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Calculate overall energy changes in kilojoules per mole for the formation of MgF(s) and
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- Consider the reactions of silver metal, Ag(s), with each of the halogens: fluorine, F2(g), chlorine, Cl2(g), and bromine, Br2(l). What chapter data could you use to decide which reaction is most exothermic? Which reaction is that?arrow_forwardCalculate the lattice energy of potassium fluoride, KF, using the BornHaber cycle. Use thermodynamic data from Appendix C to obtain the enthalpy changes for each step. (Note: You will obtain a slightly different answer if you use values given in Chapter 8 for the ionization energy and electron affinity, which are energy values at 0 K rather than the enthalpy changes at 298 K.)arrow_forwardWhich of the following compounds requires the most energy to convert one mole of the solid into separate ions? (a) MgO (b) SrO (c) KF (d) CsF (e) MgF2arrow_forward
- For which of the following substances is the least energy required to convert one mole of the solid into separate ions? (a) MgO (b) SrO (c) KF (d) CsF (e) MgF2arrow_forward3. the enthalpy of sublimation at 25 c is 148 kJ/mole. how much heat (at constant temperature and pressure) must be supplied to 1.00 g of solid magnesium metal to produce a gas composed of mg2+ ions and electrons? molar mass of magnesium is 24.31 g/mole. Sublimation Mg- Mgo AH =+148 KJ/mole First ionization Mge- Mg*e +e AH=+ 738 KJ/mole Second ionization Mge- Mg*o+e AH=+1451 KJ/mole Overall (sum) Mg)-Mg"@+2e AH= ?arrow_forwardThe lattice energy of NaCl is 769 kJ/mole. Which of the following is a correct statement about NaCl? When one mole each of gaseous Nat and CI- ions form solid NaCl, 769 kJ of heat is consumed. It requires 769 kJ to separate one mole of solid NaCl into one mole of each gaseous Na* and CI- ions. It requires 769 kJ to separate one mole of solid NaCl into gaseous one mole of Na* and two moles of CI- ions.arrow_forward
- Calculate the lattice energy of NaBr(s), given the following thermochemical equations, where A/E and AEA are ionization energy and electron affinity, respectively. Na(s)Na(g) AH = +107 kJ Na(g) Nat(g) + e A/E = +496 kJ -> 1/2 Br₂(g) → Br(g) AHf = +112 kJ - Br(g) + e¯ → Br¯(g) AEA = -325 kJ Na(s) + 1/2 Br₂(g) → NaBr(s) AH = -361 kJ ->> - -1401 kJ -751 kJ +29 kJ -29 kJ +751 kJarrow_forwardUsing the following data, calculate the lattice energy of calcium chloride: Ca2+(g) + 2Cl– (g) → CaCl2(s) ΔHlattice = ? Sublimation enthalpy of calcium ΔH = 177.8 kJ/mol First ionization energy of calcium ΔH = 590.2 kJ/mol Second ionization energy of calcium ΔH = 1144.2 kJ/mol First electron affinity of chlorine ΔH = –349 kJ/mol Heat of formation of CaCl2(s) ΔH = –795.4 kJ/mol Bond energy of Cl2 (see Table 2) Use Hess’s law to calculate the lattice energy of calcium chloride. set-up must show all the chemical equations and you must show how their H values add up to give your answer.arrow_forward1. Below is a list of enthalpy changes for the Born-Haber cycle for the formation of solid LiF from Li(s) and F(g). Use these data to determine the lattice energy for the formation LiF(s). Li(s) → Li(g) ΔH1 = +162 kJ/mol Li(g) → Li+(g) + e- ΔH2 = +520.2 kJ/molF2(g) → 2F(g) ΔH3 = 154 kJ/mol F(g) + e- → F-(g) ΔH4 = -328 kJ/molLi(s) + 1/2F2(g) → LiF(s) ΔHf = -612 kJ/mol Select an answer and submit. For keyboard navigation, use the up/down arrow keys to select an answer. a. 1371 kJ/mol b. -1371 kJ/mol c. 1043 kJ/mol d. -1043 kJ/molarrow_forward
- Consider an ionic compound, MX3, composed of generic metal M and generic gaseous halogen X. The enthalpy of formation of MX3 is Δ?∘f=−925 kJ/mol. The enthalpy of sublimation of M is Δ?sub=175 kJ/mol. The first, second, and third ionization energies of M are IE1=579 kJ/mol, IE2=1677 kJ/mol, and IE3=2479 kJ/mol. The electron affinity of X is Δ?EA=−369 kJ/mol. (Refer to the hint). The bond energy of X2 is BE=179 kJ/mol. Determine the lattice energy of MX3.arrow_forwardThe ionic radii of element E and a different metallic element, M, are shown in the following table: Both elements form oxides, E2O and MO. If lattice energy is defined as the energy required to separate an ionic solid into individual separate gaseous ions, would the lattice energy of MO be less than, equal to, or greater than the lattice energy of the oxide E2O? Justify your answer in terms of Coulomb's lawarrow_forward6- Draw Born – Haber Cycle and Calculate the lattice enthalpy for lithium fluoride, given the following information: • Enthalpy of sublimation for solid lithium = 151 kJ/mol • First ionization energy for lithium = 519 kJ/mol • F-F bond dissociation energy = 164 kJ/mol • Enthalpy of formation for F(g) = 82 kJ/mol • Electron affinity for fluorine = -348 kJ/mol Enthalpy of formation for solid lithium fluoride = -617 kJ/molarrow_forward
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