EBK GENERAL CHEMISTRY11th EditionBissonnette Publisher: VSTISBN: 9780133400588
EBK GENERAL CHEMISTRY
Solutions for EBK GENERAL CHEMISTRY
Problem 2E:
Explain why it is necessary to hybridize atomic orbitals when applying the valence bond method-that...Problem 3E:
Describe the molecular geometry of H2O suggested by each of the following methods: (a) Lewis theory;...Problem 4E:
Describe the molecular geometry of NH2 suggested by each of the following methods: (a) Lewis theory;...Problem 5E:
In which of the following, CO32-,SO2,CCl4,CO,NO3- , would you expect to find sp2 hybridization of...Problem 6E:
In the manner of Example 11-1, describe the probable structure and bonding in (a) Hl; (b) BrCl; (c)...Problem 7E:
For each of the following species, identify the central atom(s) and propose a hybridization scheme...Problem 8E:
Propose a plausible Lewis structure, geometric structure, and hybridization scheme for the ONF...Problem 9E:
Describe a hybridization scheme for the central Cl atom in the molecule CIF: that is consistent with...Problem 10E:
Describe a hybridization scheme for the central S atom in the molecule SFO that is consistent with...Problem 11E:
Match each of the following species with one of these hybridization schemes: sp, sp2 , sp3 , sp3d ,...Problem 12E:
Propose a hybridization scheme to account for bonds formed by the central carbon atom in each of the...Problem 13E:
Indicate which of the following molecules and ions are linear, which are planar, and which are...Problem 14E:
In the manner of Figure 11-18, indicate the structures of the following molecules in terms of the...Problem 15E:
Write Lewis structures for the following molecules, and then label each and bond. (a) HCN;(b) C2N2...Problem 16E:
Represent bonding in the carbon dioxide molecule, CO2 by (a) a Lewis structure and (b) the...Problem 17E:
Use the method of Figure 11-19 to represent bonding in each of the following molecules: (a) CCI4 ;...Problem 18E:
Use the method of Figure 11-19 to represent bonding in each of the following ions: (a) NO3 ; (b) I3...Problem 19E:
The molecular model below represents citric acid, an acidic component of citrus juices. Represent...Problem 20E:
Malic is e common organic acid found in unripe apples and other fruit. the help of the molecular...Problem 21E:
Shown below are ball-and-stick models. Describe hybridization and orbital-overlap schemes consistent...Problem 22E:
Shown below are ban-and-stick models. Describe hybridization and orbital-overlap schemes consistent...Problem 24E:
The structure of the molecule allene, CH2CCH2 , is shown here. Propose hybridization schemes for the...Problem 25E:
Angelic acid, shown below, occurs in symbol root, a herb used as a stimulant. Represent the bonding...Problem 26E:
Dimethylolpropionic acid, shown below, is used in the preparation of resins. Represent the bonding...Problem 27E:
Explain the essential difference in how the valence-bond method and molecular orbital theory...Problem 28E:
Describe the bond order of diatomic carbon, C2 , with Lewis theory and molecular orbital theory, and...Problem 30E:
The paramagnetism of gaseous B2 has been established. Explain how this observation confirms that the...Problem 32E:
Is it correct to say that when a diatomic molecule loses an electron, the bond energy always...Problem 33E:
For the following pairs of molecular orbitals, indicate the one you expect to have the lower energy,...Problem 34E:
For each of the species C2+,O2,F2+ , and NO+ ; a. Write the molecular orbital occupancy diagram (as...Problem 35E:
Write plausible molecular orbital occupancy diagrams for the following heteronuclear diatomic...Problem 36E:
We have used the term “isoelectronic” to refer to atoms with identical electron configurations. In...Problem 37E:
Consider the molecules NO+ and N2+ and use molecular orbital theory to answer the following: Write...Problem 38E:
Consider the molecules CO+ and CN- and use molecular orbital theory to answer the following Write...Problem 39E:
Construct the molecular orbital diagram for CF. Would you expect the bond length of CF+ to be longer...Problem 40E:
Construct the molecular orbital diagram for SrCl. Would you expect the bond length of SrCI+ to be...Problem 41E:
Explain why the concept of delocalized molecular orbitals is essential to an understanding of...Problem 42E:
Explain how it is possible to avoid the concept of resonance by using molecular orbital theory.Problem 43E:
In which of the following molecules would you expect to find delocalized molecular orbitals'...Problem 44E:
In which of the following ions would you expect to find delocalized molecular orbitals? Explain. (a)...Problem 45IAE:
The Lewis structure of N2 indicates that the nitrogen-to-nitrogen bond is a triple covalent bond....Problem 46IAE:
Show that both the valence bond method and molecular orbital theory provide an explanation for the...Problem 47IAE:
A group of spectroscopists believe that they have detected one of the following species: NeF, NeF+ ,...Problem 48IAE:
Lewis theory is satisfactory to explain bonding in the ionic compound K2O1 , but it does not readily...Problem 49IAE:
The compound potassium sesquoxide has the empirical formula K2O2 . Show that this compound tan be...Problem 50IAE:
Draw a Lewis structure for the urea molecule, CO( NH2)2 , and predict its geometric shape with the...Problem 51IAE:
Methyl nitrate, CH2NO2 , is used as a rocket propellant. The skeletal structure of the molecule is...Problem 52IAE:
Fluorine nitrate, FONO2 , is an oxidizing agent used as a rocket propellant. A reference source...Problem 53IAE:
Draw a Lewis structure(s) for the nitrite ion, NO2 . Then propose a bonding scheme to describe the ...Problem 54IAE:
Think of the reaction shown here as involving the transfer of a fluoride ion from ClF2 to AsF5 , to...Problem 57IAE:
The molecule formamide, HCONH2 , has the approximate bond angles H-C-O, 123o; H-C-N, 113o; N-C-O,...Problem 58IAE:
Pyridine, C2H2N , is used in the synthesis of vitamins and drugs. The molecule can be thought of in...Problem 60IAE:
The ion F2Cl is linear, but the ion F2Cl+ is bent. Describe hybridization schemes for the central CI...Problem 65IAE:
Histidine, an essential amino acid, serves as a part of the active center in many enzymes. It is the...Problem 66IAE:
The anion I42 is linear, and the anion I5 is V-shaped, with a 95° angle between the two arms of the...Problem 68IAE:
A conjugated hydrocarbon has an alternation of double and single bonds. Draw the molecular orbitals...Problem 69IAE:
An elusive intermediate of atmospheric reactions of HONO may be nitrosyl O-hydroxide, HOON....Problem 70FP:
Resonance energy is the difference in energy between a real molecule—a resonance hybrid—and its most...Problem 71FP:
Furan, C4H4O , is a substance derivable from oat hulls, corn cobs, and other cellulosic waste. It is...Problem 72FP:
As discussed in Are You Wondering 11-1, the sp hybrid orbitals are algebraic combinations of the s...Problem 73FP:
In Chapter 10, we saw that electronegativity differences determine whether bond dipoles exist in a...Problem 74FP:
Borazine, B2N2H2 is often referred to as inorganic benzene because of its similar structure. Like...Problem 75FP:
Which of the following combinations of orbitals give rise to bonding molecular orbitals? For those...Problem 79SAE:
Explain the important distinctions between the terms in each of the following pairs: (a) and p...Problem 80SAE:
A molecule in which sp2 hybrid orbitals are used by the central atom in forming covalent bonds is...Problem 82SAE:
The hybridization scheme for the central atom includes a d orbital contribution in (a) I3- ; (b)...Problem 83SAE:
Of the following, the species with a bond order of 1 is (a) H2+ ; (b) Li2 ; (c) He2 ; (d) H2 .Problem 87SAE:
Why does the hybridization sp2d not account for bonding in the molecule BrF5 ? What hybridization...Problem 89SAE:
Which of the following species are paramagnetic? (a) B2 ; (b) B2 ;(c) B2+. Which species has the...Problem 90SAE:
Use the valence molecular orbital configuration to determine which of the following species is...Problem 91SAE:
Use the valence molecular orbital configuration to determine which of the following species is...Problem 92SAE:
Which of these diatomic molecules do you think has the greater bond energy, Li2 or C2 ? Explain?Problem 93SAE:
For each of the following ions or molecules, decide whether the structure is best described by a...Problem 94SAE:
Draw Lewis structures for the NO2 and NO2+ ions, and determine the geometry for each by using VSEPR...Problem 95SAE:
In which of the following is the central atom sp hybridized? (a) BeCl2 ; (b) BCl2 ; (c) CCl2 ; (d)...Problem 97SAE:
According to molecular orbital theory, the O22 ion has which of the following? (a) two unpaired...Problem 98SAE:
What is the angle between the hybrid orbitals obtained by combining the 2s and two 2p orbitals of an...Browse All Chapters of This Textbook
Chapter 1 - Matter: Its Properties And MeasurementChapter 2 - Atoms And The Atomic TheoryChapter 3 - Chemical CompoundsChapter 4 - Chemical ReactionsChapter 5 - Introduction To Reactions In Aqueous SolutionsChapter 6 - GasesChapter 7 - ThermochemistryChapter 8 - Electrons In AtomsChapter 9 - The Periodic Table And Some Atomic PropertiesChapter 10 - Chemical Bonding I: Basic Concepts
Chapter 11 - Chemical Bonding Ii: Valence Bond And Molecular Orbital TheoriesChapter 12 - Intermolecular Forces: Liquids And SolidsChapter 13 - Spontaneous Change: Entropy And Gibbs EnergyChapter 14 - Solutions And Their Physical PropertiesChapter 15 - Principles Of Chemical EquilibriumChapter 16 - Acids And BasesChapter 17 - Additional Aspects Of Acid–base EquilibriaChapter 18 - Solubility And Complex-ion EquilibriaChapter 19 - ElectrochemistryChapter 20 - Chemical KineticsChapter 21 - Chemistry Of The Main-group Elements I: Groups 1, 2, 13, And 14Chapter 22 - Chemistry Of The Main-group Elements Ii: Groups 18, 17, 16, 15, And HydrogenChapter 23 - The Transition ElementsChapter 24 - Complex Ions And Coordination CompoundsChapter 25 - Nuclear ChemistryChapter 26 - Structures Of Organic CompoundsChapter 27 - Reactions Of Organic Compounds
Sample Solutions for this Textbook
We offer sample solutions for EBK GENERAL CHEMISTRY homework problems. See examples below:
Chapter 1, Problem 1EChapter 2, Problem 1EChapter 3, Problem 1EChapter 4, Problem 1EChapter 5, Problem 1EChapter 6, Problem 1EChapter 7, Problem 1EChapter 8, Problem 1EFrom periodic table and from the given data table, element having atomic number 114 will be in the...
Chapter 10, Problem 1ELewis theory and valence bond theoryexplainabout covalent bonding. But the main difference is that...Chapter 12, Problem 1EGiven information: Number of particles = 5 1D box length = L When the length of the box is increased...Chapter 14, Problem 1EChapter 15, Problem 1EChapter 16, Problem 1EChapter 17, Problem 1EChapter 18, Problem 1EChapter 19, Problem 1EChapter 20, Problem 1ECesium metal is an alkali metal and it has the tendency to form a monovalent cation, namely Cs+...Chapter 22, Problem 1EChapter 23, Problem 1EThe complex has Cr3+ as the central ion and two NH3 molecules and four Cl- ions as ligands...In β− emission, an electron is emitted from the nucleus. The given nucleus is 2655Fe here, atomic...There is a difference between structural formula and condensed formula. The formula which represents...Chapter 27, Problem 1E
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