
General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
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Question
Chapter 4.9, Problem 6QQ
Interpretation Introduction
Interpretation:
Among the given options, the binary ionic compound that has a name which includes a Roman numeral has to be chosen.
Concept Introduction:
An ionic compound has two elements one is metal and another one is non-metal. The metal ion has always positive charge and the non-metal ion has always negative ion called binary compounds.
Example:
Depending upon the chemical circumstances metal atoms able to form more than one type of ion is called variable charge metal.
Example – Fe forms
If variable charge metal atom is there in ionic compound and the naming can be done by using Roman numerals.
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
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P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
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2
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b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 4 Solutions
General, Organic, and Biological Chemistry
Ch. 4.1 - Prob. 1QQCh. 4.1 - Prob. 2QQCh. 4.1 - Prob. 3QQCh. 4.2 - How many valence electrons are present in an atom...Ch. 4.2 - Prob. 2QQCh. 4.2 - Prob. 3QQCh. 4.2 - Prob. 4QQCh. 4.2 - Which of the following elements would have the...Ch. 4.3 - Prob. 1QQCh. 4.3 - Prob. 2QQ
Ch. 4.3 - Prob. 3QQCh. 4.4 - In terms of subatomic particles, a Ca2+ ion...Ch. 4.4 - Prob. 2QQCh. 4.4 - Prob. 3QQCh. 4.4 - Prob. 4QQCh. 4.5 - An atom with a 1s22s22p4 electron configuration...Ch. 4.5 - Prob. 2QQCh. 4.5 - Prob. 3QQCh. 4.5 - Prob. 4QQCh. 4.5 - Prob. 5QQCh. 4.6 - Prob. 1QQCh. 4.6 - Prob. 2QQCh. 4.6 - Prob. 3QQCh. 4.7 - What is the chemical formula of the ionic compound...Ch. 4.7 - What is the chemical formula of the ionic compound...Ch. 4.7 - Given that Z2 ions are present in the ionic...Ch. 4.7 - Prob. 4QQCh. 4.8 - Prob. 1QQCh. 4.8 - Which of the following is a correct description of...Ch. 4.9 - Prob. 1QQCh. 4.9 - Prob. 2QQCh. 4.9 - Prob. 3QQCh. 4.9 - Prob. 4QQCh. 4.9 - Prob. 5QQCh. 4.9 - Prob. 6QQCh. 4.9 - The correct name for the binary ionic compound...Ch. 4.9 - Prob. 8QQCh. 4.10 - Prob. 1QQCh. 4.10 - Which of the following statements about polyatomic...Ch. 4.10 - The nitrate, sulfate, and phosphate ions have,...Ch. 4.10 - Prob. 4QQCh. 4.11 - Prob. 1QQCh. 4.11 - Prob. 2QQCh. 4.11 - Prob. 3QQCh. 4.11 - Prob. 4QQCh. 4.11 - Prob. 5QQCh. 4.11 - What is the chemical formula for the compound...Ch. 4 - Contrast the two general types of chemical bonds...Ch. 4 - Contrast the two general types of chemical...Ch. 4 - How many valence electrons do atoms with the...Ch. 4 - How many valence electrons do atoms with the...Ch. 4 - Prob. 4.5EPCh. 4 - Prob. 4.6EPCh. 4 - Write the complete electron configuration for each...Ch. 4 - Write the complete electron configuration for each...Ch. 4 - Prob. 4.9EPCh. 4 - For each of the following pairs of representative...Ch. 4 - How many of the highlighted elements in the...Ch. 4 - How many of the highlighted elements in the...Ch. 4 - Draw Lewis symbols for atoms of each of the...Ch. 4 - Draw Lewis symbols for atoms of each of the...Ch. 4 - Each of the following Lewis symbols represents a...Ch. 4 - Each of the following Lewis symbols represents a...Ch. 4 - Prob. 4.17EPCh. 4 - Prob. 4.18EPCh. 4 - What is the chemical property of the noble gases...Ch. 4 - Prob. 4.20EPCh. 4 - Prob. 4.21EPCh. 4 - Prob. 4.22EPCh. 4 - Give the chemical symbol for each of the following...Ch. 4 - Give the chemical symbol for each of the following...Ch. 4 - What would be the chemical symbol for an ion with...Ch. 4 - What would be the chemical symbol for an ion with...Ch. 4 - Fill in the blanks in each line in the following...Ch. 4 - Fill in the blanks in each line in the following...Ch. 4 - Fill in the blanks in each line of the following...Ch. 4 - Fill in the blanks in each line of the following...Ch. 4 - Identify element X by giving its chemical symbol,...Ch. 4 - Prob. 4.32EPCh. 4 - Prob. 4.33EPCh. 4 - Prob. 4.34EPCh. 4 - Prob. 4.35EPCh. 4 - Draw Lewis symbols for the following ions. a. O2...Ch. 4 - What is the charge on the monatomic ion formed by...Ch. 4 - What is the charge on the monatomic ion formed by...Ch. 4 - Indicate the number of electrons lost or gained...Ch. 4 - Indicate the number of electrons lost or gained...Ch. 4 - Which noble gas has an electron configuration...Ch. 4 - Prob. 4.42EPCh. 4 - Which noble gas is isoelectronic with each of the...Ch. 4 - Which noble gas is isoelectronic with each of the...Ch. 4 - Prob. 4.45EPCh. 4 - Indicate whether or not each of the following...Ch. 4 - Prob. 4.47EPCh. 4 - Prob. 4.48EPCh. 4 - Prob. 4.49EPCh. 4 - Write the electron configuration of the following....Ch. 4 - How many valence electrons are present in each of...Ch. 4 - Prob. 4.52EPCh. 4 - Using Lewis structures, show how ionic compounds...Ch. 4 - Using Lewis structures, show how ionic compounds...Ch. 4 - The following Lewis symbols for ions have the...Ch. 4 - Prob. 4.56EPCh. 4 - Prob. 4.57EPCh. 4 - Prob. 4.58EPCh. 4 - Prob. 4.59EPCh. 4 - Prob. 4.60EPCh. 4 - The component elements for four binary ionic...Ch. 4 - Prob. 4.62EPCh. 4 - Write the complete chemical formula (symbol and...Ch. 4 - Write the complete chemical formula (symbol and...Ch. 4 - Write the chemical formula for the ionic compound...Ch. 4 - Prob. 4.66EPCh. 4 - Prob. 4.67EPCh. 4 - What is the chemical formula of the ionic compound...Ch. 4 - A representative element (X) forms an ion with a 2...Ch. 4 - A representative element (Z) forms an ion with a...Ch. 4 - Prob. 4.71EPCh. 4 - The following questions pertain to the ionic...Ch. 4 - Prob. 4.73EPCh. 4 - Prob. 4.74EPCh. 4 - Prob. 4.75EPCh. 4 - Prob. 4.76EPCh. 4 - Prob. 4.77EPCh. 4 - Prob. 4.78EPCh. 4 - Prob. 4.79EPCh. 4 - Which of the following binary compounds would be...Ch. 4 - Name the following binary ionic compounds, each of...Ch. 4 - Name the following binary ionic compounds, each of...Ch. 4 - Calculate the charge on the metal ion in the...Ch. 4 - Calculate the charge on the metal ion in the...Ch. 4 - Prob. 4.85EPCh. 4 - Prob. 4.86EPCh. 4 - Prob. 4.87EPCh. 4 - Prob. 4.88EPCh. 4 - Name each of the following binary ionic compounds....Ch. 4 - Name each of the following binary ionic compounds....Ch. 4 - Prob. 4.91EPCh. 4 - Name each compound in the following pairs of...Ch. 4 - Prob. 4.93EPCh. 4 - Write chemical formulas for the following binary...Ch. 4 - Prob. 4.95EPCh. 4 - Write chemical formulas for the following binary...Ch. 4 - Prob. 4.97EPCh. 4 - Prob. 4.98EPCh. 4 - Fill in the blanks in each line of the following...Ch. 4 - Prob. 4.100EPCh. 4 - Prob. 4.101EPCh. 4 - Prob. 4.102EPCh. 4 - Prob. 4.103EPCh. 4 - How many oxygen atoms are present in each of the...Ch. 4 - Prob. 4.105EPCh. 4 - Prob. 4.106EPCh. 4 - Prob. 4.107EPCh. 4 - Prob. 4.108EPCh. 4 - Prob. 4.109EPCh. 4 - Prob. 4.110EPCh. 4 - How many ions are present per formula unit in each...Ch. 4 - Prob. 4.112EPCh. 4 - Name the following compounds, all of which contain...Ch. 4 - Prob. 4.114EPCh. 4 - Prob. 4.115EPCh. 4 - Prob. 4.116EPCh. 4 - Prob. 4.117EPCh. 4 - Write formulas for the following compounds, all of...Ch. 4 - Write chemical formulas for the following...Ch. 4 - Write chemical formulas for the following...Ch. 4 - Prob. 4.121EPCh. 4 - Prob. 4.122EPCh. 4 - Prob. 4.123EPCh. 4 - Prob. 4.124EP
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