Organic Chemistry
Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Chapter 9.6, Problem 25P

Which of the following reactions take place more rapidly when the concentration of the nucleophile is increased?

Chapter 9.6, Problem 25P, Which of the following reactions take place more rapidly when the concentration of the nucleophile

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Two cations that exchange an electron in an interface, the exchange density is worth 1.39 mA/cm2 and the current density is worth 15 mA/cm2 at 25°C. If the overvoltage is 0.14 V, calculate the reaction rate and symmetry factor. Data: R = 8,314 J mol-1 k-1: F = 96500 C
With the help of the Tafel line, it is estimated that the interchange density of the VO2+/VO2+ system on the carbon paper has a value of 3 mA cm-2. Calculate a) the current density if the voltage has a value of 1.6 mV and the temperature is 25°C. b) the beta value of the anódico process if the Tafel pendulum is 0.6 V at 25°C. Data: R = 8.314 JK-1mol-1, y F = 96485 C mol-1.
Apply the NANSTE law to the MnO4- + 8H+ + 5e- ⇄ Mn2+ + 4H2O

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