Organic And Biological Chemistry
7th Edition
ISBN: 9781305081079
Author: STOKER, H. Stephen (howard Stephen)
Publisher: Cengage Learning,
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Chapter 8.6, Problem 1QQ
Interpretation Introduction
Interpretation: The number of product molecules obtained by the complete hydrolysis of one molecule of a fat or oil has to be predicted.
Concept introduction: A hydrolysis reaction carried out in a basic solution is known as saponification reaction. The saponification of fats and oils gives fatty acid salts and glycerol.
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Consider this step in a radical reaction:
Y
What type of step is this? Check all that apply.
Draw the products of the step on the right-hand side of the drawing area
below. If more than one set of products is possible, draw any set.
Also, draw the mechanism arrows on the left-hand side of the drawing
area to show how this happens.
ionization
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initialization
passivation
none of the above
22.16 The following groups are ortho-para directors.
(a)
-C=CH₂
H
(d)
-Br
(b)
-NH2
(c)
-OCHS
Draw a contributing structure for the resonance-stabilized cation formed during elec-
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22.17 Predict the major product or products from treatment of each compound with
Cl₁/FeCl₂-
OH
(b)
NO2
CHO
22.18 How do you account for the fact that phenyl acetate is less reactive toward electro-
philic aromatic substitution than anisole?
Phenyl acetate
Anisole
CH
(d)
Chapter 8 Solutions
Organic And Biological Chemistry
Ch. 8.1 - Prob. 1QQCh. 8.1 - Which of the following is not a biochemical...Ch. 8.1 - The saponifiable/nonsaponifiable classification...Ch. 8.2 - Prob. 1QQCh. 8.2 - Prob. 2QQCh. 8.2 - Prob. 3QQCh. 8.2 - Prob. 4QQCh. 8.3 - Prob. 1QQCh. 8.3 - Prob. 2QQCh. 8.4 - How many structural subunits are present in the...
Ch. 8.4 - Prob. 2QQCh. 8.4 - Prob. 3QQCh. 8.4 - How many different mixed triglyceride molecules...Ch. 8.4 - Prob. 5QQCh. 8.4 - Unsaturated fatty acid residues are structural...Ch. 8.5 - Prob. 1QQCh. 8.5 - Prob. 2QQCh. 8.5 - Prob. 3QQCh. 8.6 - Prob. 1QQCh. 8.6 - Prob. 2QQCh. 8.6 - Prob. 3QQCh. 8.6 - Prob. 4QQCh. 8.6 - Prob. 5QQCh. 8.6 - Prob. 6QQCh. 8.7 - Based on biological function, phospholipids are...Ch. 8.7 - Prob. 2QQCh. 8.7 - Which of the following statements about the...Ch. 8.7 - When the head and two tails structural model is...Ch. 8.7 - Prob. 5QQCh. 8.7 - Prob. 6QQCh. 8.8 - The number of structural building blocks present...Ch. 8.8 - Prob. 2QQCh. 8.9 - Prob. 1QQCh. 8.9 - Which of the following types of membrane lipids...Ch. 8.9 - Prob. 3QQCh. 8.10 - Which of the following is a correct representation...Ch. 8.10 - Prob. 2QQCh. 8.10 - Prob. 3QQCh. 8.10 - Prob. 4QQCh. 8.10 - Which of the following membrane transport...Ch. 8.11 - Which of the following statements concerning bile...Ch. 8.11 - Which of the following statements concerning...Ch. 8.12 - Which of the following statements concerning...Ch. 8.12 - Prob. 2QQCh. 8.12 - Prob. 3QQCh. 8.13 - Prob. 1QQCh. 8.13 - Aspirin reduces inflammation and fever by...Ch. 8.13 - Prob. 3QQCh. 8.14 - Prob. 1QQCh. 8.14 - Prob. 2QQCh. 8.14 - Prob. 3QQCh. 8.15 - In which of the following pairs of lipid types are...Ch. 8.15 - Prob. 2QQCh. 8.15 - Prob. 3QQCh. 8 - Indicate whether each of the following general...Ch. 8 - Indicate whether each of the following general...Ch. 8 - Would you expect lipids to be soluble or insoluble...Ch. 8 - Would you expect lipids to be soluble or insoluble...Ch. 8 - What is the biochemical function category for each...Ch. 8 - What is the biochemical function category for each...Ch. 8 - Classify each of the following fatty acids as...Ch. 8 - Classify each of the following fatty acids as...Ch. 8 - Classify each of the following fatty acids as...Ch. 8 - Prob. 8.10EPCh. 8 - Prob. 8.11EPCh. 8 - Prob. 8.12EPCh. 8 - Prob. 8.13EPCh. 8 - Prob. 8.14EPCh. 8 - Classify each of the fatty acids in Problem 19-13...Ch. 8 - Prob. 8.16EPCh. 8 - Draw the condensed structural formula for the...Ch. 8 - Draw the condensed structural formula for the...Ch. 8 - Prob. 8.19EPCh. 8 - Prob. 8.20EPCh. 8 - What is the relationship between carbon chain...Ch. 8 - What is the relationship between degree of...Ch. 8 - What structural change is associated with the...Ch. 8 - Prob. 8.24EPCh. 8 - In each of the following pairs of fatty acids,...Ch. 8 - In each of the following pairs of fatty acids,...Ch. 8 - What are the four structural subunits that...Ch. 8 - Draw the general block diagram for a...Ch. 8 - Prob. 8.29EPCh. 8 - Determine the following for a triacylglycerol in...Ch. 8 - Draw the condensed structural formula of a...Ch. 8 - Draw the condensed structural formula of a...Ch. 8 - Draw block diagram structures for the four...Ch. 8 - Draw block diagram structures for the three...Ch. 8 - Identify, by common name, fatty acids present in...Ch. 8 - Identify, by common name, fatty acids present in...Ch. 8 - A mixture of triacylglycerol molecules contains...Ch. 8 - Prob. 8.38EPCh. 8 - For each of the triacylglycerol molecules in...Ch. 8 - Prob. 8.40EPCh. 8 - Prob. 8.41EPCh. 8 - Prob. 8.42EPCh. 8 - Prob. 8.43EPCh. 8 - Prob. 8.44EPCh. 8 - In a dietary context, classify each of the...Ch. 8 - In a dietary context, classify each of the...Ch. 8 - Prob. 8.47EPCh. 8 - Prob. 8.48EPCh. 8 - What are the general names for the products...Ch. 8 - What additional products are formed when a...Ch. 8 - Classify each of the reaction situations in...Ch. 8 - Prob. 8.52EPCh. 8 - Draw condensed structural formulas for all...Ch. 8 - Draw condensed structural formulas for all...Ch. 8 - Draw condensed structural formulas for all...Ch. 8 - Draw condensed structural formulas for all...Ch. 8 - Why can only unsaturated triacylglycerols undergo...Ch. 8 - Prob. 8.58EPCh. 8 - How many molecules of H2 will react with one...Ch. 8 - How many molecules of H2 will react with one...Ch. 8 - Prob. 8.61EPCh. 8 - Prob. 8.62EPCh. 8 - Prob. 8.63EPCh. 8 - Prob. 8.64EPCh. 8 - Prob. 8.65EPCh. 8 - Prob. 8.66EPCh. 8 - Prob. 8.67EPCh. 8 - Prob. 8.68EPCh. 8 - The following is a block diagram for a...Ch. 8 - Prob. 8.70EPCh. 8 - What structural subunits in the block diagram for...Ch. 8 - Prob. 8.72EPCh. 8 - Prob. 8.73EPCh. 8 - Prob. 8.74EPCh. 8 - Based on the head and two tails model for the...Ch. 8 - Prob. 8.76EPCh. 8 - Prob. 8.77EPCh. 8 - Prob. 8.78EPCh. 8 - Prob. 8.79EPCh. 8 - Prob. 8.80EPCh. 8 - Prob. 8.81EPCh. 8 - Prob. 8.82EPCh. 8 - Prob. 8.83EPCh. 8 - What portion or portions of the structure of a...Ch. 8 - Which of the terms triacylglycerol,...Ch. 8 - Prob. 8.86EPCh. 8 - Which of the terms triacylglycerol,...Ch. 8 - Which of the terms triacylglycerol,...Ch. 8 - Prob. 8.89EPCh. 8 - Prob. 8.90EPCh. 8 - Prob. 8.91EPCh. 8 - Prob. 8.92EPCh. 8 - Prob. 8.93EPCh. 8 - Prob. 8.94EPCh. 8 - Indicate whether each of the following statements...Ch. 8 - Prob. 8.96EPCh. 8 - Prob. 8.97EPCh. 8 - Prob. 8.98EPCh. 8 - Prob. 8.99EPCh. 8 - Prob. 8.100EPCh. 8 - In a dietary context, what is the difference...Ch. 8 - In a dietary context, how do HDL and LDL differ in...Ch. 8 - What is the general structural characteristic...Ch. 8 - What constitutes the two outside surfaces of a...Ch. 8 - Indicate whether each of the following statements...Ch. 8 - Indicate whether each of the following statements...Ch. 8 - What is the function of unsaturation in the...Ch. 8 - Prob. 8.108EPCh. 8 - Prob. 8.109EPCh. 8 - Prob. 8.110EPCh. 8 - Prob. 8.111EPCh. 8 - Prob. 8.112EPCh. 8 - Prob. 8.113EPCh. 8 - Prob. 8.114EPCh. 8 - Prob. 8.115EPCh. 8 - Prob. 8.116EPCh. 8 - Prob. 8.117EPCh. 8 - Prob. 8.118EPCh. 8 - Prob. 8.119EPCh. 8 - Indicate whether each of the following statements...Ch. 8 - Prob. 8.121EPCh. 8 - Prob. 8.122EPCh. 8 - Prob. 8.123EPCh. 8 - Prob. 8.124EPCh. 8 - What is the medium through which bile acids are...Ch. 8 - Prob. 8.126EPCh. 8 - Prob. 8.127EPCh. 8 - Prob. 8.128EPCh. 8 - Prob. 8.129EPCh. 8 - Classify each of the following as (1) an...Ch. 8 - Prob. 8.131EPCh. 8 - Prob. 8.132EPCh. 8 - Prob. 8.133EPCh. 8 - Prob. 8.134EPCh. 8 - Prob. 8.135EPCh. 8 - Prob. 8.136EPCh. 8 - Prob. 8.137EPCh. 8 - Prob. 8.138EPCh. 8 - Prob. 8.139EPCh. 8 - Prob. 8.140EPCh. 8 - What is the major structural difference between a...Ch. 8 - What is the major structural difference between a...Ch. 8 - What structural feature distinguishes a...Ch. 8 - What structural feature distinguishes a...Ch. 8 - Classify each of the following types of lipids as...Ch. 8 - Classify each of the following types of lipids as...Ch. 8 - Classify each of the following types of lipids as...Ch. 8 - Prob. 8.148EPCh. 8 - Prob. 8.149EPCh. 8 - Draw the condensed structural formula of a wax...Ch. 8 - Prob. 8.151EPCh. 8 - Biological waxes have a head and two tails...Ch. 8 - Prob. 8.153EPCh. 8 - Prob. 8.154EPCh. 8 - Prob. 8.155EPCh. 8 - Prob. 8.156EPCh. 8 - Prob. 8.157EPCh. 8 - Prob. 8.158EPCh. 8 - Prob. 8.159EPCh. 8 - Prob. 8.160EPCh. 8 - Prob. 8.161EPCh. 8 - Prob. 8.162EP
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