LCPO CHEMISTRY W/MODIFIED MASTERING
LCPO CHEMISTRY W/MODIFIED MASTERING
8th Edition
ISBN: 9780135214756
Author: Robinson
Publisher: PEARSON
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Chapter 6, Problem 6.85SP

Calculate a lattice energy for CaH 2 ( s ) in kilojoules per mole using the following information
E ea for H ( g ) = 72 . 8 kJ/mol E i1 for Ca ( g ) = + 589 . 8 kJ/mol E i2 for Ca ( g ) = + 1145 kJ/mol Heat of sublimation for Ca ( s ) = + 178 . 2 kJ/mol Bond dissociation energy for H 2 ( g ) = + 435 . 9 kJ/mol Net energy change for the formation of CaH 2 ( s )  from itselements = 186 . 2 kJ / mol

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1. Below is a list of enthalpy changes for the Born-Haber cycle for the formation of solid LiF from Li(s) and F(g). Use these data to determine the lattice energy for the formation LiF(s). Li(s) → Li(g)       ΔH1 = +162 kJ/mol Li(g) → Li+(g) + e-     ΔH2  = +520.2 kJ/molF2(g) → 2F(g)     ΔH3  = 154 kJ/mol F(g) + e-  →  F-(g)     ΔH4  = -328 kJ/molLi(s) +  1/2F2(g) → LiF(s)   ΔHf = -612 kJ/mol Select an answer and submit. For keyboard navigation, use the up/down arrow keys to select an answer. a. 1371 kJ/mol b. -1371 kJ/mol c. 1043 kJ/mol d. -1043 kJ/mol
Given the following information, find the lattice enthalpy (kJ/mol) of NaCl(s).   ΔHf (NaCl) = -411 kJ/mol ΔHsublimation (Na) = 107 kJ/mol IE1 (Na) = 496 kJ/mol Bond Energy (Cl-Cl) = 244 kJ/mol EA1 (Cl) = -349 kJ/mol
Using the following data, calculate the lattice energy of calcium chloride: Ca2+(g) + 2Cl– (g) → CaCl2(s)      ΔHlattice = ? Sublimation enthalpy of calcium  ΔH = 177.8 kJ/mol First ionization energy of calcium   ΔH = 590.2 kJ/mol Second ionization energy of calcium  ΔH = 1144.2 kJ/mol  First electron affinity of chlorine   ΔH = –349 kJ/mol  Heat of formation of CaCl2(s)    ΔH = –795.4 kJ/mol  Bond energy of Cl2 (see Table 2) Use Hess’s law to calculate the lattice energy of calcium chloride. set-up must show all the chemical equations and you must show how their H values add up to give your answer.

Chapter 6 Solutions

LCPO CHEMISTRY W/MODIFIED MASTERING

Ch. 6 - What electron configuration does the strontium...Ch. 6 - Prob. 6.12ACh. 6 - Prob. 6.13PCh. 6 - APPLY 6.14 Calculate the energy of electrostatic...Ch. 6 - Which substance has the largest lattice energy:...Ch. 6 - One of the following pictures represents NaCl and...Ch. 6 - Prob. 6.17PCh. 6 - What structural features do ionic liquids havethat...Ch. 6 - PROBLEM 6.18 Compare the following two ionic...Ch. 6 - PROBLEM 6.19 An ionic liquid consisting of a bulky...Ch. 6 - Where on the periodic table would you find the...Ch. 6 - Which of the following spheres is likely to...Ch. 6 - Circle the approximate part or parts of the...Ch. 6 - Prob. 6.24CPCh. 6 - This figure represents the successive ionization...Ch. 6 - In the following drawings, red spheres represent...Ch. 6 - Which of the following drawings is more likely to...Ch. 6 - Prob. 6.28CPCh. 6 - Which of the following alkali metal halides has...Ch. 6 - Which of the following alkali metal halides has...Ch. 6 - Three binary compounds are represented on the...Ch. 6 - Prob. 6.32CPCh. 6 - Prob. 6.33CPCh. 6 - What is the difference between a covalent bond and...Ch. 6 - Prob. 6.35SPCh. 6 - What is the difference between a molecule and an...Ch. 6 - Prob. 6.37SPCh. 6 - How many protons and electrons are in each of the...Ch. 6 - What is the identity of the element X in the...Ch. 6 - Prob. 6.40SPCh. 6 - Prob. 6.41SPCh. 6 - Prob. 6.42SPCh. 6 - Prob. 6.43SPCh. 6 - What doubly positive ion has the following...Ch. 6 - Prob. 6.45SPCh. 6 - Prob. 6.46SPCh. 6 - Which element in the transition-metal series Sc...Ch. 6 - Prob. 6.48SPCh. 6 - Prob. 6.49SPCh. 6 - Order the following ions from smallest to largest:...Ch. 6 - Order the following ions from smallest to largest:...Ch. 6 - Which ion has a larger atomic radius, Cu+ or Cu2+...Ch. 6 - Which ion hasa larger atomic radius, Fe2+ or Fe3+...Ch. 6 - The following ions all have the same number of...Ch. 6 - Which of the ions Se2,F,O2 and Rb+ has the largest...Ch. 6 - Which group of elements in the periodic table has...Ch. 6 - Prob. 6.57SPCh. 6 - Which element in each of the following sets has...Ch. 6 - Order the elements in each set from the smallest...Ch. 6 - (a) Which has the smaller second ionization...Ch. 6 - (a) Which has the smaller fourth ionization...Ch. 6 - Three atoms have the following electron...Ch. 6 - Three atoms have the following electron...Ch. 6 - The first four ionization energies in kJ/mol of a...Ch. 6 - The first four ionization energies in kJ/mol of a...Ch. 6 - Prob. 6.66SPCh. 6 - Prob. 6.67SPCh. 6 - Prob. 6.68SPCh. 6 - Prob. 6.69SPCh. 6 - Why is energy usually released when an electron is...Ch. 6 - Why does ionization energy increase regularly...Ch. 6 - No element has a negative second electron...Ch. 6 - Why does phosphorus have a less negative electron...Ch. 6 - Prob. 6.74SPCh. 6 - What noble-gas configurations and charge are the...Ch. 6 - Each of the following pairs of elements will react...Ch. 6 - Each of the following pairs of elements will react...Ch. 6 - Element X reacts with element Y to give a product...Ch. 6 - Element X reacts with element Y to give a product...Ch. 6 - Calculate the energy change in kilojoules per mole...Ch. 6 - Prob. 6.81SPCh. 6 - Find the lattice energy of LiBr(s) in Table 6.3,...Ch. 6 - Look up the lattice energies in Table 6.3, and...Ch. 6 - Born-4-Iaber cycles, such as those shown in...Ch. 6 - Calculate a lattice energy for CaH2(s) in...Ch. 6 - Calculate the overall energy change in kilojoules...Ch. 6 - The estimated lattice energy for CsF2(s) is +2347...Ch. 6 - Calculate the overall energy change in kilojoules...Ch. 6 - Use the data in Problem 6.88 to calculate an...Ch. 6 - Use the data and the result in Problem 6.84 to...Ch. 6 - Prob. 6.91SPCh. 6 - Calculate overall energy changes in kilojoules per...Ch. 6 - Prob. 6.93SPCh. 6 - We saw in Section 6.7 that the reaction of solid...Ch. 6 - Draw a Born—Haber cycle for the reaction of sodium...Ch. 6 - Use the following information plus the data given...Ch. 6 - Prob. 6.97SPCh. 6 - Prob. 6.98SPCh. 6 - Order the following compounds according to their...Ch. 6 - Prob. 6.100MPCh. 6 - Heating elemental cesium and platinum together for...Ch. 6 - Given the following information, construct a...Ch. 6 - Consider the electronic structure of the element...Ch. 6 - Prob. 6.104MPCh. 6 - The ionization energy of an atom can be measured...
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