The major product of the given reaction should be determined. Concept Introduction: Addition of halides to alkynes : Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below. If excess halides are present, a second addition reaction also occurs.

Question

1. How many neighbors does the proton that produces the multiplet below have? 2. 3. اللـ Draw a partial structure from the multiplet below. (The integration of the multiplet is 6) M Using the additivity constants found in appendix G of your lab manual, calculate the approximate chemical shifts of the protons indicated below. (Show your work!!!) B A Br SH

Answer 1

Question

Chapter 6.13, Problem 22P

(a)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(b)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(c)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(d)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

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1. How many neighbors does the proton that produces the multiplet below have? 2. 3. اللـ Draw a partial structure from the multiplet below. (The integration of the multiplet is 6) M Using the additivity constants found in appendix G of your lab manual, calculate the approximate chemical shifts of the protons indicated below. (Show your work!!!) B A Br SH

1) Suppose 0.1 kg ice at 0°C (273K) is in 0.5kg water at 20°C (293K). What is the change in entropy of the ice as it melts at 0°? To produce the original "water gas" mixture, carbon (in a combustible form known as coke) is reacted with steam: 131.4 kJ + H20(g) + C(s) → CO(g) + H2(g) From this information and the equations in the previous problem, calculate the enthalpy for the combustion or carbon to form carbon dioxide. kindly show me how to solve this long problem. Thanks

4. An 'H-NMR of a compound is acquired. The integration for signal A is 5692 and the integration for signal B is 25614. What is the simplest whole number ratio of protons for signals A and B? (Show your work!!!) 5. Assign the carbons in the NMR below as either carbonyl, aromatic, or alkyl. 200 150 100 50 ō (ppm) 1

Answer 2

Question

Chapter 6.13, Problem 22P

(a)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(b)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(c)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(d)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

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Answer 3

Question

Chapter 6.13, Problem 22P

(a)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(b)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(c)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(d)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

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Answer 4

Question

Chapter 6.13, Problem 22P

(a)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(b)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(c)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(d)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

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Answer 5

Chapter 6.13, Problem 22P

(a)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(b)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(c)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

(d)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

Answer 6

Chapter 6.13, Problem 22P

(a)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

Answer 7

Chapter 6.13, Problem 22P

(a)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine adds to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The major product of the given reaction should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below.

If excess halides are present, a second addition reaction also occurs.

Answer 14

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Ch. 6.1 - Draw the mechanism for the reaction of cyclohexene...Ch. 6.2 - a. How many bond orbitals are available for...Ch. 6.2 - Prob. 3P Ch. 6.2 - Prob. 4P Ch. 6.3 - Prob. 5P Ch. 6.3 - Prob. 6P Ch. 6.3 - Prob. 7P Ch. 6.5 - Prob. 9P Ch. 6.5 - Prob. 10P Ch. 6.5 - a. What is the major product of each of the...

The major product of the given reaction should be determined. Concept Introduction: Addition of halides to alkynes : Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below. If excess halides are present, a second addition reaction also occurs.

Solution Summary: The author explains how halogens like chlorine and bromine add to the alkyne compounds.

Chapter 6 Solutions