Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 6, Problem 3PP
Interpretation Introduction

Interpretation:

The net ionic equations are to be written, and the nucleophile, substrate, and leaving group are to be designated in the given equations.

Concept introduction:

Nucleophilic substitution is a reaction in which an electron-rich group, called a nucleophile, substitutes an outgoing group on a saturated carbon atom. The group that is replaced carries the bonding electron pair with it and is called the leaving group. Nucleophilic substitution reactions are of two types- when the order of the reaction is first order it is represented as Sn1 ands when the order is of second order then represented as Sn2.

Spectator ions are ions that are present on both sides of the equation and neither undergo any change nor are involved in covalent bonding.

A net ionic equation is the ionic equation with no spectator ions.

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When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.
When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.   Which experimental number must be initialled by the Lab TA for the first run of Part 1 of the experiment? a) the heat capacity of the calorimeter b) Mass of sample c) Ti d) The molarity of the HCl e) Tf
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