Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 6, Problem 13PP
Interpretation Introduction

Interpretation:

The order of decreasing nucleophilicity in a protic solvent of the given compounds is to be ranked.

Concept introduction:

Nucleophilicity is a measure of the ability of any nucleophile to react with an electron-deficient species.

Nucleophiles are Lewis bases, mean electron rich, and have the ability to donate electron pairs.

The order of nucleophilicity can be decided on the basis of charge.

A negatively charged nucleophile is more reactive than its conjugate acid.

In the given nucleophiles, the negatively charged nucleophiles are more reactive than the neutral one.

The nucleophile attached with electron withdrawing group has less nucleophilicity because electron withdrawing attracts electron density toward itself.

Nucleophilicity increases down the group in the periodic table.

Protic solvents are the solvents that form hydrogen bonds. They contain a hydrogen atom, which is bonded to an electronegative atom such as oxygen or nitrogen.

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a) Draw the octahedral mer-[FeCl3(CN)3] complex and determine its point group. Use proper wedges and dashes in order to illustrate 3 dimensional details. Use the point group to determine if the complex has a resulting net dipole moment and describe its allowed direction with respect to its symmetry elements (if applicable). ード M 4- b) Substitute one chlorido ligand in mer-[FeCl3(CN)3] 4 with one fluorido ligand. Determine all possible isomers and their corresponding point groups. Use the point groups to determine if the complexes have resulting net dipole moments and describe their allowed direction with respect to its symmetry elements (if applicable). The number of complex sketches below is not necessarily indicative of the number of isomers. 4- 4- ☐☐☐ c) Substitute two chlorido ligands in mer-[FeCl3 (CN)3] 4 with two fluorido ligands. Determine all possible isomers and their corresponding point groups.. Use the point groups to determine if the complexes have resulting net dipole…
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