Bundle: Chemistry: Principles and React...8th EditionWilliam L. Masterton, Cecile N. Hurley Publisher: Cengage LearningISBN: 9781305717497
Bundle: Chemistry: Principles and React...
Solutions for Bundle: Chemistry: Principles and Reactions, 8th, Loose-Leaf + OWLv2, 1 term (6 months) Printed Access Card
Problem 1QAP:
The following data are for the system A(g)2B(g) (a) How long does it take the system to reach...Problem 2QAP:
The following data are for the system A(g)2B(g) (a) How long does it take the system to reach...Problem 5QAP:
Write the equilibrium expressions (K) for the following reactions: (a) CH4(g)+H2O(l)CO(g)+3H2(g) (b)...Problem 6QAP:
Write the equilibrium expressions (K) for the following reactions: (a) Na2CO3(s)2NaO(s)+CO2(g) (b)...Problem 8QAP:
Write the equilibrium expressions (K) for the following reactions: (a) I2(s)+2Cl(g)Cl2(g)+2 I(aq)...Problem 9QAP:
Given the following descriptions of reversible reactions, write a balanced equation (smallest...Problem 10QAP:
Given the following descriptions of reversible reactions, write a balanced net ionic equation...Problem 11QAP:
Write an equation for an equilibrium system that would lead to the following expressions (ac) for K....Problem 12QAP:
Write a chemical equation for an equilibrium system that would lead to the following expressions...Problem 13QAP:
Consider the following reaction at 250C: A(s)+2B(g)C(s)+2D(g) (a) Write an equilibrium constant...Problem 14QAP:
Consider the following reaction at 1000 C: NO(g)+12 Cl2(g)NOCl(g) (a) Write an equilibrium constant...Problem 15QAP:
At 627C, K=0.76 for the reaction 2SO2(g)+O2(g)2SO3(g) Calculate K at 627C for (a) the synthesis of...Problem 16QAP:
At 800C, K=2.2104 for the following reaction 2H2S(g)2H2(g)+S2(g) Calculate K at 8000C for (a) the...Problem 18QAP:
Given the following data at 25C 2NO(g)N2(g)+O2(g)K=1 10 30 2NO(g)+Br2(g)2NOBr(g)K=8 101 Calculate K...Problem 20QAP:
Consider the following hypothetical reactions and their equilibrium constants at 75C,...Problem 21QAP:
When one mole of carbon disulfide gas reacts with hydrogen gas, methane and hydrogen sulfide gases...Problem 22QAP:
Calculate K for the formation of methyl alcohol at 100C: CO(g)+2H2(g)CH3OH(g) given that at...Problem 23QAP:
Ammonium carbamate solid (NH4CO2NH2) decomposes at 313 K into ammonia and carbon dioxide gases. At...Problem 24QAP:
Consider the decomposition at 25C of one mole of NOBr gas into NO and Br2 gases. At equilibrium, the...Problem 25QAP:
Consider the decomposition of ammonium hydrogen sulfide: NH4HS(s)NH3(g)+H2S(g) In a sealed flask at...Problem 26QAP:
A sealed flask has 0.541 atm of SO3 at 1000 K. The following equilibrium is established....Problem 27QAP:
A gaseous reaction mixture contains 0.30 atm SO2, 0.16 atm Cl2, and 0.50 atm SO2Cl2 in a 2.0-L...Problem 28QAP:
For the system PCl5(g)PCl3(g)+Cl2(g)K is 26 at 300C. In a 1.0-L flask at 300C, a gaseous mixture...Problem 29QAP:
The reversible reaction between hydrogen chloride gas and one mole of oxygen gas produces steam and...Problem 30QAP:
The reversible reaction between hydrogen chloride gas and one mole of oxygen gas produces steam and...Problem 31QAP:
A compound, X, decomposes at 131C according to the following equation: 2X(g)A(g)+3C(g)K=1.1103 If a...Problem 32QAP:
Consider the following reaction at 75C: 3R(s)+2Q(g)A(g)+5B(l)K=9.4 A 10.0-L sample contains 0.30 mol...Problem 33QAP:
Consider the reaction between nitrogen and steam: 2N2(g)+6H2O(g)4NH3(g)+3O2(g)At a certain...Problem 34QAP:
At 500C, k for the for the formation of ammonia from nitrogen and hydrogen gases is 1.5105....Problem 35QAP:
At a certain temperature, K is 4.9 for the formation of one mole of bromine chloride gas (BrCl) from...Problem 36QAP:
At a certain temperature, K=0.29 for the decomposition of two moles of iodine trichloride, ICl3(s),...Problem 37QAP:
For the reaction N2(g)+2H2O(g)2NO(g)+2H2(g) K is 1.54103. When equilibrium is established, the...Problem 38QAP:
Nitrogen dioxide can decompose to nitrogen oxide and oxygen. 2NO2(g)2NO(g)+O2(g) K is 0.87 at a...Problem 39QAP:
Consider the following reaction: N2(g)+O2(g)2NO(g)At a certain temperature, the equilibrium constant...Problem 40QAP:
Consider the hypothetical reaction at 325C R(g)+Q(g)2Z(g)K=2.71 What are the equilibrium partial...Problem 41QAP:
At a certain temperature, the equilibrium constant for the following reaction is 0.0472....Problem 42QAP:
At 460C, the reaction SO2(g)+NO2(g)NO(g)+SO3(g) has K=84.7. All gases are at an initial pressure of...Problem 43QAP:
Solid ammonium iodide decomposes to ammonia and hydrogen gases at sufficiently high temperatures....Problem 44QAP:
Consider the following decomposition at 80C. PH3BCl3(s)PH3(g)+Bcl3(g)K=0.054 Twenty grams of PH3BCl3...Problem 45QAP:
Hydrogen cyanide, a highly toxic gas, can decompose to cyanogen and hydrogen gases,...Problem 46QAP:
At 800 K, hydrogen iodide can decompose into hydrogen and iodine gases. 2HI(g)I2(g)+H2(g) At this...Problem 47QAP:
For the following reactions, predict whether the pressure of the reactants or products increases or...Problem 48QAP:
Follow the directions of Question 47 for the following reactions: (a) 2H2O(l)+O2(g)2H2O2(g) (b)...Problem 49QAP:
Consider the system SO3(g)SO2(g)+12 O2(g)H=98.9kJ (a) Predict whether the forward or reverse...Problem 50QAP:
Consider the system 4NH3(g)+3O2(g)2N2(g)+6H2O(l)H=1530.4kJ (a) How will the amount of ammonia at...Problem 51QAP:
Predict the direction in which each of the following equilibria will shift if the pressure on the...Problem 52QAP:
Predict the direction in which each of the following equilibria will shift if the pressure on the...Problem 53QAP:
At a certain temperature, nitrogen and oxygen gases combine to form nitrogen oxide gas....Problem 54QAP:
Consider the following hypothetical reaction: X2(g)+R(s)X2R(g) R has a molar mass of 73 g/mol. When...Problem 56QAP:
Sulfur oxychloride, SO2Cl2, decomposes to sulfur dioxide and chlorine gases. SO2Cl2(g)SO2(g)+Cl2(g)...Problem 57QAP:
For the following reaction C(s)+2H2(g)CH4(g) K=0.26 at 1000C (3 significant figures). What is the...Problem 58QAP:
For the system 2SO3(g)2SO2(g)+O2(g) K=1.32 at 627. What is the equilibrium constant at 555C?Problem 59QAP:
For a certain reaction, H is +33 kJ. What is the ratio of the equilibrium constant at 400 K to that...Problem 61QAP:
Hemoglobin (Hb) binds to both oxygen and carbon monoxide. When the carbon monoxide replaces the...Problem 62QAP:
Mustard gas, used in chemical warfare in World War I, has been found to be an effective agent in the...Problem 64QAP:
For the decomposition of CaCO3 at 900C, K=1.04. CaCO3(s)CaO(s)+O2(g)Find the smallest mass of CaCO3...Problem 65QAP:
Isopropyl alcohol is the main ingredient in rubbing alcohol. It can decompose into acetone (the main...Problem 66QAP:
Consider the equilibrium H2(g)+S(s)H2S(g)When this system is at equilibrium at 25C in a 2.00-L...Problem 68QAP:
The following data apply to the unbalanced equation A(g)B(g) (a) On the basis of the data, balance...Problem 69QAP:
Consider the reaction: A(g)+2B(g)+C(s)2D(g)At 25C, only A, B, and C are present. The partial...Problem 70QAP:
For the reaction C(s)+CO2(g)2CO(g) K=168 at 1273 K. If one starts with 0.3 atm of CO2 and 12.0 g of...Problem 71QAP:
Consider the system A(g)+2B(g)+C(g)2D(g)at 25C. At zero time, only A, B, and C are present. The...Problem 72QAP:
The graph below is similar to that of Figure 12.2. If after 100 s have elapsed the partial pressure...Problem 74QAP:
The figures below represent the following reaction at equilibrium at different temperatures....Problem 77QAP:
Consider the following reaction at a certain temperature: 2NO(g)+O22NO2(g)A reaction mixture...Problem 79QAP:
Ammonia can decompose into its constituent elements according to the reaction 2NH3(g)N2(g)+3H2(g)The...Problem 80QAP:
Hydrogen iodide gas decomposes to hydrogen gas and iodine gas: 2HI(g)H2(g)+I2(g)To determine the...Problem 81QAP:
For the system SO3(g)SO2(g)+12 O2(g)at 1000 K, K=0.45. Sulfur trioxide, originally at 1.00 atm...Problem 82QAP:
A student studies the equilibrium I2(g)2I(g)at a high temperature. She finds that the total pressure...Problem 83QAP:
At a certain temperature, the reaction Xe(g)+2F2(g)XeF4(g)gives a 50.0% yield of XeF4, starting with...Browse All Chapters of This Textbook
Chapter 1 - Matter And MeasurementsChapter 2 - Atoms, Molecules, And IonsChapter 3 - Mass Relations In Chemistry; StoichiometryChapter 4 - Reactions In Aqueous SolutionChapter 5 - GasesChapter 6 - Electronic Structure And The Periodic TableChapter 7 - Covalent BondingChapter 8 - ThermochemistryChapter 9 - Liquids And SolidsChapter 10 - Solutions
Chapter 11 - Rate Of ReactionChapter 12 - Gaseous Chemical EquilibriumChapter 13 - Acids And BasesChapter 14 - Equilibria In Acid-base SolutionsChapter 15 - Complex Ion And Precipitation EquilibriaChapter 16 - Spontaneity Of ReactionChapter 17 - ElectrochemistryChapter 18 - Nuclear ReactionsChapter 19 - Complex IonsChapter 20 - Chemistry Of The MetalsChapter 21 - Chemistry Of The NonmetalsChapter 22 - Organic ChemistryChapter 23 - Organic Polymers, Natural And Synthetic
Sample Solutions for this Textbook
We offer sample solutions for Bundle: Chemistry: Principles and Reactions, 8th, Loose-Leaf + OWLv2, 1 term (6 months) Printed Access Card homework problems. See examples below:
Chapter 1, Problem 1QAPChapter 1, Problem 27QAPChapter 1, Problem 28QAPChapter 2, Problem 1QAPChapter 2, Problem 27QAPChapter 2, Problem 28QAPChapter 2, Problem 36QAPChapter 2, Problem 37QAPChapter 2, Problem 38QAP
Given structural formula- In above structural formula, CH3 group is attached with acetic acid group...Methane is a member of Alkane family that has only 1 carbon atom and general formula for molecular...Chemical name of molecule = silicon disulfide In this chemical compound: Least electronegative atom...Potassium and strontium are metals. Potassium is present in group 1 known as alkali metal group in...Chapter 3, Problem 1QAPChapter 3, Problem 13QAPChapter 3, Problem 18QAPChapter 3, Problem 25QAPChapter 3, Problem 47QAPChapter 3, Problem 48QAPChapter 3, Problem 51QAPChapter 3, Problem 52QAPChapter 3, Problem 74QAPChapter 3, Problem 94QAPChapter 4, Problem 1QAPChapter 4, Problem 7QAPChapter 4, Problem 8QAPChapter 4, Problem 9QAPChapter 4, Problem 10QAPChapter 4, Problem 63QAPChapter 4, Problem 74QAPVolume of a gas in a container is equal to the volume of the container. Conversion factor for gallon...The force exerted by gas over a unit surface of area is called pressure of gas. The expression of...As per the given table we have to find the moles and grams of propane gas. First let us calculate...The gas 1 is taken as CO2 and gas 2 as H2 . For both the gases pressure, volume and temperatures are...Below is the expression of ideal gas equation: PV = nRT .......... (1) Here, volume i.e. V, pressure...The gas present in bulb A is N2 and bulb is NH3 . The moles of N2 and NH3 is 1 mol each. In both...Chapter 5, Problem 86QAPThe given tanks are as follows: Here, circles represent CH4 gas, square represents oxygen and...The pressure, volume and temperature of both tanks A and B is 1.38 atm, 750 ml or 0.750 L, and 25 0C...By burning sulfur with oxygen sulfur trioxide can be prepared 2S(s) + 3O2(g) → 2SO3(g) In the 5 g of...Chapter 6, Problem 1QAPChapter 6, Problem 27QAPChapter 6, Problem 28QAPChapter 6, Problem 39QAPChapter 6, Problem 40QAPChapter 6, Problem 42QAPChapter 6, Problem 49QAPChapter 6, Problem 50QAPChapter 6, Problem 67QAPCalculate the total number of valence electrons in molecule CCl4: Total number of valence electrons...Chapter 7, Problem 4QAPChapter 7, Problem 5QAPChapter 7, Problem 6QAPGiven Information: The molecule is Cl2. Here thetotal valence electrons are: 2×7(Cl)=14 and the...Given Information: The ion is BrO-. Here, the total valence electrons are: 7(Br)+6(O)+1(charge)=14....Chapter 7, Problem 17QAPChapter 7, Problem 18QAPChapter 8, Problem 1QAPChapter 8, Problem 5QAPChapter 8, Problem 6QAPChapter 8, Problem 16QAPChapter 8, Problem 35QAPChapter 8, Problem 43QAPChapter 8, Problem 44QAPChapter 8, Problem 72QAPChapter 8, Problem 76QAPChapter 8, Problem 87QAPGiven: P1 = 254 mm Hg T1 = 57 0C = (57+273) K = 330 K T2 = 35 0C = (35+273) K = 308 K and T2 = 45 0C...Chapter 9, Problem 3QAPGiven Information: The phase diagram of compound X is as follows: The triple point is defined as the...Chapter 9, Problem 18QAPNitrogen monoxide ( NO ) The number of valence electrons of both species. Nitrogen (N) has 5 valence...Chapter 9, Problem 61QAPGiven: The volume of one atom is 43πr3 and the volume of the cell is s3. The percentage of the total...Given: Volume = 10.0 L Mass of hydrogen gas = 0.400 g Mass of oxygen gas = 3.2 g Reaction:...Chapter 9, Problem 78QAPChapter 10, Problem 1QAPChapter 10, Problem 9QAPChapter 10, Problem 10QAPChapter 10, Problem 17QAPChapter 10, Problem 18QAPChapter 10, Problem 33QAPChapter 10, Problem 34QAPGiven, Temperature =22 °C Convert temperature from Celsius to Kelvin as follows: T=(22+273) K=295 K...Chapter 10, Problem 40QAPChapter 11, Problem 1QAPChapter 11, Problem 17QAPChapter 11, Problem 19QAPChapter 11, Problem 20QAPChapter 11, Problem 21QAPChapter 11, Problem 22QAPChapter 11, Problem 25QAPChapter 11, Problem 26QAPChapter 11, Problem 27QAPChapter 11, Problem 28QAPGiven Information: Here the chemical reaction is: 2NO(g) + O2(g) → 2NO2(g) Experiment No....Chapter 12, Problem 1QAPThe reaction of the system is as follows: 2A(g)+B(g)→3C(g) The given incomplete data is as follows:...Chapter 12, Problem 10QAPChapter 12, Problem 11QAPChapter 12, Problem 12QAPChapter 12, Problem 14QAPChapter 12, Problem 16QAPChapter 12, Problem 69QAPChapter 12, Problem 71QAPChapter 13, Problem 1QAPChapter 13, Problem 9QAPThe given species is Zn(H2O)3OH+. On reaction with water, it can act as an acid by donating hydrogen...The given species is (CH3)3N. On reaction with water, it can act as a base by accepting hydrogen ion...Chapter 13, Problem 51QAPChapter 13, Problem 52QAPChapter 13, Problem 59QAPChapter 13, Problem 61QAPChapter 13, Problem 62QAPChapter 13, Problem 67QAPChapter 13, Problem 74QAPChapter 13, Problem 98QAPChapter 14, Problem 1QAPChapter 14, Problem 6QAPChapter 14, Problem 9QAPChapter 14, Problem 10QAPChapter 14, Problem 32QAPChapter 14, Problem 34QAPChapter 14, Problem 36QAPChapter 14, Problem 50QAPChapter 14, Problem 74QAPChapter 15, Problem 1QAPChapter 15, Problem 32QAPChapter 15, Problem 34QAPChapter 15, Problem 55QAPThe equation of reaction of iron (II) sulfate with barium hydroxide is shown as follows:...Reason for correct option/s: b. The equation of Ag(NH3)2+ with strong acid is- Ag(NH3)2+(aq)+2H+(aq)...The equilibrium reaction of Mg(OH)2 is as follows: Mg(OH)2(s)⇌Mg2+(aq)+2OH−. The solubility product...Given the reaction is as follows: Zn(NH3)42+(aq)+4OH−(aq)⇌ Zn(OH)42−(aq)+4NH3(aq) For this reaction...Chapter 16, Problem 1QAPChapter 16, Problem 17QAPGiven process is: 4NH3 (g)+5O2(g)→4NO(g)+6H2O(g) The mathematical expression for the standard...Chapter 16, Problem 20QAPGiven process is: 2Cr (s)+3CO2(g)→Cr2O3(s)+3CO(g) The mathematical expression for the standard...Given process is: 2HNO3(l)+3H2S(g)→4H2O(l) + 2NO(g)+3S(s) The mathematical expression for the...Chapter 16, Problem 25QAPChapter 16, Problem 26QAPThe chemical equation corresponding to the reaction between iron ore and hydrogen is given as:...The given reaction is: MnO2(s) ⇌ Mn(s) + O2(g) For the above reaction, the ΔG0 value can be deduced...Given: ΔHf0(H2SO4) = -902.9 kJS0(H2SO4) = 17.14 J/K The dissociation of H2 SO4 can be expressed as...Chapter 17, Problem 1QAPChapter 17, Problem 5QAPChapter 17, Problem 6QAPSO2(g) + I2(aq)→SO3(g) + I-(aq) Determining the oxidation numbers: The oxidation number of I in I2...Chapter 17, Problem 8QAPChapter 17, Problem 9QAPChapter 17, Problem 37QAPChapter 17, Problem 39QAPChapter 17, Problem 73QAPChapter 17, Problem 74QAPChapter 17, Problem 100QAPChapter 18, Problem 1QAPThe reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...Chapter 18, Problem 19QAPThe reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...Given information: Half-life of uranium = 7×108 years The given equation is:...In the given compound, [Fe(C2O4)2(NH3)Cl3-] Oxalate is denoted by the symbol ‘ox’ and its chemical...A ligand is an atom or a group of atoms or an anion having an unshared pair of electrons and thus it...A ligand is an atom or a group of atoms or an anion that has an unshared pair of electrons and thus...Cadmium is a 4d transition metal element and its atomic number is 48. Its electronic configuration...Chapter 19, Problem 41QAPIn case of transition metal cations, the electrons that are present beyond the noble gas are in...Chapter 20, Problem 1QAPChapter 20, Problem 23QAPChapter 20, Problem 24QAPChapter 20, Problem 39QAPGiven Information: (1) A solution of potassium dichromate is made basic with sodium hydroxide. The...The compound has three elements and anion is periodate ion that is, IO4− because in naming of acid...The reaction of sulphate ion (SO42−) to form sulfur dioxide is as follows: SO42−(aq)⇌SO2(g) Balance...Iodine is oxidized to iodate. I2(s)⇌IO3−(aq) Balance the above reaction. Balance all atoms except...Chapter 21, Problem 18QAPAt 25°C, reaction of bromine is: Br2(I)+H2O ⇌ H+(aq)+Br−(aq)+HBrO(aq) Initial concentration: C 0 0 0...Chapter 21, Problem 53QAPChapter 21, Problem 61QAPBalance the reaction as follows: Consider oxidation and reduction reaction separately as given...Chapter 22, Problem 1QAPChapter 22, Problem 25QAPChapter 22, Problem 26QAPChapter 22, Problem 27QAPChapter 22, Problem 28QAPThe dissolved hydrochloric acid first dissociates into its ionic forms under the aqueous medium as...Chapter 22, Problem 60QAPTetrachloroethylene polymer consists of number of monomer unit of 1,1,2,2-tetrachloroethylene. The...If all the polymers contain the same number of monomer units, the molar mass of polymers can be...If all the polymers contain the same number of monomer units, the molar mass of polymers can be...Cellulose is a polyssaccharide which consists of several units of glucose joined through glycosidic...Chapter 23, Problem 29QAPThe given amino acid is alanine which has the following structure: The structures of the respective...
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