General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 9, Problem 9.131MP
The Rankine temperature scale used in engineering is to the Fahrenheit scale as the Kelvin scale is to the Celsius scale. That is, 1 Rankine degree is the same size as 1 Fahrenheit degree, and 0 °R = absolute zero.
- (a) What temperature corresponds to the freezing point of water on the Rankine scale?
- (b) What is the value of the gas constant R on the Rankine scale in (L · atm)/( °R · mol)?
- (c) Use the van der Waals equation to determine the pressure inside a 400.0 mL vessel that contains 2.50 mol of CH4 at a temperature of 525 °R. For CH4, a = 2.253 (L2 · atm)/mol2; b = 0.04278 L/mol.
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111
States of Matter
Understanding conceptual components of the enthalpy of solution
0/5
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A small amount of acetonitrile (CH, CN) is dissolved in a large amount of water. Imagine separating this process into the four stages sketched below. (These
sketches show only a portion of the substances, so you can see the density and distribution of atoms and molecules in them.)
CH,CN
H₂O
B
88
C
Use these sketches to answer the questions in the table below.
The enthalpy of solution AH is negative
soln
when CH3CN dissolves in water. Use this
information to list the stages in order of increasing
enthalpy.
Would heat be absorbed or released if the system
moved from Stage C to D?
What force would oppose or favor the system
moving from Stage C to D? Check all that apply.
1
absorbed
O released
neither absorbed nor released.
none
O ionic bonding force
covalent bonding force…
In a system with an anodic overpotential, the variation of ŋ as a function of
the current density:
1. at low fields is linear 2. at higher fields, it follows Tafel's law
Find the range of current densities for which the overpotential has the same
value as when calculated for cases 1 and 2 (maximum relative difference of
5% with respect to the behavior for higher fields). To which overpotential
range does this correspond?
Data: 10 = 1.5 mA cm², T = 300°C, ẞ = 0.64, R = 8.314 J K 1 mol¹ and F = 96485
C mol-1.
Indicate 10.6 with only one significant figure.
Chapter 9 Solutions
General Chemistry: Atoms First
Ch. 9.1 - Yet another common measure of pressure is the unit...Ch. 9.1 - If the density of water is 1.00 g/mL and the...Ch. 9.1 - What is the pressure in atmospheres in a container...Ch. 9.1 - Prob. 9.4CPCh. 9.2 - Prob. 9.5CPCh. 9.3 - How many moles of methane gas, CH4, are in a...Ch. 9.3 - Prob. 9.7PCh. 9.3 - Prob. 9.8PCh. 9.3 - Prob. 9.9PCh. 9.3 - Prob. 9.10CP
Ch. 9.4 - Carbonate-bearing rocks like limestone (CaCO3)...Ch. 9.4 - Prob. 9.12PCh. 9.4 - Prob. 9.13PCh. 9.5 - What is the mole fraction of each component in a...Ch. 9.5 - What is the total pressure in atmospheres and what...Ch. 9.5 - Prob. 9.16PCh. 9.5 - Prob. 9.17CPCh. 9.6 - Calculate the average speed of a nitrogen molecule...Ch. 9.6 - At what temperature does the average speed of an...Ch. 9.7 - Prob. 9.20PCh. 9.7 - Prob. 9.21PCh. 9.8 - Assume that you have 0.500 mol of N2 in a volume...Ch. 9.9 - Prob. 9.23PCh. 9.9 - For ether, a partial pressure of 15 mm Hg results...Ch. 9.9 - Prob. 9.25PCh. 9 - Prob. 9.26CPCh. 9 - Prob. 9.27CPCh. 9 - Prob. 9.28CPCh. 9 - Prob. 9.29CPCh. 9 - Assume that you have a mixture of He (atomic...Ch. 9 - Prob. 9.31CPCh. 9 - Prob. 9.32CPCh. 9 - Prob. 9.33CPCh. 9 - Prob. 9.34CPCh. 9 - Prob. 9.36SPCh. 9 - Prob. 9.37SPCh. 9 - Prob. 9.38SPCh. 9 - Prob. 9.39SPCh. 9 - Prob. 9.40SPCh. 9 - Prob. 9.41SPCh. 9 - Assume that you have an open-end manometer filled...Ch. 9 - Assume that you have an open-end manometer filled...Ch. 9 - Prob. 9.44SPCh. 9 - Prob. 9.45SPCh. 9 - Prob. 9.46SPCh. 9 - Prob. 9.47SPCh. 9 - Prob. 9.48SPCh. 9 - Prob. 9.49SPCh. 9 - Prob. 9.50SPCh. 9 - Prob. 9.51SPCh. 9 - Prob. 9.52SPCh. 9 - Prob. 9.53SPCh. 9 - Prob. 9.54SPCh. 9 - Prob. 9.55SPCh. 9 - Prob. 9.56SPCh. 9 - Prob. 9.57SPCh. 9 - Prob. 9.58SPCh. 9 - Prob. 9.59SPCh. 9 - Prob. 9.60SPCh. 9 - Prob. 9.61SPCh. 9 - Prob. 9.62SPCh. 9 - Prob. 9.63SPCh. 9 - Prob. 9.64SPCh. 9 - Prob. 9.65SPCh. 9 - Prob. 9.66SPCh. 9 - Prob. 9.67SPCh. 9 - Prob. 9.68SPCh. 9 - Prob. 9.69SPCh. 9 - Prob. 9.70SPCh. 9 - Prob. 9.71SPCh. 9 - Prob. 9.72SPCh. 9 - Prob. 9.73SPCh. 9 - Prob. 9.74SPCh. 9 - Prob. 9.75SPCh. 9 - Prob. 9.76SPCh. 9 - Prob. 9.77SPCh. 9 - Prob. 9.78SPCh. 9 - Prob. 9.79SPCh. 9 - Prob. 9.80SPCh. 9 - Prob. 9.81SPCh. 9 - Prob. 9.82SPCh. 9 - Prob. 9.83SPCh. 9 - Prob. 9.84SPCh. 9 - Prob. 9.85SPCh. 9 - Prob. 9.86SPCh. 9 - Prob. 9.87SPCh. 9 - Prob. 9.88SPCh. 9 - Prob. 9.89SPCh. 9 - Prob. 9.90SPCh. 9 - Prob. 9.91SPCh. 9 - Prob. 9.92SPCh. 9 - Prob. 9.93SPCh. 9 - Prob. 9.94SPCh. 9 - Prob. 9.95SPCh. 9 - Prob. 9.96SPCh. 9 - Prob. 9.97SPCh. 9 - Prob. 9.98CHPCh. 9 - Prob. 9.99CHPCh. 9 - Prob. 9.100CHPCh. 9 - Prob. 9.101CHPCh. 9 - Prob. 9.102CHPCh. 9 - Prob. 9.103CHPCh. 9 - Prob. 9.104CHPCh. 9 - Prob. 9.105CHPCh. 9 - Prob. 9.106CHPCh. 9 - Prob. 9.107CHPCh. 9 - Prob. 9.108CHPCh. 9 - Prob. 9.109CHPCh. 9 - Prob. 9.110CHPCh. 9 - Prob. 9.111CHPCh. 9 - Prob. 9.112CHPCh. 9 - Prob. 9.113CHPCh. 9 - Prob. 9.114CHPCh. 9 - Prob. 9.115CHPCh. 9 - Prob. 9.116CHPCh. 9 - Prob. 9.117CHPCh. 9 - Prob. 9.118CHPCh. 9 - Prob. 9.119CHPCh. 9 - Prob. 9.120CHPCh. 9 - Prob. 9.121CHPCh. 9 - Prob. 9.122CHPCh. 9 - Prob. 9.123CHPCh. 9 - Prob. 9.124CHPCh. 9 - Prob. 9.125CHPCh. 9 - Prob. 9.126CHPCh. 9 - Prob. 9.127CHPCh. 9 - Prob. 9.128MPCh. 9 - Prob. 9.129MPCh. 9 - Prob. 9.130MPCh. 9 - The Rankine temperature scale used in engineering...Ch. 9 - Prob. 9.132MPCh. 9 - Combustion analysis of 0.1500 g of methyl...
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