Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 6, Problem 39P
Interpretation Introduction

Interpretation:

The effect of increasing solvent polarity on the rate of each of the given nucleophilic substitution reaction is to be determined.

Concept introduction:

Electrophiles are electron-deficient species, which has positive or partially positive charge. Lewis acids are electrophiles, which accept electron pair.

Nucleophiles are electron-rich species, which has negative or partially negative charge. Lewis bases are nucleophiles, which donate electron pair.

Substitution reaction: A reaction in which one of the hydrogen atoms of a hydrocarbon or a functional group is substituted by any other functional group is called substitution reaction.

Nucleophilic substitution reaction is a reaction in which an electron-rich nucleophile attacks the positive or partial positive charge of an atom or a group of atoms to replace a leaving group.

An SN2 reaction is the nucleophilic substitution reaction in which two components are involved in the rate determining step. SN2 reaction occurs in one step.

An SN1 reaction is the nucleophilic substitution reaction in which one component is involved in the rate determining step. SN1 reaction occurs in two step.

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