Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Textbook Question
Chapter 1, Problem 1.21P
Identify the atom that has each ground-state electron configuration.
- (a) 1s2 2s2 2p6 3s2 3p4
- (b) 1s2 2s2 2p4
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(a) Identify the following neutral elements by their condensed electron configurations. (Enter the chemical symbol or name of the element.)
(i) [Ar] 4s2 3d3 (ii) [Kr] 5s2 4d10 5p3 (iii) [Ar] 4s2 3d10 4p4
Write the ground-state electron configuration for each atom. After each atom is its atomic number in parentheses.
(a) Sodium (11) (b) Magnesium (12) (c) Oxygen (8) (d) Nitrogen (7)
2) What is the electron geometry of the indicated atoms?
A-
C
D
Atom A =
Atom B =
Atom C =
Atom D =
B
Chapter 1 Solutions
Organic Chemistry
Ch. 1.1 - Prob. 1.1PCh. 1.2 - Prob. 1.2PCh. 1.2 - Judging from their relative positions in the...Ch. 1.2 - Classify each bond as nonpolar covalent or polar...Ch. 1.2 - Using the symbols and +, indicate the direction...Ch. 1.2 - Draw Lewis structures showing all valence...Ch. 1.2 - Draw Lewis structures for these ions and show...Ch. 1.3 - Draw Lewis structures and condensed structural...Ch. 1.3 - Prob. 1.9PCh. 1.3 - Prob. 1.10P
Ch. 1.3 - Prob. 1.11PCh. 1.3 - Prob. 1.12PCh. 1.4 - Predict all bond angles for these molecules. (a)...Ch. 1.5 - The geometry of carbon in diamond is tetrahedral,...Ch. 1.5 - Because of their spherical shape, C60 molecules...Ch. 1.5 - What best describes the CCC bond angles in C60? 1....Ch. 1.5 - Prob. 1.14PCh. 1.7 - Describe the bonding in these molecules in terms...Ch. 1.8 - Prob. 1.16PCh. 1.8 - Prob. 1.17PCh. 1.8 - Prob. 1.18PCh. 1.9 - Draw three contributing structures of the...Ch. 1.9 - What is the hybridization state of the circled...Ch. 1.9 - The molecule shown on the right in the example in...Ch. 1.9 - Prob. CQCh. 1.9 - The following structure is called imidazolium....Ch. 1 - Write the ground-state electron configuration for...Ch. 1 - Identify the atom that has each ground-state...Ch. 1 - Define valence shell and valence electron.Ch. 1 - How many electrons are in the valence shell of...Ch. 1 - Prob. 1.24PCh. 1 - Prob. 1.25PCh. 1 - Prob. 1.26PCh. 1 - Write Lewis structures for these compounds. Show...Ch. 1 - Write Lewis structures for these ions. Show all...Ch. 1 - Prob. 1.29PCh. 1 - Some of these structural formulas are incorrect...Ch. 1 - Following the rule that each atom of carbon,...Ch. 1 - Following are several Lewis structures showing all...Ch. 1 - Which statements are true about electronegativity?...Ch. 1 - Why does fluorine, the element in the upper right...Ch. 1 - Arrange the single covalent bonds within each set...Ch. 1 - Using the values of electronegativity given in...Ch. 1 - Prob. 1.37PCh. 1 - Use VSEPR to predict bond angles about each...Ch. 1 - Use VSEPR to predict bond angles about each atom...Ch. 1 - Use VSEPR to predict the geometry of these ions....Ch. 1 - Prob. 1.41PCh. 1 - Prob. 1.42PCh. 1 - What is the meaning of the term tertiary (3) when...Ch. 1 - What is the meaning of the term tertiary (3) when...Ch. 1 - Draw structural formulas for (a) The four primary...Ch. 1 - Draw structural formulas for the three tertiary...Ch. 1 - Prob. 1.47PCh. 1 - Identify the functional groups in each compound.Ch. 1 - Draw a three-dimensional representation for each...Ch. 1 - Tetrafluoroethylene, C2F4, is the starting...Ch. 1 - Which statements are true about resonance...Ch. 1 - Prob. 1.52PCh. 1 - Prob. 1.53PCh. 1 - Prob. 1.54PCh. 1 - Are the structures in each set valid contributing...Ch. 1 - State the orbital hybridization of each...Ch. 1 - Describe each highlighted bond in terms of the...Ch. 1 - Following is a structural formula of the...Ch. 1 - Draw a Lewis structure for methyl isocyanate,...Ch. 1 - What is the hybridization of the highlighted atoms...Ch. 1 - Using cartoon representations, draw a molecular...Ch. 1 - In what kind of orbitals do the lone-pair...Ch. 1 - Draw the delocalized molecular orbitals for the...Ch. 1 - Prob. 1.64APCh. 1 - Each compound contains both ions and covalent...Ch. 1 - Predict whether the carbon-metal bond in these...Ch. 1 - Prob. 1.67APCh. 1 - Phosphorus is immediately under nitrogen in the...Ch. 1 - Draw a Lewis structure for the azide ion, N3. (The...Ch. 1 - Cyanic acid, HOCN, and isocyanic acid, HNCO,...Ch. 1 - In Chapter 6, we study a group of organic cations...Ch. 1 - Many reactions involve a change in hybridization...Ch. 1 - Following is a structural formula of benzene,...Ch. 1 - Following are three contributing structures for...Ch. 1 - (a) Draw a Lewis structure for the ozone molecule,...Ch. 1 - The following two compounds are isomers; that is,...Ch. 1 - In future chapters, we will encounter...Ch. 1 - Prob. 1.78AP
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- Which species, has the following ground state electron configuration: 1s2 2s2 2p6 3s2 3p6 4s0 3d8 (a) Fe+ (b) Ni (c) Ni2+ (d) Cu2+arrow_forwardIdentify all the possible elements that have the following valence electronic configuration. a) S2d1 T1 A1 b) S2p6 T1 A1arrow_forwardUse the noble-gas notation and write the ground-state electronic configurations of the following ions:(a) Ca2+ (b) Ga3+ (c) Cr3+arrow_forward
- Question 25 of 25 Describe the atomic orbital shown in this picture. +Z A) 2dxy B) 3dyz C) 3dху +y D) 3dx²-y? +X E) 4dyzarrow_forwardQ25. Identify the following atoms or ions from their electron configurations: (a) W: 1s 2 2s 2 2p6 3s 2 3p6 4s 2 3d10 4p6,5s1 (b) X-: 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 (c) Y++: 1s2 2s2 2p6 3s 2 3p6 4s 2 3d10 4p6 5s2 4d10 5p6 (d) Z: 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f 11arrow_forwardUsing complete subshell notation (1s^22s^22p^6, and so forth), predict the electron configurations of the following ions. (a) N3– (b) Ca2+ (c) S– (d) Cs2+ (e) Cr2+ (f) Gd3+arrow_forward
- part 1: Given an electron configuration: 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p5 Give the electron configuration of the most stable ion of this element: ???????? part 2: Given an electron configuration: 1s2 2s2 2p6 3s2 3p6 4s2 3d10 Give the electron configuration of the most stable ion of this element: ???????? Please answer part 1 and part 2. Thank youarrow_forwardThe electron configuration of a cation M3+ is [Ar] 3d3. What is the electron configuration of the original atom M? (M is not a real chemical symbol of an element.) (A) [Ar] 4s1 3d5 (B) [Ar] 4s2 3d4 (C) [Ar] 3d6 (D) [Ar] 3d4 4p2arrow_forward(2) In which do we find only electron sharing? a) NO2 b) NaNO3 c) AsH3 d) CaO e) HBr f) Cl2 g) CuCl2 (3) Which are diatomic? a) NO2 b) CuCl2 c) HBr d) CaO e) AsH3 f) Cl2 g) NaNO3arrow_forward
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