Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 7, Problem 7QRT
Interpretation Introduction
Interpretation:
A molecule with polar bonds can be a nonpolar molecule has to be shown using an example.
Concept Introduction:
A polar molecule is a molecule where the polar bonds are asymmetrically arranged (the dipoles do not cancel)
A nonpolar molecule is a molecule with no polar bonds or a molecule where the polar bonds are symmetrically arranged.
In polar molecule the charge separation occurred with respect to the difference in electronegativity of atoms in the molecule.
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 7 Solutions
Chemistry: The Molecular Science
Ch. 7.2 - Identify the electron-region geometry, the...Ch. 7.2 - Based on the discussion so far, identify a...Ch. 7.2 - Prob. 7.2PSPCh. 7.2 - Determine the electron-region geometry and the...Ch. 7.2 - Prob. 7.2CECh. 7.2 - Prob. 7.3ECh. 7.2 - Prob. 7.4PSPCh. 7.4 - Using hybridization and sigma and pi bonding,...Ch. 7.4 - Prob. 7.4CECh. 7.5 - Decide whether each molecule is polar and, if so,...
Ch. 7.5 - Prob. 7.5ECh. 7.6 - Prob. 7.8PSPCh. 7.6 - Prob. 7.7CECh. 7.6 - Prob. 7.9PSPCh. 7.7 - Prob. 7.8CECh. 7.7 - Prob. 7.9CECh. 7 - Write the Lewis structures and give the...Ch. 7 - The structural formula for the open-chain form of...Ch. 7 - Describe the VSEPR model. How is the model used to...Ch. 7 - What is the difference between the electron-region...Ch. 7 - Prob. 3QRTCh. 7 - Prob. 4QRTCh. 7 - If you have three electron regions around a...Ch. 7 - Prob. 6QRTCh. 7 - Prob. 7QRTCh. 7 - Prob. 8QRTCh. 7 - Prob. 9QRTCh. 7 - Prob. 10QRTCh. 7 - Prob. 11QRTCh. 7 - Prob. 12QRTCh. 7 - Prob. 13QRTCh. 7 - Prob. 14QRTCh. 7 - Prob. 15QRTCh. 7 - Prob. 16QRTCh. 7 - Write Lewis structures for XeOF2 and ClOF3. Use...Ch. 7 - Write Lewis structures for HCP and [IOF4]. Use...Ch. 7 - Prob. 19QRTCh. 7 - Prob. 20QRTCh. 7 - Explain why (I3)+ is bent, but (I3) is linear.Ch. 7 - Prob. 22QRTCh. 7 - Prob. 23QRTCh. 7 - Give approximate values for the indicated bond...Ch. 7 - Give approximate values for the indicated bond...Ch. 7 - Prob. 26QRTCh. 7 - Compare the FClF angles in ClF2+ and ClF2. From...Ch. 7 - Prob. 28QRTCh. 7 - Prob. 29QRTCh. 7 - Prob. 30QRTCh. 7 - Prob. 31QRTCh. 7 - Describe the geometry and hybridization of carbon...Ch. 7 - Describe the geometry and hybridization for each C...Ch. 7 - Describe the hybridization around the central atom...Ch. 7 - The hybridization of the two carbon atoms differs...Ch. 7 - The hybridization of the two nitrogen atoms...Ch. 7 - Identify the type of hybridization, approximate...Ch. 7 - Prob. 38QRTCh. 7 - Prob. 39QRTCh. 7 - Prob. 40QRTCh. 7 - Prob. 41QRTCh. 7 - Methylcyanoacrylate is the active ingredient in...Ch. 7 - Prob. 43QRTCh. 7 - Prob. 44QRTCh. 7 - Prob. 45QRTCh. 7 - Prob. 46QRTCh. 7 - Which of these molecules has a net dipole moment?...Ch. 7 - Prob. 48QRTCh. 7 - Use molecular structures and noncovalent...Ch. 7 - Prob. 50QRTCh. 7 - Explain why water “beads up” on a freshly waxed...Ch. 7 - Explain why water will not remove tar from your...Ch. 7 - Prob. 53QRTCh. 7 - Prob. 54QRTCh. 7 - Prob. 55QRTCh. 7 - Prob. 56QRTCh. 7 - The structural formula for vitamin C is Give a...Ch. 7 - Prob. 58QRTCh. 7 - Prob. 59QRTCh. 7 - Prob. 60QRTCh. 7 - Prob. 61QRTCh. 7 - Prob. 62QRTCh. 7 - Prob. 63QRTCh. 7 - Prob. 64QRTCh. 7 - Prob. 65QRTCh. 7 - Prob. 66QRTCh. 7 - Methylcyanoacrylate is the active ingredient in...Ch. 7 - Prob. 68QRTCh. 7 - Prob. 69QRTCh. 7 - Use Lewis structures and VSEPR theory to predict...Ch. 7 - In addition to CO, CO2, and C3O2, there is another...Ch. 7 - Prob. 72QRTCh. 7 - Prob. 73QRTCh. 7 - Prob. 74QRTCh. 7 - Prob. 75QRTCh. 7 - In the gas phase, positive and negative ions form...Ch. 7 - Prob. 77QRTCh. 7 - Prob. 78QRTCh. 7 - Prob. 79QRTCh. 7 - Prob. 80QRTCh. 7 - Prob. 81QRTCh. 7 - Prob. 82QRTCh. 7 - Prob. 83QRTCh. 7 - Prob. 84QRTCh. 7 - Prob. 85QRTCh. 7 - Prob. 86QRTCh. 7 - Prob. 87QRTCh. 7 - Prob. 88QRTCh. 7 - Prob. 89QRTCh. 7 - Prob. 90QRTCh. 7 - Prob. 91QRTCh. 7 - Prob. 92QRTCh. 7 - Prob. 93QRTCh. 7 - Prob. 94QRTCh. 7 - Which of these are examples of hydrogen bonding?Ch. 7 - Prob. 96QRTCh. 7 - Prob. 97QRTCh. 7 - Prob. 98QRTCh. 7 - Halothane, which had been used as an anesthetic,...Ch. 7 - Ketene, C2H2O, is a reactant for synthesizing...Ch. 7 - Gamma hydroxybutyric acid, GHB, infamous as a date...Ch. 7 - There are two compounds with the molecular formula...Ch. 7 - Piperine, the active ingredient in black pepper,...Ch. 7 - Prob. 105QRTCh. 7 - Two compounds have the molecular formula N3H3. One...Ch. 7 - Prob. 108QRTCh. 7 - Prob. 109QRTCh. 7 - Prob. 110QRTCh. 7 - Prob. 111QRTCh. 7 - Prob. 7.ACPCh. 7 - Prob. 7.BCPCh. 7 - Prob. 7.CCPCh. 7 - Prob. 7.DCP
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