Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions. Concept Introduction: Rate α [ alkyl halide ] [ nucleophile ] Thus, rate = k[alkyl halide][nucleophile] , where k is the rate constant. Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower. The rate of the S N 2 reaction depends not only on the number of alkyl group but also on the size. Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state. Higher the height of the energy barrier lowers the rate constant.

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Answer 1

Question

Chapter 9, Problem 56P

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the SN2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the SN2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the S_N2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <

2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity

Answer 2

Question

Chapter 9, Problem 56P

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the SN2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the SN2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the S_N2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

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Answer 3

Question

Chapter 9, Problem 56P

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the SN2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the SN2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the S_N2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 9, Problem 56P

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the SN2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the SN2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the S_N2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

Expert Solution & Answer

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Answer 5

Chapter 9, Problem 56P

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the SN2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the SN2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the S_N2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

Answer 6

Chapter 9, Problem 56P

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the SN2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

Answer 7

Chapter 9, Problem 56P

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the SN2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the SN2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the SN2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the S_N2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction of methyl iodide with quinuclidine and methyl iodide with trimethylamine is measured in nitrobenzene, based on it answer the following questions.

Concept Introduction:

Rate α [alkyl halide][nucleophile]

Thus,

rate = k[alkyl halide][nucleophile] , where k is the rate constant.

Increasing the height of the energy barrier decreases the magnitude of the rate constant, thus causes the reaction to be slower.

The rate of the S_N2 reaction depends not only on the number of alkyl group but also on the size.

Steric hindrance decreases the rate of the reaction by increasing the energy of the transition state.

Higher the height of the energy barrier lowers the rate constant.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 9.1 - Prob. 3P Ch. 9.1 - Does increasing the energy barrier for an SN2...Ch. 9.1 - Rank the following alkyl bromides from most...Ch. 9.2 - Prob. 8P Ch. 9.2 - Prob. 9P Ch. 9.2 - Prob. 10P Ch. 9.2 - Prob. 11P Ch. 9.2 - Which substitution reaction lakes place more...Ch. 9.2 - Prob. 14P Ch. 9.2 - Prob. 16P

Solution Summary: The author explains that the rate of the reaction of methyl iodide with quinuclidine is measured in nitrobenzene.

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Chapter 9 Solutions