a) CH 3 Br + NaOH → CH 3 OH + NaBr Interpretation: The reaction CH 3 Br + NaOH → CH 3 OH + NaBr is to be classified as an addition, elimination, substitution or rearrangement reaction. Concept introduction: In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product. To classify: The reaction CH 3 Br + NaOH → CH 3 OH + NaBr as an addition, elimination, substitution or rearrangement reaction.

Question

Draw a stepwise mechanism for the following reaction. OH

Answer 1

Question

Chapter 6.1, Problem 1P

Interpretation Introduction

a) CH₃Br + NaOH → CH₃OH + NaBr

Interpretation:

The reaction CH₃Br + NaOH → CH₃OH + NaBr is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₃Br + NaOH → CH₃OH + NaBr as an addition, elimination, substitution or rearrangement reaction.

Interpretation Introduction

b) CH₃CH₂Br → CH₂=CH₂ + HBr

Interpretation:

The reaction CH₃CH₂Br → CH₂=CH₂ + HBr is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₃CH₂Br → CH₂=CH₂ + HBr as an addition, elimination, substitution or rearrangement reaction.

Interpretation Introduction

c) CH₂=CH₂ + H₂ → CH₃-CH₃

Interpretation:

The reaction CH₂=CH₂ + H₂ → CH₃-CH₃ is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₂=CH₂ + H₂ → CH₃-CH₃ as an addition, elimination, substitution or rearrangement reaction.

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Draw a stepwise mechanism for the following reaction. OH

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Answer 2

Question

Chapter 6.1, Problem 1P

Interpretation Introduction

a) CH₃Br + NaOH → CH₃OH + NaBr

Interpretation:

The reaction CH₃Br + NaOH → CH₃OH + NaBr is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₃Br + NaOH → CH₃OH + NaBr as an addition, elimination, substitution or rearrangement reaction.

Interpretation Introduction

b) CH₃CH₂Br → CH₂=CH₂ + HBr

Interpretation:

The reaction CH₃CH₂Br → CH₂=CH₂ + HBr is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₃CH₂Br → CH₂=CH₂ + HBr as an addition, elimination, substitution or rearrangement reaction.

Interpretation Introduction

c) CH₂=CH₂ + H₂ → CH₃-CH₃

Interpretation:

The reaction CH₂=CH₂ + H₂ → CH₃-CH₃ is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₂=CH₂ + H₂ → CH₃-CH₃ as an addition, elimination, substitution or rearrangement reaction.

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Answer 3

Question

Chapter 6.1, Problem 1P

Interpretation Introduction

a) CH₃Br + NaOH → CH₃OH + NaBr

Interpretation:

The reaction CH₃Br + NaOH → CH₃OH + NaBr is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₃Br + NaOH → CH₃OH + NaBr as an addition, elimination, substitution or rearrangement reaction.

Interpretation Introduction

b) CH₃CH₂Br → CH₂=CH₂ + HBr

Interpretation:

The reaction CH₃CH₂Br → CH₂=CH₂ + HBr is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₃CH₂Br → CH₂=CH₂ + HBr as an addition, elimination, substitution or rearrangement reaction.

Interpretation Introduction

c) CH₂=CH₂ + H₂ → CH₃-CH₃

Interpretation:

The reaction CH₂=CH₂ + H₂ → CH₃-CH₃ is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₂=CH₂ + H₂ → CH₃-CH₃ as an addition, elimination, substitution or rearrangement reaction.

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Answer 4

Question

Chapter 6.1, Problem 1P

Interpretation Introduction

a) CH₃Br + NaOH → CH₃OH + NaBr

Interpretation:

The reaction CH₃Br + NaOH → CH₃OH + NaBr is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₃Br + NaOH → CH₃OH + NaBr as an addition, elimination, substitution or rearrangement reaction.

Interpretation Introduction

b) CH₃CH₂Br → CH₂=CH₂ + HBr

Interpretation:

The reaction CH₃CH₂Br → CH₂=CH₂ + HBr is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₃CH₂Br → CH₂=CH₂ + HBr as an addition, elimination, substitution or rearrangement reaction.

Interpretation Introduction

c) CH₂=CH₂ + H₂ → CH₃-CH₃

Interpretation:

The reaction CH₂=CH₂ + H₂ → CH₃-CH₃ is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₂=CH₂ + H₂ → CH₃-CH₃ as an addition, elimination, substitution or rearrangement reaction.

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Answer 5

Chapter 6.1, Problem 1P

Interpretation Introduction

a) CH₃Br + NaOH → CH₃OH + NaBr

Interpretation:

The reaction CH₃Br + NaOH → CH₃OH + NaBr is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₃Br + NaOH → CH₃OH + NaBr as an addition, elimination, substitution or rearrangement reaction.

Interpretation Introduction

b) CH₃CH₂Br → CH₂=CH₂ + HBr

Interpretation:

The reaction CH₃CH₂Br → CH₂=CH₂ + HBr is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₃CH₂Br → CH₂=CH₂ + HBr as an addition, elimination, substitution or rearrangement reaction.

Interpretation Introduction

c) CH₂=CH₂ + H₂ → CH₃-CH₃

Interpretation:

The reaction CH₂=CH₂ + H₂ → CH₃-CH₃ is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₂=CH₂ + H₂ → CH₃-CH₃ as an addition, elimination, substitution or rearrangement reaction.

Answer 6

Chapter 6.1, Problem 1P

Interpretation Introduction

a) CH₃Br + NaOH → CH₃OH + NaBr

Interpretation:

The reaction CH₃Br + NaOH → CH₃OH + NaBr is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₃Br + NaOH → CH₃OH + NaBr as an addition, elimination, substitution or rearrangement reaction.

Answer 7

Chapter 6.1, Problem 1P

Interpretation Introduction

a) CH₃Br + NaOH → CH₃OH + NaBr

Interpretation:

The reaction CH₃Br + NaOH → CH₃OH + NaBr is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₃Br + NaOH → CH₃OH + NaBr as an addition, elimination, substitution or rearrangement reaction.

Answer 8

Interpretation Introduction

b) CH₃CH₂Br → CH₂=CH₂ + HBr

Interpretation:

The reaction CH₃CH₂Br → CH₂=CH₂ + HBr is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₃CH₂Br → CH₂=CH₂ + HBr as an addition, elimination, substitution or rearrangement reaction.

Answer 9

Interpretation Introduction

b) CH₃CH₂Br → CH₂=CH₂ + HBr

Interpretation:

The reaction CH₃CH₂Br → CH₂=CH₂ + HBr is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₃CH₂Br → CH₂=CH₂ + HBr as an addition, elimination, substitution or rearrangement reaction.

Answer 10

Interpretation Introduction

c) CH₂=CH₂ + H₂ → CH₃-CH₃

Interpretation:

The reaction CH₂=CH₂ + H₂ → CH₃-CH₃ is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₂=CH₂ + H₂ → CH₃-CH₃ as an addition, elimination, substitution or rearrangement reaction.

Answer 11

Interpretation Introduction

c) CH₂=CH₂ + H₂ → CH₃-CH₃

Interpretation:

The reaction CH₂=CH₂ + H₂ → CH₃-CH₃ is to be classified as an addition, elimination, substitution or rearrangement reaction.

Concept introduction:

In addition reactions two reactants add together to form a single product. In elimination reactions a single reactant splits in to two products often with the formation of small molecules like water, HBr etc. In substitution reactions two reactants exchange parts to give new products. In rearrangement reactions a single reactant undergoes a reorganization of bonds and groups to yield a new isomeric product.

To classify:

The reaction CH₂=CH₂ + H₂ → CH₃-CH₃ as an addition, elimination, substitution or rearrangement reaction.

Answer 12

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Answer 23

Ch. 6.1 - Prob. 1P Ch. 6.3 - Prob. 2P Ch. 6.3 - Using curved fishhook arrows, propose a mechanism...Ch. 6.4 - Prob. 4P Ch. 6.4 - An electrostatic potential map of boron...Ch. 6.5 - What product would you expect from reaction of...Ch. 6.5 - Reaction of HBr with 2-methylpropene yields...Ch. 6.6 - Prob. 8P Ch. 6.6 - Predict the products of the following polar...Ch. 6.7 - Which reaction is more energetically favored, one...

Solution Summary: The author explains that the reaction CH 3 Br + NaOH Ch 3 OH+ NaBr can be classified as an addition, elimination, substitution, or rearrangement reaction.

Chapter 6 Solutions