The classification of the given reaction situation as involving whether complete hydrolysis or partial hydrolysis has to be predicted. Concept introduction: Triacylglycerol is produced by the reaction of one molecule of glycerol and three molecules of fatty acid. The three hydroxyl groups of glycerol get esterified on reaction with fatty acids. The hydrolysis of triacylglycerol is carried out in the presence of an acid or a base. The hydrolysis of triacylglycerol takes place in the presence of an acid forms glycerol and fatty acid as the desired products. The hydrolysis of triacylglycerol takes place in the presence of a base forms glycerol and fatty acid salts as the desired products.

Question

#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv

Answer 1

Question

Chapter 8, Problem 8.52EP

(a)

Interpretation Introduction

Interpretation: The classification of the given reaction situation as involving whether complete hydrolysis or partial hydrolysis has to be predicted.

Concept introduction: Triacylglycerol is produced by the reaction of one molecule of glycerol and three molecules of fatty acid. The three hydroxyl groups of glycerol get esterified on reaction with fatty acids.

The hydrolysis of triacylglycerol is carried out in the presence of an acid or a base. The hydrolysis of triacylglycerol takes place in the presence of an acid forms glycerol and fatty acid as the desired products. The hydrolysis of triacylglycerol takes place in the presence of a base forms glycerol and fatty acid salts as the desired products.

(b)

Interpretation Introduction

Interpretation: The classification of the given reaction situation as involving whether complete hydrolysis or partial hydrolysis has to be predicted.

Concept introduction: Triacylglycerol is produced by the reaction of one molecule of glycerol and three molecules of fatty acid. The three hydroxyl groups of glycerol get esterified on reaction with fatty acids.

The hydrolysis of triacylglycerol is carried out in the presence of an acid or a base. The hydrolysis of triacylglycerol takes place in the presence of an acid forms glycerol and fatty acid as the desired products. The hydrolysis of triacylglycerol takes place in the presence of a base forms glycerol and fatty acid salts as the desired products.

(c)

Interpretation Introduction

Interpretation: The classification of the given reaction situation as involving whether complete hydrolysis or partial hydrolysis has to be predicted.

Concept introduction: Triacylglycerol is produced by the reaction of one molecule of glycerol and three molecules of fatty acid. The three hydroxyl groups of glycerol get esterified on reaction with fatty acids.

The hydrolysis of triacylglycerol is carried out in the presence of an acid or a base. The hydrolysis of triacylglycerol takes place in the presence of an acid forms glycerol and fatty acid as the desired products. The hydrolysis of triacylglycerol takes place in the presence of a base forms glycerol and fatty acid salts as the desired products.

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."