
General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Question
Chapter 9, Problem 9.60SP
Interpretation Introduction
Interpretation:
The difference between
Concept Introduction:
Ideal gas equation is an equation that is describing the state of an imaginary ideal gas.
Where,
P is the pressure of the gas
V is the volume
n is the number of moles of gas
R is the universal gas constant
T is the temperature
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 9 Solutions
General Chemistry: Atoms First
Ch. 9.1 - Yet another common measure of pressure is the unit...Ch. 9.1 - If the density of water is 1.00 g/mL and the...Ch. 9.1 - What is the pressure in atmospheres in a container...Ch. 9.1 - Prob. 9.4CPCh. 9.2 - Prob. 9.5CPCh. 9.3 - How many moles of methane gas, CH4, are in a...Ch. 9.3 - Prob. 9.7PCh. 9.3 - Prob. 9.8PCh. 9.3 - Prob. 9.9PCh. 9.3 - Prob. 9.10CP
Ch. 9.4 - Carbonate-bearing rocks like limestone (CaCO3)...Ch. 9.4 - Prob. 9.12PCh. 9.4 - Prob. 9.13PCh. 9.5 - What is the mole fraction of each component in a...Ch. 9.5 - What is the total pressure in atmospheres and what...Ch. 9.5 - Prob. 9.16PCh. 9.5 - Prob. 9.17CPCh. 9.6 - Calculate the average speed of a nitrogen molecule...Ch. 9.6 - At what temperature does the average speed of an...Ch. 9.7 - Prob. 9.20PCh. 9.7 - Prob. 9.21PCh. 9.8 - Assume that you have 0.500 mol of N2 in a volume...Ch. 9.9 - Prob. 9.23PCh. 9.9 - For ether, a partial pressure of 15 mm Hg results...Ch. 9.9 - Prob. 9.25PCh. 9 - Prob. 9.26CPCh. 9 - Prob. 9.27CPCh. 9 - Prob. 9.28CPCh. 9 - Prob. 9.29CPCh. 9 - Assume that you have a mixture of He (atomic...Ch. 9 - Prob. 9.31CPCh. 9 - Prob. 9.32CPCh. 9 - Prob. 9.33CPCh. 9 - Prob. 9.34CPCh. 9 - Prob. 9.36SPCh. 9 - Prob. 9.37SPCh. 9 - Prob. 9.38SPCh. 9 - Prob. 9.39SPCh. 9 - Prob. 9.40SPCh. 9 - Prob. 9.41SPCh. 9 - Assume that you have an open-end manometer filled...Ch. 9 - Assume that you have an open-end manometer filled...Ch. 9 - Prob. 9.44SPCh. 9 - Prob. 9.45SPCh. 9 - Prob. 9.46SPCh. 9 - Prob. 9.47SPCh. 9 - Prob. 9.48SPCh. 9 - Prob. 9.49SPCh. 9 - Prob. 9.50SPCh. 9 - Prob. 9.51SPCh. 9 - Prob. 9.52SPCh. 9 - Prob. 9.53SPCh. 9 - Prob. 9.54SPCh. 9 - Prob. 9.55SPCh. 9 - Prob. 9.56SPCh. 9 - Prob. 9.57SPCh. 9 - Prob. 9.58SPCh. 9 - Prob. 9.59SPCh. 9 - Prob. 9.60SPCh. 9 - Prob. 9.61SPCh. 9 - Prob. 9.62SPCh. 9 - Prob. 9.63SPCh. 9 - Prob. 9.64SPCh. 9 - Prob. 9.65SPCh. 9 - Prob. 9.66SPCh. 9 - Prob. 9.67SPCh. 9 - Prob. 9.68SPCh. 9 - Prob. 9.69SPCh. 9 - Prob. 9.70SPCh. 9 - Prob. 9.71SPCh. 9 - Prob. 9.72SPCh. 9 - Prob. 9.73SPCh. 9 - Prob. 9.74SPCh. 9 - Prob. 9.75SPCh. 9 - Prob. 9.76SPCh. 9 - Prob. 9.77SPCh. 9 - Prob. 9.78SPCh. 9 - Prob. 9.79SPCh. 9 - Prob. 9.80SPCh. 9 - Prob. 9.81SPCh. 9 - Prob. 9.82SPCh. 9 - Prob. 9.83SPCh. 9 - Prob. 9.84SPCh. 9 - Prob. 9.85SPCh. 9 - Prob. 9.86SPCh. 9 - Prob. 9.87SPCh. 9 - Prob. 9.88SPCh. 9 - Prob. 9.89SPCh. 9 - Prob. 9.90SPCh. 9 - Prob. 9.91SPCh. 9 - Prob. 9.92SPCh. 9 - Prob. 9.93SPCh. 9 - Prob. 9.94SPCh. 9 - Prob. 9.95SPCh. 9 - Prob. 9.96SPCh. 9 - Prob. 9.97SPCh. 9 - Prob. 9.98CHPCh. 9 - Prob. 9.99CHPCh. 9 - Prob. 9.100CHPCh. 9 - Prob. 9.101CHPCh. 9 - Prob. 9.102CHPCh. 9 - Prob. 9.103CHPCh. 9 - Prob. 9.104CHPCh. 9 - Prob. 9.105CHPCh. 9 - Prob. 9.106CHPCh. 9 - Prob. 9.107CHPCh. 9 - Prob. 9.108CHPCh. 9 - Prob. 9.109CHPCh. 9 - Prob. 9.110CHPCh. 9 - Prob. 9.111CHPCh. 9 - Prob. 9.112CHPCh. 9 - Prob. 9.113CHPCh. 9 - Prob. 9.114CHPCh. 9 - Prob. 9.115CHPCh. 9 - Prob. 9.116CHPCh. 9 - Prob. 9.117CHPCh. 9 - Prob. 9.118CHPCh. 9 - Prob. 9.119CHPCh. 9 - Prob. 9.120CHPCh. 9 - Prob. 9.121CHPCh. 9 - Prob. 9.122CHPCh. 9 - Prob. 9.123CHPCh. 9 - Prob. 9.124CHPCh. 9 - Prob. 9.125CHPCh. 9 - Prob. 9.126CHPCh. 9 - Prob. 9.127CHPCh. 9 - Prob. 9.128MPCh. 9 - Prob. 9.129MPCh. 9 - Prob. 9.130MPCh. 9 - The Rankine temperature scale used in engineering...Ch. 9 - Prob. 9.132MPCh. 9 - Combustion analysis of 0.1500 g of methyl...
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