Organic Chemistry
Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Chapter 9.5, Problem 21P

(a)

Interpretation Introduction

Interpretation:

Among the given compounds, the one which is more reactive in a SN2 reaction has to be identified.

Concept Introduction:

Vinyl and aryl halides: (SN2 reaction)

Vinylic halides and aryl halides do not undergo SN2 reaction. Because, as the nucleophile approaches the back side of the sp2 carbon, it is repelled by the π electrons of the double bond or the benzene ring.

(b)

Interpretation Introduction

Interpretation:

Among the given compounds, the one which is more reactive in a SN2 reaction has to be identified.

Concept Introduction:

Vinyl and aryl halides: (SN2 reaction)

Vinylic halides and aryl halides do not undergo SN2 reaction. Because, as the nucleophile approaches the back side of the sp2 carbon, it is repelled by the π electrons of the double bond or the benzene ring.

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