Organic And Biological Chemistry
Organic And Biological Chemistry
7th Edition
ISBN: 9781305081079
Author: STOKER, H. Stephen (howard Stephen)
Publisher: Cengage Learning,
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Concept explainers

Carbohydrates
Carbohydrates are the organic compounds that are obtained in foods and living matters in the shape of sugars, cellulose, and starch. The general formula of carbohydrates is Cn(H2O)2. The ratio of H and O present in carbohydrates is identical to water.
Starch
Starch is a polysaccharide carbohydrate that belongs to the category of polysaccharide carbohydrates.
Mutarotation
The rotation of a particular structure of the chiral compound because of the epimerization is called mutarotation. It is the repercussion of the ring chain tautomerism. In terms of glucose, this can be defined as the modification in the equilibrium of th…
L Sugar
A chemical compound that is represented with a molecular formula C6H12O6 is called L-(-) sugar. At the carbon’s 5th position, the hydroxyl group is placed to the compound’s left and therefore the sugar is represented as L(-)-sugar. It is capable of rotat…
Question
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Chapter 7, Problem 7.135EP

(a)

Interpretation Introduction

Interpretation: The term monosaccharide, disaccharide, reducing sugar, anomers, enantiomer and aldohexoses whether applies to both the members of the given pair or not has to be stated.

Concept introduction: Monosaccharides are those type of sugars which cannot be hydrolysed further.

Disaccharides are those type of sugars which have two units of monosaccharides.

The enantiomers are the molecules that form non-superimposable mirror images of each other.

Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.  The molecule containing the anomeric carbon is called anomer.

The monosaccharides that have aldehyde as a functional group and a long chain of six carbon atoms are called aldohexoses.

The sugars that have a free carbonyl group are called reducing sugars.

(b)

Interpretation Introduction

Interpretation: The term monosaccharide, disaccharide, reducing sugar, anomers, enantiomer and aldohexoses whether applies to both the members of the given pair or not has to be stated.

Concept introduction: Monosaccharides are those type of sugars which cannot be hydrolysed further.

Disaccharides are those type of sugars which have two units of monosaccharides.

The enantiomers are the molecules that form non-superimposable mirror images of each other.

Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.  The molecule containing the anomeric carbon is called anomer.

The monosaccharides that have aldehyde as a functional group and a long chain of six carbon atoms are called aldohexoses.

The sugars that have a free carbonyl group are called reducing sugars.

(c)

Interpretation Introduction

Interpretation: The term monosaccharide, disaccharide, reducing sugar, anomers, enantiomer and aldohexoses whether applies to both the members of the given pair or not has to be stated.

Concept introduction: Monosaccharides are those type of sugars which cannot be hydrolysed further.

Disaccharides are those type of sugars which have two units of monosaccharides.

The enantiomers are the molecules that form non-superimposable mirror images of each other.

Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.  The molecule containing the anomeric carbon is called anomer.

The monosaccharides that have aldehyde as a functional group and a long chain of six carbon atoms are called aldohexoses.

The sugars that have a free carbonyl group are called reducing sugars.

(d)

Interpretation Introduction

Interpretation: The term monosaccharide, disaccharide, reducing sugar, anomers, enantiomer and aldohexoses whether applies to both the members of the given pair or not has to be stated.

Concept introduction: Monosaccharides are those type of sugars which cannot be hydrolysed further.

Disaccharides are those type of sugars which have two units of monosaccharides.

The enantiomers are the molecules that form non-superimposable mirror images of each other.

Carbon atom which behaves as a stereocenter in the cyclic form of the hemiacetal compound is known as anomeric carbon.  The molecule containing the anomeric carbon is called anomer.

The monosaccharides that have aldehyde as a functional group and a long chain of six carbon atoms are called aldohexoses.

The sugars that have a free carbonyl group are called reducing sugars.

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Please answer the question and provide a detailed drawing of the structure. If there will not be a new C – C bond, then the box under the drawing area will be checked.  Will the following reaction make a molecule with a new C – C bond as its major product:  Draw the major organic product or products, if the reaction will work. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry.
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Chapter 7 Solutions

Organic And Biological Chemistry

Ch. 7.1 - In terms of mass percent, which of the following...Ch. 7.1 - Which of the following is the most abundant type...Ch. 7.2 - Which of the following statements concerning the...Ch. 7.2 - Prob. 2QQCh. 7.3 - Prob. 1QQCh. 7.3 - Prob. 2QQCh. 7.3 - Which of the following is not a possible value for...Ch. 7.3 - The complete hydrolysis of a polysaccharide...Ch. 7.4 - Prob. 1QQCh. 7.4 - Prob. 2QQ
Ch. 7.4 - Prob. 3QQCh. 7.4 - Prob. 4QQCh. 7.5 - Prob. 1QQCh. 7.5 - Prob. 2QQCh. 7.6 - Prob. 1QQCh. 7.6 - Which of the following Fischer projection formulas...Ch. 7.6 - Prob. 3QQCh. 7.6 - Prob. 4QQCh. 7.7 - Prob. 1QQCh. 7.7 - Prob. 2QQCh. 7.8 - Prob. 1QQCh. 7.8 - Which of the following statements about...Ch. 7.8 - Prob. 3QQCh. 7.9 - Prob. 1QQCh. 7.9 - Prob. 2QQCh. 7.9 - Prob. 3QQCh. 7.9 - In which of the following pairs of monosaccharides...Ch. 7.9 - In which of the following pairs of monosaccharides...Ch. 7.10 - Prob. 1QQCh. 7.10 - Which of the following structures represents a...Ch. 7.10 - Prob. 3QQCh. 7.10 - Prob. 4QQCh. 7.10 - Prob. 5QQCh. 7.11 - Prob. 1QQCh. 7.11 - Which of the following is the correct Haworth...Ch. 7.12 - Prob. 1QQCh. 7.12 - Prob. 2QQCh. 7.12 - Prob. 3QQCh. 7.12 - Prob. 4QQCh. 7.12 - Prob. 5QQCh. 7.13 - Which of the following disaccharides contains...Ch. 7.13 - Which of the following disaccharides will produce...Ch. 7.13 - In which of the following disaccharides is the...Ch. 7.13 - In which of the following pairs of disaccharides...Ch. 7.13 - Which of the following disaccharides is not a...Ch. 7.13 - The terms milk sugar and table sugar apply,...Ch. 7.14 - Prob. 1QQCh. 7.14 - Prob. 2QQCh. 7.15 - Which of the following statements about...Ch. 7.15 - Prob. 2QQCh. 7.16 - Which of the following storage polysaccharides has...Ch. 7.16 - Prob. 2QQCh. 7.16 - Prob. 3QQCh. 7.16 - Prob. 4QQCh. 7.17 - Prob. 1QQCh. 7.17 - Which of the following statements about cellulose...Ch. 7.17 - Chitin is a polysaccharide in which the...Ch. 7.18 - Which of the following statements about the...Ch. 7.18 - Which of the following statements about the...Ch. 7.19 - Which of the following is not classified as a...Ch. 7.19 - Prob. 2QQCh. 7.20 - Which of the following types of compounds are...Ch. 7.20 - Which of the following is not a biochemical...Ch. 7 - Prob. 7.1EPCh. 7 - Prob. 7.2EPCh. 7 - Prob. 7.3EPCh. 7 - Prob. 7.4EPCh. 7 - Prob. 7.5EPCh. 7 - Prob. 7.6EPCh. 7 - Prob. 7.7EPCh. 7 - Prob. 7.8EPCh. 7 - Prob. 7.9EPCh. 7 - Prob. 7.10EPCh. 7 - Prob. 7.11EPCh. 7 - Prob. 7.12EPCh. 7 - Prob. 7.13EPCh. 7 - Prob. 7.14EPCh. 7 - Prob. 7.15EPCh. 7 - Prob. 7.16EPCh. 7 - Prob. 7.17EPCh. 7 - Prob. 7.18EPCh. 7 - Prob. 7.19EPCh. 7 - Prob. 7.20EPCh. 7 - Prob. 7.21EPCh. 7 - Prob. 7.22EPCh. 7 - Prob. 7.23EPCh. 7 - Prob. 7.24EPCh. 7 - Prob. 7.25EPCh. 7 - Indicate whether or not each of the molecules in...Ch. 7 - Prob. 7.27EPCh. 7 - Prob. 7.28EPCh. 7 - Prob. 7.29EPCh. 7 - Prob. 7.30EPCh. 7 - Prob. 7.31EPCh. 7 - Prob. 7.32EPCh. 7 - Prob. 7.33EPCh. 7 - Prob. 7.34EPCh. 7 - Prob. 7.35EPCh. 7 - Draw the Fischer projection formula for each of...Ch. 7 - Prob. 7.37EPCh. 7 - Prob. 7.38EPCh. 7 - Prob. 7.39EPCh. 7 - Prob. 7.40EPCh. 7 - Prob. 7.41EPCh. 7 - Prob. 7.42EPCh. 7 - Prob. 7.43EPCh. 7 - Prob. 7.44EPCh. 7 - Prob. 7.45EPCh. 7 - Prob. 7.46EPCh. 7 - Prob. 7.47EPCh. 7 - Prob. 7.48EPCh. 7 - Prob. 7.49EPCh. 7 - Prob. 7.50EPCh. 7 - Prob. 7.51EPCh. 7 - Prob. 7.52EPCh. 7 - Prob. 7.53EPCh. 7 - Prob. 7.54EPCh. 7 - Prob. 7.55EPCh. 7 - Prob. 7.56EPCh. 7 - Prob. 7.57EPCh. 7 - Prob. 7.58EPCh. 7 - Prob. 7.59EPCh. 7 - Prob. 7.60EPCh. 7 - Prob. 7.61EPCh. 7 - Prob. 7.62EPCh. 7 - Prob. 7.63EPCh. 7 - Prob. 7.64EPCh. 7 - Prob. 7.65EPCh. 7 - Prob. 7.66EPCh. 7 - Prob. 7.67EPCh. 7 - Prob. 7.68EPCh. 7 - Prob. 7.69EPCh. 7 - Prob. 7.70EPCh. 7 - Prob. 7.71EPCh. 7 - Prob. 7.72EPCh. 7 - Prob. 7.73EPCh. 7 - Prob. 7.74EPCh. 7 - Prob. 7.75EPCh. 7 - Prob. 7.76EPCh. 7 - Prob. 7.77EPCh. 7 - Prob. 7.78EPCh. 7 - Prob. 7.79EPCh. 7 - Prob. 7.80EPCh. 7 - Prob. 7.81EPCh. 7 - Prob. 7.82EPCh. 7 - Prob. 7.83EPCh. 7 - Prob. 7.84EPCh. 7 - Prob. 7.85EPCh. 7 - Prob. 7.86EPCh. 7 - Prob. 7.87EPCh. 7 - Prob. 7.88EPCh. 7 - Prob. 7.89EPCh. 7 - Prob. 7.90EPCh. 7 - Prob. 7.91EPCh. 7 - Prob. 7.92EPCh. 7 - Prob. 7.93EPCh. 7 - Prob. 7.94EPCh. 7 - Prob. 7.95EPCh. 7 - Prob. 7.96EPCh. 7 - Prob. 7.97EPCh. 7 - Classify each of the glucose derivatives in...Ch. 7 - Prob. 7.99EPCh. 7 - Prob. 7.100EPCh. 7 - Prob. 7.101EPCh. 7 - Prob. 7.102EPCh. 7 - Prob. 7.103EPCh. 7 - Prob. 7.104EPCh. 7 - Prob. 7.105EPCh. 7 - Prob. 7.106EPCh. 7 - Prob. 7.107EPCh. 7 - Prob. 7.108EPCh. 7 - Prob. 7.109EPCh. 7 - Prob. 7.110EPCh. 7 - Prob. 7.111EPCh. 7 - Prob. 7.112EPCh. 7 - Prob. 7.113EPCh. 7 - Prob. 7.114EPCh. 7 - Prob. 7.115EPCh. 7 - Prob. 7.116EPCh. 7 - Prob. 7.117EPCh. 7 - Prob. 7.118EPCh. 7 - Prob. 7.119EPCh. 7 - Prob. 7.120EPCh. 7 - Prob. 7.121EPCh. 7 - Prob. 7.122EPCh. 7 - Prob. 7.123EPCh. 7 - Prob. 7.124EPCh. 7 - Prob. 7.125EPCh. 7 - Prob. 7.126EPCh. 7 - Prob. 7.127EPCh. 7 - Prob. 7.128EPCh. 7 - Prob. 7.129EPCh. 7 - Prob. 7.130EPCh. 7 - Prob. 7.131EPCh. 7 - Prob. 7.132EPCh. 7 - Prob. 7.133EPCh. 7 - Prob. 7.134EPCh. 7 - Prob. 7.135EPCh. 7 - Prob. 7.136EPCh. 7 - Prob. 7.137EPCh. 7 - Prob. 7.138EPCh. 7 - Prob. 7.139EPCh. 7 - Prob. 7.140EPCh. 7 - Prob. 7.141EPCh. 7 - Prob. 7.142EPCh. 7 - Prob. 7.143EPCh. 7 - Prob. 7.144EPCh. 7 - Prob. 7.145EPCh. 7 - Prob. 7.146EPCh. 7 - Prob. 7.147EPCh. 7 - Prob. 7.148EPCh. 7 - Prob. 7.149EPCh. 7 - Prob. 7.150EPCh. 7 - Prob. 7.151EPCh. 7 - Prob. 7.152EPCh. 7 - Prob. 7.153EPCh. 7 - Prob. 7.154EPCh. 7 - Prob. 7.155EPCh. 7 - Prob. 7.156EPCh. 7 - Prob. 7.157EPCh. 7 - Prob. 7.158EPCh. 7 - Prob. 7.159EPCh. 7 - Prob. 7.160EPCh. 7 - Prob. 7.161EPCh. 7 - Prob. 7.162EPCh. 7 - Prob. 7.163EPCh. 7 - Prob. 7.164EPCh. 7 - Prob. 7.165EPCh. 7 - Prob. 7.166EPCh. 7 - Prob. 7.167EPCh. 7 - Prob. 7.168EPCh. 7 - Prob. 7.169EPCh. 7 - Prob. 7.170EPCh. 7 - Prob. 7.171EPCh. 7 - Prob. 7.172EP
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