General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 9, Problem 9.103CHP
Interpretation Introduction
Interpretation:
The height of the column when the air in the column is liquefied has to be calculated.
Concept Introduction:
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There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS).
Ca, ppm
V, ppm
SCa, arb. units
SV, arb. units
20.0
10.0
14375.11
14261.02
40.0
10.0
36182.15
17997.10
60.0
10.0
39275.74
12988.01
80.0
10.0
57530.75
14268.54
100.0…
A mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C.
H₂O(g) + C₁₂O(g) = 2 HOCl(g)
K = 0.0900 at 25°C
с
Calculate the equilibrium concentrations of each gas at 25 °C.
[H₂O]=
[C₁₂O]=
[HOCI]=
M
Σ
M
What units (if any) does the response factor (K) have? Does the response factor (K) depend upon how the concentration is expressed (e.g. molarity, ppm, ppb, etc.)?
Chapter 9 Solutions
General Chemistry: Atoms First
Ch. 9.1 - Yet another common measure of pressure is the unit...Ch. 9.1 - If the density of water is 1.00 g/mL and the...Ch. 9.1 - What is the pressure in atmospheres in a container...Ch. 9.1 - Prob. 9.4CPCh. 9.2 - Prob. 9.5CPCh. 9.3 - How many moles of methane gas, CH4, are in a...Ch. 9.3 - Prob. 9.7PCh. 9.3 - Prob. 9.8PCh. 9.3 - Prob. 9.9PCh. 9.3 - Prob. 9.10CP
Ch. 9.4 - Carbonate-bearing rocks like limestone (CaCO3)...Ch. 9.4 - Prob. 9.12PCh. 9.4 - Prob. 9.13PCh. 9.5 - What is the mole fraction of each component in a...Ch. 9.5 - What is the total pressure in atmospheres and what...Ch. 9.5 - Prob. 9.16PCh. 9.5 - Prob. 9.17CPCh. 9.6 - Calculate the average speed of a nitrogen molecule...Ch. 9.6 - At what temperature does the average speed of an...Ch. 9.7 - Prob. 9.20PCh. 9.7 - Prob. 9.21PCh. 9.8 - Assume that you have 0.500 mol of N2 in a volume...Ch. 9.9 - Prob. 9.23PCh. 9.9 - For ether, a partial pressure of 15 mm Hg results...Ch. 9.9 - Prob. 9.25PCh. 9 - Prob. 9.26CPCh. 9 - Prob. 9.27CPCh. 9 - Prob. 9.28CPCh. 9 - Prob. 9.29CPCh. 9 - Assume that you have a mixture of He (atomic...Ch. 9 - Prob. 9.31CPCh. 9 - Prob. 9.32CPCh. 9 - Prob. 9.33CPCh. 9 - Prob. 9.34CPCh. 9 - Prob. 9.36SPCh. 9 - Prob. 9.37SPCh. 9 - Prob. 9.38SPCh. 9 - Prob. 9.39SPCh. 9 - Prob. 9.40SPCh. 9 - Prob. 9.41SPCh. 9 - Assume that you have an open-end manometer filled...Ch. 9 - Assume that you have an open-end manometer filled...Ch. 9 - Prob. 9.44SPCh. 9 - Prob. 9.45SPCh. 9 - Prob. 9.46SPCh. 9 - Prob. 9.47SPCh. 9 - Prob. 9.48SPCh. 9 - Prob. 9.49SPCh. 9 - Prob. 9.50SPCh. 9 - Prob. 9.51SPCh. 9 - Prob. 9.52SPCh. 9 - Prob. 9.53SPCh. 9 - Prob. 9.54SPCh. 9 - Prob. 9.55SPCh. 9 - Prob. 9.56SPCh. 9 - Prob. 9.57SPCh. 9 - Prob. 9.58SPCh. 9 - Prob. 9.59SPCh. 9 - Prob. 9.60SPCh. 9 - Prob. 9.61SPCh. 9 - Prob. 9.62SPCh. 9 - Prob. 9.63SPCh. 9 - Prob. 9.64SPCh. 9 - Prob. 9.65SPCh. 9 - Prob. 9.66SPCh. 9 - Prob. 9.67SPCh. 9 - Prob. 9.68SPCh. 9 - Prob. 9.69SPCh. 9 - Prob. 9.70SPCh. 9 - Prob. 9.71SPCh. 9 - Prob. 9.72SPCh. 9 - Prob. 9.73SPCh. 9 - Prob. 9.74SPCh. 9 - Prob. 9.75SPCh. 9 - Prob. 9.76SPCh. 9 - Prob. 9.77SPCh. 9 - Prob. 9.78SPCh. 9 - Prob. 9.79SPCh. 9 - Prob. 9.80SPCh. 9 - Prob. 9.81SPCh. 9 - Prob. 9.82SPCh. 9 - Prob. 9.83SPCh. 9 - Prob. 9.84SPCh. 9 - Prob. 9.85SPCh. 9 - Prob. 9.86SPCh. 9 - Prob. 9.87SPCh. 9 - Prob. 9.88SPCh. 9 - Prob. 9.89SPCh. 9 - Prob. 9.90SPCh. 9 - Prob. 9.91SPCh. 9 - Prob. 9.92SPCh. 9 - Prob. 9.93SPCh. 9 - Prob. 9.94SPCh. 9 - Prob. 9.95SPCh. 9 - Prob. 9.96SPCh. 9 - Prob. 9.97SPCh. 9 - Prob. 9.98CHPCh. 9 - Prob. 9.99CHPCh. 9 - Prob. 9.100CHPCh. 9 - Prob. 9.101CHPCh. 9 - Prob. 9.102CHPCh. 9 - Prob. 9.103CHPCh. 9 - Prob. 9.104CHPCh. 9 - Prob. 9.105CHPCh. 9 - Prob. 9.106CHPCh. 9 - Prob. 9.107CHPCh. 9 - Prob. 9.108CHPCh. 9 - Prob. 9.109CHPCh. 9 - Prob. 9.110CHPCh. 9 - Prob. 9.111CHPCh. 9 - Prob. 9.112CHPCh. 9 - Prob. 9.113CHPCh. 9 - Prob. 9.114CHPCh. 9 - Prob. 9.115CHPCh. 9 - Prob. 9.116CHPCh. 9 - Prob. 9.117CHPCh. 9 - Prob. 9.118CHPCh. 9 - Prob. 9.119CHPCh. 9 - Prob. 9.120CHPCh. 9 - Prob. 9.121CHPCh. 9 - Prob. 9.122CHPCh. 9 - Prob. 9.123CHPCh. 9 - Prob. 9.124CHPCh. 9 - Prob. 9.125CHPCh. 9 - Prob. 9.126CHPCh. 9 - Prob. 9.127CHPCh. 9 - Prob. 9.128MPCh. 9 - Prob. 9.129MPCh. 9 - Prob. 9.130MPCh. 9 - The Rankine temperature scale used in engineering...Ch. 9 - Prob. 9.132MPCh. 9 - Combustion analysis of 0.1500 g of methyl...
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