Bundle: Chemistry: Principles and React...8th EditionWilliam L. Masterton, Cecile N. Hurley Publisher: Cengage LearningISBN: 9781305717497
Bundle: Chemistry: Principles and React...
Solutions for Bundle: Chemistry: Principles and Reactions, 8th, Loose-Leaf + OWLv2, 1 term (6 months) Printed Access Card
Problem 1QAP:
Express the rate of the reaction 2N2H4(l)+N2O4(l)3N2(g)+4H2O(g) in terms of (b) [ N2O4 ] (a) [ N2 ]Problem 2QAP:
Express the rate of the reaction 2N2O(g)2N2(g)+O2(g) in terms of (b) [ N2O ] (a) [ O2 ]Problem 3QAP:
Consider the following hypothetical reaction: X( g )Y( g ) A 200.0-mL flask is filled with 0.120...Problem 4QAP:
Consider the following hypothetical reaction: 2AB2(g)A2(g)+2B2(g)A 500.0-mL flask is filled with...Problem 5QAP:
Consider the combustion of ethane: 2C2H6(g)+7O2(g)4CO2(g)+6H2O(g)If the ethane is burning at the...Problem 6QAP:
For the reaction 5Br(aq)+BrO3(aq)+6 H+(aq)3Br2(aq)+3H2O It was found that at a particular instant,...Problem 7QAP:
Nitrosyl chloride (NOCI) decomposes to nitrogen oxide and chlorine gases. (a) Write a balanced...Problem 8QAP:
Ammonia is produced by the reaction between nitrogen and hydrogen gases. (a) Write a balanced...Problem 9QAP:
Experimental data are listed for the following hypothetical reaction: A+Bproducts (a) Plot these...Problem 10QAP:
Experimental data are listed for the hypothetical reaction A+BZ (a) Plot these data as in Figure...Problem 11QAP:
A reaction has two reactants X and Y. What is the order with respect to each reactant and the...Problem 12QAP:
A reaction has two reactants Q and P. What is the order with respect to each reactant and the...Problem 13QAP:
What will the units of the rate constants in Question 11 be if the rate is expressed in mol/L min?Problem 14QAP:
What will the units of the rate constants in Question 12 be if the rate is expressed in mol/L min?Problem 15QAP:
Consider the reaction ZproductsThe data below give the rate of the reaction and the concentration of...Problem 16QAP:
Consider the reaction YproductsThe graph below plots the rate of the reaction versus the...Problem 17QAP:
Complete the following table for the reaction 2R(g)+3S(g)productsthat is first-order in R and...Problem 18QAP:
Complete the following table for the reaction below. It is first-order in both X and Y....Problem 19QAP:
The decomposition of nitrogen dioxide is a second-order reaction. At 550 K, a 0.250 M sample...Problem 20QAP:
The decomposition of ammonia on tungsten at 1100C is zero-order with a rate constant of...Problem 21QAP:
The reaction ICl(g)+12 H2(g)12 I2(g)+HCl(g)is first-order in both reactants. At a certain...Problem 22QAP:
The hypothetical reaction X(g)+12Y(g)productsis first-order in X and second-order in Y. The rate of...Problem 23QAP:
For a reaction involving the decomposition of Z at a certain temperature, the following data are...Problem 24QAP:
For a reaction involving the decomposition of Y, the following data are obtained: (a) Determine the...Problem 25QAP:
When boron trifluoride reacts with ammonia, the following reaction occurs: BF3(g)+NH3(g)BF3NH3(g)The...Problem 26QAP:
When nitrogen dioxide reacts with carbon monoxide, the following reaction occurs. Â...Problem 27QAP:
Hydrogen bromide is a highly reactive and corrosive gas used mainly as a catalyst for organic...Problem 29QAP:
The equation for the reaction between iodide and bromate ions in acidic solution is  6...Problem 31QAP:
In a solution at a constant H+ concentration, iodide ions react with hydrogen peroxide to produce...Problem 32QAP:
Consider the reaction  CH3CO2CH3(aq)+OH(aq)CH3CO2(aq)+CH3OH(aq)The following data are obtained at a...Problem 33QAP:
Nitrosyl bromide decomposes to nitrogen oxide and bromine. Use the following data to determine the...Problem 35QAP:
Azomethane decomposes into nitrogen and ethane at high temperatures according to the following...Problem 36QAP:
The decomposition of sulfuryl chloride, SO2Cl2, to sulfur dioxide and chlorine gases is a...Problem 37QAP:
The first-order rate constant for the decomposition of a certain hormone in water at 25C is...Problem 38QAP:
Consider the first-order decomposition of phosgene at a certain temperature. COCl2(g)productsIt is...Problem 39QAP:
The decomposition of azomethane, (CH3)2N2, to nitrogen and ethane gases is a first-order reaction,...Problem 40QAP:
The first-order rate constant for the decomposition of a certain drug at 25C is 0.215 month-1. (a)...Problem 41QAP:
In the first-order decomposition of acetone at 500C CH3COCH3(g)productsIt is found that it takes...Problem 42QAP:
The decomposition of sulfuryl chlorideSO2Cl2fur dioxide and chlorine gases is a first-order...Problem 43QAP:
Dinitrogen pentoxide gas decomposes to form nitrogen dioxide and oxygen. The reaction is first-order...Problem 44QAP:
Sucrose (C12H22O11) hydrolyzes into glucose and fructose. The hydrolysis is a first-order reaction....Problem 45QAP:
Iodine-131 is used to treat tumors in the thyroid. Its decomposition is first-order with a half-life...Problem 46QAP:
Cesium-131 is the latest tool of nuclear medicine. It is used to treat malignant tumors by...Problem 48QAP:
A sample of sodium-24 chloride contains 0.050 mg of Na-24 to study the sodium balance of an animal....Problem 49QAP:
The decomposition of A at 850C is a zero-order reaction. It takes 35 minutes to decompose 37% of an...Problem 50QAP:
The decomposition of R at 33C is a zero-order reaction. It takes 128 minutes to decompose 41.0% of...Problem 51QAP:
For the zero-order decomposition of HI on a gold surface HI(g) Au 12 H2(g)+12 I2(g)it takes 16.0 s...Problem 52QAP:
For the zero-order decomposition of ammonia on tungsten NH3(g) W 12 N2(g)+32 H2(g)the rate constant...Problem 53QAP:
Ammonium cyanate, NH4NCO, in water rearranges to produce urea, a common fertilizer, (NH2)2CO:...Problem 54QAP:
Butadiene, C4H6, dimerizes according to the following reaction: C4H6(g)C8H12(g)The dimerization is a...Problem 55QAP:
The rate constant for the second-order reaction NOBr(g)NO(g)+12 Br2(g)is 48 L/mol min at a certain...Problem 56QAP:
The decomposition of nitrosyl chloride NOCl(g)NO(g)+12 Cl2(g)is a second-order reaction. If it takes...Problem 57QAP:
An increase in temperature from 23C to 36C increases the rate constant of a certain reaction by...Problem 58QAP:
If the activation energy of a reaction is 9.13 kJ, then what is the percent increase in the rate...Problem 59QAP:
The following data are obtained for the gas-phase decomposition of acetaldehyde: Plot these data (In...Problem 60QAP:
The following data are obtained for the reactionSiH4(g)Si(s)+2H2(g) Plot these data (In k versus...Problem 61QAP:
Consider the following hypothetical reaction: X+YProductsH=75kJ Draw a reaction-energy diagram for...Problem 62QAP:
For the reaction: Q+RY+ZH=128kJ Draw a reaction-energy diagram for the reaction if the activation...Problem 63QAP:
The uncoiling of deoxyribonucleic acid (DNA) is a first-order reaction. Its activation energy is 420...Problem 64QAP:
The precipitation of egg albumin in water at 100C has an activation energy of 52.0 kJ/mol. By what...Problem 67QAP:
For the reaction 2N2O(g)2N2(g)+O2(g) the rate constant is 0.066 L/mol min at 565C and 22.8 L/mol min...Problem 68QAP:
For the decomposition of a peroxide, the activation energy is 17.4 kJ/mol. The rate constant at 25C...Problem 69QAP:
Consider a 5.000 M solution of the hypothetical com- pound R. Its decomposition is a second-order...Problem 70QAP:
The decomposition of N2O5 to NO2 and NO3 is a first-order gas-phase reaction. At 250C, the reaction...Problem 71QAP:
For a certain reaction, Ea is 135 kJ and H=45 kJ. In the presence of a catalyst, the activation...Problem 72QAP:
Consider a reaction in which E a=129 kJ and H=29 kJ. In the presence of a catalyst, the activation...Problem 73QAP:
A catalyst lowers the activation energy of a reaction from 215 kJ to 206 kJ. By what factor would...Problem 74QAP:
A reaction has an activation energy of 363 kJ at 25C. If the rate constant has to increase ten-fold,...Problem 75QAP:
Write the rate expression for each of the following elementary steps: (a) NO3+CONO2+CO2(b) I22I(c)...Problem 76QAP:
Write the rate expression for each of the following elementary steps: (a) Cl22Cl(b) N2O2+O22NO2(c) I...Problem 77QAP:
For the reaction between hydrogen and iodine, H2(g)+I22HI(g) the experimental rate expression is...Problem 78QAP:
For the reaction 2H2(g)+2NO(g)N2(g)+2H2O(g) the experimental rate expression is rate rate=k[ NO ]2[...Problem 79QAP:
At low temperatures, the rate law for the reaction CO(g)+NO2(g)CO2(g)+NO(g)is as follows:...Problem 80QAP:
Two mechanisms are proposed for the reaction 2NO(g)+O2(g)2NO2(g)Mechanism 1: NO+O2NO3(fast)...Problem 81QAP:
The hypothetical reaction QR+Xproductswas monitored at 27C as a function of time. The following...Problem 82QAP:
When a base is added to an aqueous solution of chlorine dioxide gas, the following reaction occurs:...Problem 83QAP:
The decomposition of sulfuryl chloride, SO2Cl2, to sulfur dioxide and chlorine gases is a...Problem 84QAP:
How much faster would a reaction proceed at 46C than at 28C if the activation energy of the reaction...Problem 87QAP:
A drug decomposes in the blood by a first-order process. A pill containing 0.500 g of the active...Problem 91QAP:
Consider the decomposition of A represented by circles, where each circle represents a molecule of...Problem 92QAP:
Consider the decomposition reaction 2X2Y+ZThe following graph shows the change in concentration with...Problem 93QAP:
Consider the following activation energy diagram. Which of the following statements about the...Problem 94QAP:
Three first-order reactions have the following activation energies: (a) Which reaction is the...Problem 95QAP:
Consider the first-order decomposition reaction A+BCwhere A (circles) decomposes to B (triangles)...Problem 96QAP:
Consider the following energy diagram (not to scale) for the reaction. 2CH3(g)C2H6(g) (a) What is...Problem 99QAP:
The gas-phase reaction between hydrogen and iodine H2(g)+I22HI(g)proceeds with a rate constant for...Problem 100QAP:
Consider the coagulation of a protein at 100C. The first-order reaction has an activation energy of...Browse All Chapters of This Textbook
Chapter 1 - Matter And MeasurementsChapter 2 - Atoms, Molecules, And IonsChapter 3 - Mass Relations In Chemistry; StoichiometryChapter 4 - Reactions In Aqueous SolutionChapter 5 - GasesChapter 6 - Electronic Structure And The Periodic TableChapter 7 - Covalent BondingChapter 8 - ThermochemistryChapter 9 - Liquids And SolidsChapter 10 - Solutions
Chapter 11 - Rate Of ReactionChapter 12 - Gaseous Chemical EquilibriumChapter 13 - Acids And BasesChapter 14 - Equilibria In Acid-base SolutionsChapter 15 - Complex Ion And Precipitation EquilibriaChapter 16 - Spontaneity Of ReactionChapter 17 - ElectrochemistryChapter 18 - Nuclear ReactionsChapter 19 - Complex IonsChapter 20 - Chemistry Of The MetalsChapter 21 - Chemistry Of The NonmetalsChapter 22 - Organic ChemistryChapter 23 - Organic Polymers, Natural And Synthetic
Sample Solutions for this Textbook
We offer sample solutions for Bundle: Chemistry: Principles and Reactions, 8th, Loose-Leaf + OWLv2, 1 term (6 months) Printed Access Card homework problems. See examples below:
Chapter 1, Problem 1QAPChapter 1, Problem 27QAPChapter 1, Problem 28QAPChapter 2, Problem 1QAPChapter 2, Problem 27QAPChapter 2, Problem 28QAPChapter 2, Problem 36QAPChapter 2, Problem 37QAPChapter 2, Problem 38QAP
Given structural formula- In above structural formula, CH3 group is attached with acetic acid group...Methane is a member of Alkane family that has only 1 carbon atom and general formula for molecular...Chemical name of molecule = silicon disulfide In this chemical compound: Least electronegative atom...Potassium and strontium are metals. Potassium is present in group 1 known as alkali metal group in...Chapter 3, Problem 1QAPChapter 3, Problem 13QAPChapter 3, Problem 18QAPChapter 3, Problem 25QAPChapter 3, Problem 47QAPChapter 3, Problem 48QAPChapter 3, Problem 51QAPChapter 3, Problem 52QAPChapter 3, Problem 74QAPChapter 3, Problem 94QAPChapter 4, Problem 1QAPChapter 4, Problem 7QAPChapter 4, Problem 8QAPChapter 4, Problem 9QAPChapter 4, Problem 10QAPChapter 4, Problem 63QAPChapter 4, Problem 74QAPVolume of a gas in a container is equal to the volume of the container. Conversion factor for gallon...The force exerted by gas over a unit surface of area is called pressure of gas. The expression of...As per the given table we have to find the moles and grams of propane gas. First let us calculate...The gas 1 is taken as CO2 and gas 2 as H2 . For both the gases pressure, volume and temperatures are...Below is the expression of ideal gas equation: PV = nRT .......... (1) Here, volume i.e. V, pressure...The gas present in bulb A is N2 and bulb is NH3 . The moles of N2 and NH3 is 1 mol each. In both...Chapter 5, Problem 86QAPThe given tanks are as follows: Here, circles represent CH4 gas, square represents oxygen and...The pressure, volume and temperature of both tanks A and B is 1.38 atm, 750 ml or 0.750 L, and 25 0C...By burning sulfur with oxygen sulfur trioxide can be prepared 2S(s) + 3O2(g) → 2SO3(g) In the 5 g of...Chapter 6, Problem 1QAPChapter 6, Problem 27QAPChapter 6, Problem 28QAPChapter 6, Problem 39QAPChapter 6, Problem 40QAPChapter 6, Problem 42QAPChapter 6, Problem 49QAPChapter 6, Problem 50QAPChapter 6, Problem 67QAPCalculate the total number of valence electrons in molecule CCl4: Total number of valence electrons...Chapter 7, Problem 4QAPChapter 7, Problem 5QAPChapter 7, Problem 6QAPGiven Information: The molecule is Cl2. Here thetotal valence electrons are: 2×7(Cl)=14 and the...Given Information: The ion is BrO-. Here, the total valence electrons are: 7(Br)+6(O)+1(charge)=14....Chapter 7, Problem 17QAPChapter 7, Problem 18QAPChapter 8, Problem 1QAPChapter 8, Problem 5QAPChapter 8, Problem 6QAPChapter 8, Problem 16QAPChapter 8, Problem 35QAPChapter 8, Problem 43QAPChapter 8, Problem 44QAPChapter 8, Problem 72QAPChapter 8, Problem 76QAPChapter 8, Problem 87QAPGiven: P1 = 254 mm Hg T1 = 57 0C = (57+273) K = 330 K T2 = 35 0C = (35+273) K = 308 K and T2 = 45 0C...Chapter 9, Problem 3QAPGiven Information: The phase diagram of compound X is as follows: The triple point is defined as the...Chapter 9, Problem 18QAPNitrogen monoxide ( NO ) The number of valence electrons of both species. Nitrogen (N) has 5 valence...Chapter 9, Problem 61QAPGiven: The volume of one atom is 43πr3 and the volume of the cell is s3. The percentage of the total...Given: Volume = 10.0 L Mass of hydrogen gas = 0.400 g Mass of oxygen gas = 3.2 g Reaction:...Chapter 9, Problem 78QAPChapter 10, Problem 1QAPChapter 10, Problem 9QAPChapter 10, Problem 10QAPChapter 10, Problem 17QAPChapter 10, Problem 18QAPChapter 10, Problem 33QAPChapter 10, Problem 34QAPGiven, Temperature =22 °C Convert temperature from Celsius to Kelvin as follows: T=(22+273) K=295 K...Chapter 10, Problem 40QAPChapter 11, Problem 1QAPChapter 11, Problem 17QAPChapter 11, Problem 19QAPChapter 11, Problem 20QAPChapter 11, Problem 21QAPChapter 11, Problem 22QAPChapter 11, Problem 25QAPChapter 11, Problem 26QAPChapter 11, Problem 27QAPChapter 11, Problem 28QAPGiven Information: Here the chemical reaction is: 2NO(g) + O2(g) → 2NO2(g) Experiment No....Chapter 12, Problem 1QAPThe reaction of the system is as follows: 2A(g)+B(g)→3C(g) The given incomplete data is as follows:...Chapter 12, Problem 10QAPChapter 12, Problem 11QAPChapter 12, Problem 12QAPChapter 12, Problem 14QAPChapter 12, Problem 16QAPChapter 12, Problem 69QAPChapter 12, Problem 71QAPChapter 13, Problem 1QAPChapter 13, Problem 9QAPThe given species is Zn(H2O)3OH+. On reaction with water, it can act as an acid by donating hydrogen...The given species is (CH3)3N. On reaction with water, it can act as a base by accepting hydrogen ion...Chapter 13, Problem 51QAPChapter 13, Problem 52QAPChapter 13, Problem 59QAPChapter 13, Problem 61QAPChapter 13, Problem 62QAPChapter 13, Problem 67QAPChapter 13, Problem 74QAPChapter 13, Problem 98QAPChapter 14, Problem 1QAPChapter 14, Problem 6QAPChapter 14, Problem 9QAPChapter 14, Problem 10QAPChapter 14, Problem 32QAPChapter 14, Problem 34QAPChapter 14, Problem 36QAPChapter 14, Problem 50QAPChapter 14, Problem 74QAPChapter 15, Problem 1QAPChapter 15, Problem 32QAPChapter 15, Problem 34QAPChapter 15, Problem 55QAPThe equation of reaction of iron (II) sulfate with barium hydroxide is shown as follows:...Reason for correct option/s: b. The equation of Ag(NH3)2+ with strong acid is- Ag(NH3)2+(aq)+2H+(aq)...The equilibrium reaction of Mg(OH)2 is as follows: Mg(OH)2(s)⇌Mg2+(aq)+2OH−. The solubility product...Given the reaction is as follows: Zn(NH3)42+(aq)+4OH−(aq)⇌ Zn(OH)42−(aq)+4NH3(aq) For this reaction...Chapter 16, Problem 1QAPChapter 16, Problem 17QAPGiven process is: 4NH3 (g)+5O2(g)→4NO(g)+6H2O(g) The mathematical expression for the standard...Chapter 16, Problem 20QAPGiven process is: 2Cr (s)+3CO2(g)→Cr2O3(s)+3CO(g) The mathematical expression for the standard...Given process is: 2HNO3(l)+3H2S(g)→4H2O(l) + 2NO(g)+3S(s) The mathematical expression for the...Chapter 16, Problem 25QAPChapter 16, Problem 26QAPThe chemical equation corresponding to the reaction between iron ore and hydrogen is given as:...The given reaction is: MnO2(s) ⇌ Mn(s) + O2(g) For the above reaction, the ΔG0 value can be deduced...Given: ΔHf0(H2SO4) = -902.9 kJS0(H2SO4) = 17.14 J/K The dissociation of H2 SO4 can be expressed as...Chapter 17, Problem 1QAPChapter 17, Problem 5QAPChapter 17, Problem 6QAPSO2(g) + I2(aq)→SO3(g) + I-(aq) Determining the oxidation numbers: The oxidation number of I in I2...Chapter 17, Problem 8QAPChapter 17, Problem 9QAPChapter 17, Problem 37QAPChapter 17, Problem 39QAPChapter 17, Problem 73QAPChapter 17, Problem 74QAPChapter 17, Problem 100QAPChapter 18, Problem 1QAPThe reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...Chapter 18, Problem 19QAPThe reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...Given information: Half-life of uranium = 7×108 years The given equation is:...In the given compound, [Fe(C2O4)2(NH3)Cl3-] Oxalate is denoted by the symbol ‘ox’ and its chemical...A ligand is an atom or a group of atoms or an anion having an unshared pair of electrons and thus it...A ligand is an atom or a group of atoms or an anion that has an unshared pair of electrons and thus...Cadmium is a 4d transition metal element and its atomic number is 48. Its electronic configuration...Chapter 19, Problem 41QAPIn case of transition metal cations, the electrons that are present beyond the noble gas are in...Chapter 20, Problem 1QAPChapter 20, Problem 23QAPChapter 20, Problem 24QAPChapter 20, Problem 39QAPGiven Information: (1) A solution of potassium dichromate is made basic with sodium hydroxide. The...The compound has three elements and anion is periodate ion that is, IO4− because in naming of acid...The reaction of sulphate ion (SO42−) to form sulfur dioxide is as follows: SO42−(aq)⇌SO2(g) Balance...Iodine is oxidized to iodate. I2(s)⇌IO3−(aq) Balance the above reaction. Balance all atoms except...Chapter 21, Problem 18QAPAt 25°C, reaction of bromine is: Br2(I)+H2O ⇌ H+(aq)+Br−(aq)+HBrO(aq) Initial concentration: C 0 0 0...Chapter 21, Problem 53QAPChapter 21, Problem 61QAPBalance the reaction as follows: Consider oxidation and reduction reaction separately as given...Chapter 22, Problem 1QAPChapter 22, Problem 25QAPChapter 22, Problem 26QAPChapter 22, Problem 27QAPChapter 22, Problem 28QAPThe dissolved hydrochloric acid first dissociates into its ionic forms under the aqueous medium as...Chapter 22, Problem 60QAPTetrachloroethylene polymer consists of number of monomer unit of 1,1,2,2-tetrachloroethylene. The...If all the polymers contain the same number of monomer units, the molar mass of polymers can be...If all the polymers contain the same number of monomer units, the molar mass of polymers can be...Cellulose is a polyssaccharide which consists of several units of glucose joined through glycosidic...Chapter 23, Problem 29QAPThe given amino acid is alanine which has the following structure: The structures of the respective...
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