General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 9.8, Problem 9.22P
Assume that you have 0.500 mol of N2 in a volume of 0.600 L at 300 K. Calculate the pressure in atmospheres using both the
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Consider the reaction below to answer the following questions:
Acetoacetic ester can be prepared by the Claisen self-condensation reaction of ethyl acetate.
1. NaOEt, EtOH
H&C
OCH CH3 2 H30
H3C
CH2
OCH2CH3
A. Write the complete stepwise mechanism for this reaction. Show all electron flow with arrows and
draw all intermediate structures.
B. Ethyl acetate can be prepared from ethanol as the only organic starting material. Show all reagents
and structures for all intermediates in this preparation.
C. Give the structures of the ester precursors for the following Claisen condensation product and
formulate the reaction.
OEt
Use the phase diagram of Substance X below to find the temperature at which X turns to a gas, if the pressure above the solid is 3.7 atm.
pressure (atm)
32
16
solid
liquid
gas
0
0
200
temperature (K)
Note: your answer must be within 20 °C of the exact answer to be graded correct.
Шос
☑
ك
Starting from bromoethane, how could you prepare the following compounds:
a. Ethanol.
b. Acetaldehyde
f. Acetone.
e. 2-Propanol
i. Acetoacetic ester.
d. 2-Bromoacetic acid.
c. Acetic acid
g. Acetamide.
j. Ethylmalonate
k. Gama ketoacid.
h. Ethyl magnesium bromide.
Chapter 9 Solutions
General Chemistry: Atoms First
Ch. 9.1 - Yet another common measure of pressure is the unit...Ch. 9.1 - If the density of water is 1.00 g/mL and the...Ch. 9.1 - What is the pressure in atmospheres in a container...Ch. 9.1 - Prob. 9.4CPCh. 9.2 - Prob. 9.5CPCh. 9.3 - How many moles of methane gas, CH4, are in a...Ch. 9.3 - Prob. 9.7PCh. 9.3 - Prob. 9.8PCh. 9.3 - Prob. 9.9PCh. 9.3 - Prob. 9.10CP
Ch. 9.4 - Carbonate-bearing rocks like limestone (CaCO3)...Ch. 9.4 - Prob. 9.12PCh. 9.4 - Prob. 9.13PCh. 9.5 - What is the mole fraction of each component in a...Ch. 9.5 - What is the total pressure in atmospheres and what...Ch. 9.5 - Prob. 9.16PCh. 9.5 - Prob. 9.17CPCh. 9.6 - Calculate the average speed of a nitrogen molecule...Ch. 9.6 - At what temperature does the average speed of an...Ch. 9.7 - Prob. 9.20PCh. 9.7 - Prob. 9.21PCh. 9.8 - Assume that you have 0.500 mol of N2 in a volume...Ch. 9.9 - Prob. 9.23PCh. 9.9 - For ether, a partial pressure of 15 mm Hg results...Ch. 9.9 - Prob. 9.25PCh. 9 - Prob. 9.26CPCh. 9 - Prob. 9.27CPCh. 9 - Prob. 9.28CPCh. 9 - Prob. 9.29CPCh. 9 - Assume that you have a mixture of He (atomic...Ch. 9 - Prob. 9.31CPCh. 9 - Prob. 9.32CPCh. 9 - Prob. 9.33CPCh. 9 - Prob. 9.34CPCh. 9 - Prob. 9.36SPCh. 9 - Prob. 9.37SPCh. 9 - Prob. 9.38SPCh. 9 - Prob. 9.39SPCh. 9 - Prob. 9.40SPCh. 9 - Prob. 9.41SPCh. 9 - Assume that you have an open-end manometer filled...Ch. 9 - Assume that you have an open-end manometer filled...Ch. 9 - Prob. 9.44SPCh. 9 - Prob. 9.45SPCh. 9 - Prob. 9.46SPCh. 9 - Prob. 9.47SPCh. 9 - Prob. 9.48SPCh. 9 - Prob. 9.49SPCh. 9 - Prob. 9.50SPCh. 9 - Prob. 9.51SPCh. 9 - Prob. 9.52SPCh. 9 - Prob. 9.53SPCh. 9 - Prob. 9.54SPCh. 9 - Prob. 9.55SPCh. 9 - Prob. 9.56SPCh. 9 - Prob. 9.57SPCh. 9 - Prob. 9.58SPCh. 9 - Prob. 9.59SPCh. 9 - Prob. 9.60SPCh. 9 - Prob. 9.61SPCh. 9 - Prob. 9.62SPCh. 9 - Prob. 9.63SPCh. 9 - Prob. 9.64SPCh. 9 - Prob. 9.65SPCh. 9 - Prob. 9.66SPCh. 9 - Prob. 9.67SPCh. 9 - Prob. 9.68SPCh. 9 - Prob. 9.69SPCh. 9 - Prob. 9.70SPCh. 9 - Prob. 9.71SPCh. 9 - Prob. 9.72SPCh. 9 - Prob. 9.73SPCh. 9 - Prob. 9.74SPCh. 9 - Prob. 9.75SPCh. 9 - Prob. 9.76SPCh. 9 - Prob. 9.77SPCh. 9 - Prob. 9.78SPCh. 9 - Prob. 9.79SPCh. 9 - Prob. 9.80SPCh. 9 - Prob. 9.81SPCh. 9 - Prob. 9.82SPCh. 9 - Prob. 9.83SPCh. 9 - Prob. 9.84SPCh. 9 - Prob. 9.85SPCh. 9 - Prob. 9.86SPCh. 9 - Prob. 9.87SPCh. 9 - Prob. 9.88SPCh. 9 - Prob. 9.89SPCh. 9 - Prob. 9.90SPCh. 9 - Prob. 9.91SPCh. 9 - Prob. 9.92SPCh. 9 - Prob. 9.93SPCh. 9 - Prob. 9.94SPCh. 9 - Prob. 9.95SPCh. 9 - Prob. 9.96SPCh. 9 - Prob. 9.97SPCh. 9 - Prob. 9.98CHPCh. 9 - Prob. 9.99CHPCh. 9 - Prob. 9.100CHPCh. 9 - Prob. 9.101CHPCh. 9 - Prob. 9.102CHPCh. 9 - Prob. 9.103CHPCh. 9 - Prob. 9.104CHPCh. 9 - Prob. 9.105CHPCh. 9 - Prob. 9.106CHPCh. 9 - Prob. 9.107CHPCh. 9 - Prob. 9.108CHPCh. 9 - Prob. 9.109CHPCh. 9 - Prob. 9.110CHPCh. 9 - Prob. 9.111CHPCh. 9 - Prob. 9.112CHPCh. 9 - Prob. 9.113CHPCh. 9 - Prob. 9.114CHPCh. 9 - Prob. 9.115CHPCh. 9 - Prob. 9.116CHPCh. 9 - Prob. 9.117CHPCh. 9 - Prob. 9.118CHPCh. 9 - Prob. 9.119CHPCh. 9 - Prob. 9.120CHPCh. 9 - Prob. 9.121CHPCh. 9 - Prob. 9.122CHPCh. 9 - Prob. 9.123CHPCh. 9 - Prob. 9.124CHPCh. 9 - Prob. 9.125CHPCh. 9 - Prob. 9.126CHPCh. 9 - Prob. 9.127CHPCh. 9 - Prob. 9.128MPCh. 9 - Prob. 9.129MPCh. 9 - Prob. 9.130MPCh. 9 - The Rankine temperature scale used in engineering...Ch. 9 - Prob. 9.132MPCh. 9 - Combustion analysis of 0.1500 g of methyl...
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