LCPO CHEMISTRY W/MODIFIED MASTERING
LCPO CHEMISTRY W/MODIFIED MASTERING
8th Edition
ISBN: 9780135214756
Author: Robinson
Publisher: PEARSON
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Chapter 6, Problem 6.96SP

Use the following information plus the data given in Tables6.2 and 6.3 to calculate the second electron affinity, E ea2 , of oxygen. Is the O 2 ion stable in the gas phase? Why is its table in solid MgO?
Heat of sublimation for Mg ( s ) = + 147 . 7 kJ / mol Bond dissociation energy for O 2 ( g ) = + 498 . 4 kJ / mol E ea1 for O ( g ) = 141 .0  kJ / mol Net energy change for formation of MgO ( s )  from its elements = 6 0 1 . 7 kJ / mol

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Calculate the second ionization energy of the metal M (AHion2 in kJ/mol) using the following data: Lattice enthalpy of MO(s), AH = -2278 kJ/mol Bond dissociation enthalpy of O2(g) = +498 kJ/mol First electron affinity of O = -141 kJ/mol Second electron affinity of O = +744 kJ/mol Enthalpy of sublimation of M = + 125 kJ/mol First ionization energy of M = + 309 kJ/mol Standard enthalpy of formation of MO(s), AH = -341 kJ/mol
Consider an ionic compound, MX3, composed of generic metal M and generic gaseous halogen X. The enthalpy of formation of MX3 is Δ?∘f=−925 kJ/mol. The enthalpy of sublimation of M is Δ?sub=175 kJ/mol. The first, second, and third ionization energies of M are IE1=579 kJ/mol, IE2=1677 kJ/mol, and IE3=2479 kJ/mol. The electron affinity of X is Δ?EA=−369 kJ/mol. (Refer to the hint). The bond energy of X2 is BE=179 kJ/mol. Determine the lattice energy of MX3.
Calculate the second ionization energy of the metal M (AH¡on2 in kJ/mol) using the following data: Lattice enthalpy of MO(s), AH = -2278 kJ/mol Bond dissociation enthalpy of O2(g) = +498 kJ/mol %3D First electron affinity of O = -141 kJ/mol Second electron affinity of O = +744 kJ/mol Enthalpy of sublimation of M = + 125 kJ/mol First ionization energy of M = + 309 kJ/mol Standard enthalpy of formation of MO(s), AHf = -341 kJ/mol

Chapter 6 Solutions

LCPO CHEMISTRY W/MODIFIED MASTERING

Ch. 6 - What electron configuration does the strontium...Ch. 6 - Prob. 6.12ACh. 6 - Prob. 6.13PCh. 6 - APPLY 6.14 Calculate the energy of electrostatic...Ch. 6 - Which substance has the largest lattice energy:...Ch. 6 - One of the following pictures represents NaCl and...Ch. 6 - Prob. 6.17PCh. 6 - What structural features do ionic liquids havethat...Ch. 6 - PROBLEM 6.18 Compare the following two ionic...Ch. 6 - PROBLEM 6.19 An ionic liquid consisting of a bulky...Ch. 6 - Where on the periodic table would you find the...Ch. 6 - Which of the following spheres is likely to...Ch. 6 - Circle the approximate part or parts of the...Ch. 6 - Prob. 6.24CPCh. 6 - This figure represents the successive ionization...Ch. 6 - In the following drawings, red spheres represent...Ch. 6 - Which of the following drawings is more likely to...Ch. 6 - Prob. 6.28CPCh. 6 - Which of the following alkali metal halides has...Ch. 6 - Which of the following alkali metal halides has...Ch. 6 - Three binary compounds are represented on the...Ch. 6 - Prob. 6.32CPCh. 6 - Prob. 6.33CPCh. 6 - What is the difference between a covalent bond and...Ch. 6 - Prob. 6.35SPCh. 6 - What is the difference between a molecule and an...Ch. 6 - Prob. 6.37SPCh. 6 - How many protons and electrons are in each of the...Ch. 6 - What is the identity of the element X in the...Ch. 6 - Prob. 6.40SPCh. 6 - Prob. 6.41SPCh. 6 - Prob. 6.42SPCh. 6 - Prob. 6.43SPCh. 6 - What doubly positive ion has the following...Ch. 6 - Prob. 6.45SPCh. 6 - Prob. 6.46SPCh. 6 - Which element in the transition-metal series Sc...Ch. 6 - Prob. 6.48SPCh. 6 - Prob. 6.49SPCh. 6 - Order the following ions from smallest to largest:...Ch. 6 - Order the following ions from smallest to largest:...Ch. 6 - Which ion has a larger atomic radius, Cu+ or Cu2+...Ch. 6 - Which ion hasa larger atomic radius, Fe2+ or Fe3+...Ch. 6 - The following ions all have the same number of...Ch. 6 - Which of the ions Se2,F,O2 and Rb+ has the largest...Ch. 6 - Which group of elements in the periodic table has...Ch. 6 - Prob. 6.57SPCh. 6 - Which element in each of the following sets has...Ch. 6 - Order the elements in each set from the smallest...Ch. 6 - (a) Which has the smaller second ionization...Ch. 6 - (a) Which has the smaller fourth ionization...Ch. 6 - Three atoms have the following electron...Ch. 6 - Three atoms have the following electron...Ch. 6 - The first four ionization energies in kJ/mol of a...Ch. 6 - The first four ionization energies in kJ/mol of a...Ch. 6 - Prob. 6.66SPCh. 6 - Prob. 6.67SPCh. 6 - Prob. 6.68SPCh. 6 - Prob. 6.69SPCh. 6 - Why is energy usually released when an electron is...Ch. 6 - Why does ionization energy increase regularly...Ch. 6 - No element has a negative second electron...Ch. 6 - Why does phosphorus have a less negative electron...Ch. 6 - Prob. 6.74SPCh. 6 - What noble-gas configurations and charge are the...Ch. 6 - Each of the following pairs of elements will react...Ch. 6 - Each of the following pairs of elements will react...Ch. 6 - Element X reacts with element Y to give a product...Ch. 6 - Element X reacts with element Y to give a product...Ch. 6 - Calculate the energy change in kilojoules per mole...Ch. 6 - Prob. 6.81SPCh. 6 - Find the lattice energy of LiBr(s) in Table 6.3,...Ch. 6 - Look up the lattice energies in Table 6.3, and...Ch. 6 - Born-4-Iaber cycles, such as those shown in...Ch. 6 - Calculate a lattice energy for CaH2(s) in...Ch. 6 - Calculate the overall energy change in kilojoules...Ch. 6 - The estimated lattice energy for CsF2(s) is +2347...Ch. 6 - Calculate the overall energy change in kilojoules...Ch. 6 - Use the data in Problem 6.88 to calculate an...Ch. 6 - Use the data and the result in Problem 6.84 to...Ch. 6 - Prob. 6.91SPCh. 6 - Calculate overall energy changes in kilojoules per...Ch. 6 - Prob. 6.93SPCh. 6 - We saw in Section 6.7 that the reaction of solid...Ch. 6 - Draw a Born—Haber cycle for the reaction of sodium...Ch. 6 - Use the following information plus the data given...Ch. 6 - Prob. 6.97SPCh. 6 - Prob. 6.98SPCh. 6 - Order the following compounds according to their...Ch. 6 - Prob. 6.100MPCh. 6 - Heating elemental cesium and platinum together for...Ch. 6 - Given the following information, construct a...Ch. 6 - Consider the electronic structure of the element...Ch. 6 - Prob. 6.104MPCh. 6 - The ionization energy of an atom can be measured...
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