
General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Question
Chapter 9, Problem 9.66SP
Interpretation Introduction
Interpretation:
The molecular weight of the unknown gas has to be calculated.
Concept Introduction:
Molecular mass:
It is a physical property, which is defined as the mass of a given substance divided by the amount of substance. Unit of the molecular mass is
Ideal gas equation is an equation that is describing the state of an imaginary ideal gas.
Where,
P is the pressure of the gas
V is the volume
n is the number of moles of gas
R is the universal gas constant
T is the temperature
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 9 Solutions
General Chemistry: Atoms First
Ch. 9.1 - Yet another common measure of pressure is the unit...Ch. 9.1 - If the density of water is 1.00 g/mL and the...Ch. 9.1 - What is the pressure in atmospheres in a container...Ch. 9.1 - Prob. 9.4CPCh. 9.2 - Prob. 9.5CPCh. 9.3 - How many moles of methane gas, CH4, are in a...Ch. 9.3 - Prob. 9.7PCh. 9.3 - Prob. 9.8PCh. 9.3 - Prob. 9.9PCh. 9.3 - Prob. 9.10CP
Ch. 9.4 - Carbonate-bearing rocks like limestone (CaCO3)...Ch. 9.4 - Prob. 9.12PCh. 9.4 - Prob. 9.13PCh. 9.5 - What is the mole fraction of each component in a...Ch. 9.5 - What is the total pressure in atmospheres and what...Ch. 9.5 - Prob. 9.16PCh. 9.5 - Prob. 9.17CPCh. 9.6 - Calculate the average speed of a nitrogen molecule...Ch. 9.6 - At what temperature does the average speed of an...Ch. 9.7 - Prob. 9.20PCh. 9.7 - Prob. 9.21PCh. 9.8 - Assume that you have 0.500 mol of N2 in a volume...Ch. 9.9 - Prob. 9.23PCh. 9.9 - For ether, a partial pressure of 15 mm Hg results...Ch. 9.9 - Prob. 9.25PCh. 9 - Prob. 9.26CPCh. 9 - Prob. 9.27CPCh. 9 - Prob. 9.28CPCh. 9 - Prob. 9.29CPCh. 9 - Assume that you have a mixture of He (atomic...Ch. 9 - Prob. 9.31CPCh. 9 - Prob. 9.32CPCh. 9 - Prob. 9.33CPCh. 9 - Prob. 9.34CPCh. 9 - Prob. 9.36SPCh. 9 - Prob. 9.37SPCh. 9 - Prob. 9.38SPCh. 9 - Prob. 9.39SPCh. 9 - Prob. 9.40SPCh. 9 - Prob. 9.41SPCh. 9 - Assume that you have an open-end manometer filled...Ch. 9 - Assume that you have an open-end manometer filled...Ch. 9 - Prob. 9.44SPCh. 9 - Prob. 9.45SPCh. 9 - Prob. 9.46SPCh. 9 - Prob. 9.47SPCh. 9 - Prob. 9.48SPCh. 9 - Prob. 9.49SPCh. 9 - Prob. 9.50SPCh. 9 - Prob. 9.51SPCh. 9 - Prob. 9.52SPCh. 9 - Prob. 9.53SPCh. 9 - Prob. 9.54SPCh. 9 - Prob. 9.55SPCh. 9 - Prob. 9.56SPCh. 9 - Prob. 9.57SPCh. 9 - Prob. 9.58SPCh. 9 - Prob. 9.59SPCh. 9 - Prob. 9.60SPCh. 9 - Prob. 9.61SPCh. 9 - Prob. 9.62SPCh. 9 - Prob. 9.63SPCh. 9 - Prob. 9.64SPCh. 9 - Prob. 9.65SPCh. 9 - Prob. 9.66SPCh. 9 - Prob. 9.67SPCh. 9 - Prob. 9.68SPCh. 9 - Prob. 9.69SPCh. 9 - Prob. 9.70SPCh. 9 - Prob. 9.71SPCh. 9 - Prob. 9.72SPCh. 9 - Prob. 9.73SPCh. 9 - Prob. 9.74SPCh. 9 - Prob. 9.75SPCh. 9 - Prob. 9.76SPCh. 9 - Prob. 9.77SPCh. 9 - Prob. 9.78SPCh. 9 - Prob. 9.79SPCh. 9 - Prob. 9.80SPCh. 9 - Prob. 9.81SPCh. 9 - Prob. 9.82SPCh. 9 - Prob. 9.83SPCh. 9 - Prob. 9.84SPCh. 9 - Prob. 9.85SPCh. 9 - Prob. 9.86SPCh. 9 - Prob. 9.87SPCh. 9 - Prob. 9.88SPCh. 9 - Prob. 9.89SPCh. 9 - Prob. 9.90SPCh. 9 - Prob. 9.91SPCh. 9 - Prob. 9.92SPCh. 9 - Prob. 9.93SPCh. 9 - Prob. 9.94SPCh. 9 - Prob. 9.95SPCh. 9 - Prob. 9.96SPCh. 9 - Prob. 9.97SPCh. 9 - Prob. 9.98CHPCh. 9 - Prob. 9.99CHPCh. 9 - Prob. 9.100CHPCh. 9 - Prob. 9.101CHPCh. 9 - Prob. 9.102CHPCh. 9 - Prob. 9.103CHPCh. 9 - Prob. 9.104CHPCh. 9 - Prob. 9.105CHPCh. 9 - Prob. 9.106CHPCh. 9 - Prob. 9.107CHPCh. 9 - Prob. 9.108CHPCh. 9 - Prob. 9.109CHPCh. 9 - Prob. 9.110CHPCh. 9 - Prob. 9.111CHPCh. 9 - Prob. 9.112CHPCh. 9 - Prob. 9.113CHPCh. 9 - Prob. 9.114CHPCh. 9 - Prob. 9.115CHPCh. 9 - Prob. 9.116CHPCh. 9 - Prob. 9.117CHPCh. 9 - Prob. 9.118CHPCh. 9 - Prob. 9.119CHPCh. 9 - Prob. 9.120CHPCh. 9 - Prob. 9.121CHPCh. 9 - Prob. 9.122CHPCh. 9 - Prob. 9.123CHPCh. 9 - Prob. 9.124CHPCh. 9 - Prob. 9.125CHPCh. 9 - Prob. 9.126CHPCh. 9 - Prob. 9.127CHPCh. 9 - Prob. 9.128MPCh. 9 - Prob. 9.129MPCh. 9 - Prob. 9.130MPCh. 9 - The Rankine temperature scale used in engineering...Ch. 9 - Prob. 9.132MPCh. 9 - Combustion analysis of 0.1500 g of methyl...
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