Organic Chemistry
Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Chapter 9, Problem 44P

(a)

Interpretation Introduction

Interpretation:

Substitution products obtained when 2-bromo-2-methypropane is dissolved in a mixture of 80% ethanol and 20% water is to be identified.

Concept Introduction:

Ether can be synthesized by the reaction of an alkyl halide with an alkoxide ion.  This reaction is called the Williamson ether synthesis.

R-Br+R-O-R-O-R+Br-

Where R-Br is alkyl halide and R-O- is alkoxide ion.

(b)

Interpretation Introduction

Interpretation:

The same products are obtained in part (a) when 2-chloro-2-methypropane is dissolved a mixture of 80% ethanol and 20% water is to be identified.

Concept Introduction:

Ether can be synthesized by the reaction of an alkyl halide with an alkoxide ion. This reaction is called the Williamson ether synthesis.

R-Br+R-O-R-O-R+Br-

Where R-Br is alkyl halide and R-O- is alkoxide ion.

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