to standard one is called accuracy. The closeness of measurements with each other is termed as precision. It determines the extent to which measurements are close to each other.
c)

Explanation of Solution
Average value of set I match with that of standard value and its range is quite low so it is the most accurate and most precise set of measurement.
d)
Interpretation:Among below sets of measurements, set that is the least accurate and the least precise should be determined.
Concept introduction:The extent to which calculated or measured values are close to standard one is called accuracy. The closeness of measurements with each other is termed as precision. It determines the extent to which measurements are close to each other.
d)

Explanation of Solution
Average value of set I differs highly from standard value and its range is maximum so it is the least accurate and least precise set of measurement.
Want to see more full solutions like this?
Chapter 1 Solutions
Principles of General Chemistry
- Q4: Write organic product(s) of the following reactions and show the curved-arrow mechanism of the reactions. Br MeOH OSO2CH3 MeOHarrow_forwardProvide the correct IUPAC name for the compound shown here. Reset cis- 5- trans- ☑ 4-6- 2- 1- 3- di iso tert- tri cyclo sec- oct but hept prop hex pent yl yne ene anearrow_forwardQ6: Predict the major product(s) for the following reactions. Note the mechanism (SN1, SN2, E1 or E2) the reaction proceeds through. If no reaction takes place, indicate why. Pay attention to stereochemistry. NaCN DMF Br σ Ilm... Br H Br H H NaCN CH3OH KOtBu tBuOH NaBr H₂O LDA Et2O (CH3)2CHOH KCN DMSO NaOH H₂O, A LDA LDA Systemarrow_forward
- Q7: For the following reactions, indicate the reaction conditions that would provide the indicated product in a high yield. Note the major reaction pathway that would take place (SN1, SN2, E1, or E2) Note: There may be other products that are not shown. There maybe more than one plausible pathway. Br H3C OH H3C CI ... H3C SCH2CH3 CI i SCH2CH3 ཨ་ Br System Settarrow_forwardQ2: Rank the compounds in each of the following groups in order of decreasing rate of solvolysis in aqueous acetone. OSO2CF3 OSO2CH3 OH a. b. CI Brarrow_forwardох 4-tert-butyl oxy cyclohex-1-ene Incorrect, 1 attempt remaining The systematic name of this compound classifies the -OR group as a substituent of the hydrocarbon, which is considered the principal functional group. The ether substituent is named with the suffix 'oxy'. The general format for the systematic name of a hydrocarbon is: [prefix/substituent] + [parent] + [functional group suffix] Substituents are listed in alphabetical order. Molecules with a chiral center will indicate the absolute configuration at the beginning of its name with the R and S notation.arrow_forward
- 5. Compressibility (6 points total). The isothermal compressibility is a measure of how hard/easy it is to compress an object (how squishy is it?) at constant temperature. It is др defined as Br=-()=-(200²)T' (a) You might wonder why there is a negative sign in this formula. What does it mean when this quantity is positive and what does it mean when this quantity is negative? (b) Derive the formula for the isothermal compressibility of an ideal gas (it is very simple!) (c) Explain under what conditions for the ideal gas the compressibility is higher or lower, and why that makes sense.arrow_forward19. (3 pts) in Chapter 7 we will see a reaction of halocyclohexanes that requires that the halogen occupy an axial position with this in mind, would you expect cis-1-bromo-3-methylcyclohexane or trans-1-bromo-3-methylcyclohexane to be more reactive in this reaction? Briefly explain your choice using structures to support your answer. Mere-eries-cecleone) The tran-i-browse-3-methylcyclohexionearrow_forwardPlease help me calculate the undiluted samples ppm concentration. My calculations were 280.11 ppm. Please see if I did my math correctly using the following standard curve. Link: https://mnscu-my.sharepoint.com/:x:/g/personal/vi2163ss_go_minnstate_edu/EVSJL_W0qrxMkUjK2J3xMUEBHDu0UM1vPKQ-bc9HTcYXDQ?e=hVuPC4arrow_forward
- Provide an IUPAC name for each of the compounds shown. (Specify (E)/(Z) stereochemistry, if relevant, for straight chain alkenes only. Pay attention to commas, dashes, etc.) H₁₂C C(CH3)3 C=C H3C CH3 CH3CH2CH CI CH3 Submit Answer Retry Entire Group 2 more group attempts remaining Previous Nextarrow_forwardArrange the following compounds / ions in increasing nucleophilicity (least to most nucleophilic) CH3NH2 CH3C=C: CH3COO 1 2 3 5 Multiple Choice 1 point 1, 2, 3 2, 1, 3 3, 1, 2 2, 3, 1 The other answers are not correct 0000arrow_forwardcurved arrows are used to illustrate the flow of electrons. using the provided starting and product structures, draw the cured electron-pushing arrows for thw following reaction or mechanistic steps. be sure to account for all bond-breaking and bond making stepsarrow_forward
- General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning

