General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
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Question
Chapter 4.9, Problem 6QQ
Interpretation Introduction
Interpretation:
Among the given options, the binary ionic compound that has a name which includes a Roman numeral has to be chosen.
Concept Introduction:
An ionic compound has two elements one is metal and another one is non-metal. The metal ion has always positive charge and the non-metal ion has always negative ion called binary compounds.
Example:
Depending upon the chemical circumstances metal atoms able to form more than one type of ion is called variable charge metal.
Example – Fe forms
If variable charge metal atom is there in ionic compound and the naming can be done by using Roman numerals.
Expert Solution & Answer
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 4 Solutions
General, Organic, and Biological Chemistry
Ch. 4.1 - Prob. 1QQCh. 4.1 - Prob. 2QQCh. 4.1 - Prob. 3QQCh. 4.2 - How many valence electrons are present in an atom...Ch. 4.2 - Prob. 2QQCh. 4.2 - Prob. 3QQCh. 4.2 - Prob. 4QQCh. 4.2 - Which of the following elements would have the...Ch. 4.3 - Prob. 1QQCh. 4.3 - Prob. 2QQ
Ch. 4.3 - Prob. 3QQCh. 4.4 - In terms of subatomic particles, a Ca2+ ion...Ch. 4.4 - Prob. 2QQCh. 4.4 - Prob. 3QQCh. 4.4 - Prob. 4QQCh. 4.5 - An atom with a 1s22s22p4 electron configuration...Ch. 4.5 - Prob. 2QQCh. 4.5 - Prob. 3QQCh. 4.5 - Prob. 4QQCh. 4.5 - Prob. 5QQCh. 4.6 - Prob. 1QQCh. 4.6 - Prob. 2QQCh. 4.6 - Prob. 3QQCh. 4.7 - What is the chemical formula of the ionic compound...Ch. 4.7 - What is the chemical formula of the ionic compound...Ch. 4.7 - Given that Z2 ions are present in the ionic...Ch. 4.7 - Prob. 4QQCh. 4.8 - Prob. 1QQCh. 4.8 - Which of the following is a correct description of...Ch. 4.9 - Prob. 1QQCh. 4.9 - Prob. 2QQCh. 4.9 - Prob. 3QQCh. 4.9 - Prob. 4QQCh. 4.9 - Prob. 5QQCh. 4.9 - Prob. 6QQCh. 4.9 - The correct name for the binary ionic compound...Ch. 4.9 - Prob. 8QQCh. 4.10 - Prob. 1QQCh. 4.10 - Which of the following statements about polyatomic...Ch. 4.10 - The nitrate, sulfate, and phosphate ions have,...Ch. 4.10 - Prob. 4QQCh. 4.11 - Prob. 1QQCh. 4.11 - Prob. 2QQCh. 4.11 - Prob. 3QQCh. 4.11 - Prob. 4QQCh. 4.11 - Prob. 5QQCh. 4.11 - What is the chemical formula for the compound...Ch. 4 - Contrast the two general types of chemical bonds...Ch. 4 - Contrast the two general types of chemical...Ch. 4 - How many valence electrons do atoms with the...Ch. 4 - How many valence electrons do atoms with the...Ch. 4 - Prob. 4.5EPCh. 4 - Prob. 4.6EPCh. 4 - Write the complete electron configuration for each...Ch. 4 - Write the complete electron configuration for each...Ch. 4 - Prob. 4.9EPCh. 4 - For each of the following pairs of representative...Ch. 4 - How many of the highlighted elements in the...Ch. 4 - How many of the highlighted elements in the...Ch. 4 - Draw Lewis symbols for atoms of each of the...Ch. 4 - Draw Lewis symbols for atoms of each of the...Ch. 4 - Each of the following Lewis symbols represents a...Ch. 4 - Each of the following Lewis symbols represents a...Ch. 4 - Prob. 4.17EPCh. 4 - Prob. 4.18EPCh. 4 - What is the chemical property of the noble gases...Ch. 4 - Prob. 4.20EPCh. 4 - Prob. 4.21EPCh. 4 - Prob. 4.22EPCh. 4 - Give the chemical symbol for each of the following...Ch. 4 - Give the chemical symbol for each of the following...Ch. 4 - What would be the chemical symbol for an ion with...Ch. 4 - What would be the chemical symbol for an ion with...Ch. 4 - Fill in the blanks in each line in the following...Ch. 4 - Fill in the blanks in each line in the following...Ch. 4 - Fill in the blanks in each line of the following...Ch. 4 - Fill in the blanks in each line of the following...Ch. 4 - Identify element X by giving its chemical symbol,...Ch. 4 - Prob. 4.32EPCh. 4 - Prob. 4.33EPCh. 4 - Prob. 4.34EPCh. 4 - Prob. 4.35EPCh. 4 - Draw Lewis symbols for the following ions. a. O2...Ch. 4 - What is the charge on the monatomic ion formed by...Ch. 4 - What is the charge on the monatomic ion formed by...Ch. 4 - Indicate the number of electrons lost or gained...Ch. 4 - Indicate the number of electrons lost or gained...Ch. 4 - Which noble gas has an electron configuration...Ch. 4 - Prob. 4.42EPCh. 4 - Which noble gas is isoelectronic with each of the...Ch. 4 - Which noble gas is isoelectronic with each of the...Ch. 4 - Prob. 4.45EPCh. 4 - Indicate whether or not each of the following...Ch. 4 - Prob. 4.47EPCh. 4 - Prob. 4.48EPCh. 4 - Prob. 4.49EPCh. 4 - Write the electron configuration of the following....Ch. 4 - How many valence electrons are present in each of...Ch. 4 - Prob. 4.52EPCh. 4 - Using Lewis structures, show how ionic compounds...Ch. 4 - Using Lewis structures, show how ionic compounds...Ch. 4 - The following Lewis symbols for ions have the...Ch. 4 - Prob. 4.56EPCh. 4 - Prob. 4.57EPCh. 4 - Prob. 4.58EPCh. 4 - Prob. 4.59EPCh. 4 - Prob. 4.60EPCh. 4 - The component elements for four binary ionic...Ch. 4 - Prob. 4.62EPCh. 4 - Write the complete chemical formula (symbol and...Ch. 4 - Write the complete chemical formula (symbol and...Ch. 4 - Write the chemical formula for the ionic compound...Ch. 4 - Prob. 4.66EPCh. 4 - Prob. 4.67EPCh. 4 - What is the chemical formula of the ionic compound...Ch. 4 - A representative element (X) forms an ion with a 2...Ch. 4 - A representative element (Z) forms an ion with a...Ch. 4 - Prob. 4.71EPCh. 4 - The following questions pertain to the ionic...Ch. 4 - Prob. 4.73EPCh. 4 - Prob. 4.74EPCh. 4 - Prob. 4.75EPCh. 4 - Prob. 4.76EPCh. 4 - Prob. 4.77EPCh. 4 - Prob. 4.78EPCh. 4 - Prob. 4.79EPCh. 4 - Which of the following binary compounds would be...Ch. 4 - Name the following binary ionic compounds, each of...Ch. 4 - Name the following binary ionic compounds, each of...Ch. 4 - Calculate the charge on the metal ion in the...Ch. 4 - Calculate the charge on the metal ion in the...Ch. 4 - Prob. 4.85EPCh. 4 - Prob. 4.86EPCh. 4 - Prob. 4.87EPCh. 4 - Prob. 4.88EPCh. 4 - Name each of the following binary ionic compounds....Ch. 4 - Name each of the following binary ionic compounds....Ch. 4 - Prob. 4.91EPCh. 4 - Name each compound in the following pairs of...Ch. 4 - Prob. 4.93EPCh. 4 - Write chemical formulas for the following binary...Ch. 4 - Prob. 4.95EPCh. 4 - Write chemical formulas for the following binary...Ch. 4 - Prob. 4.97EPCh. 4 - Prob. 4.98EPCh. 4 - Fill in the blanks in each line of the following...Ch. 4 - Prob. 4.100EPCh. 4 - Prob. 4.101EPCh. 4 - Prob. 4.102EPCh. 4 - Prob. 4.103EPCh. 4 - How many oxygen atoms are present in each of the...Ch. 4 - Prob. 4.105EPCh. 4 - Prob. 4.106EPCh. 4 - Prob. 4.107EPCh. 4 - Prob. 4.108EPCh. 4 - Prob. 4.109EPCh. 4 - Prob. 4.110EPCh. 4 - How many ions are present per formula unit in each...Ch. 4 - Prob. 4.112EPCh. 4 - Name the following compounds, all of which contain...Ch. 4 - Prob. 4.114EPCh. 4 - Prob. 4.115EPCh. 4 - Prob. 4.116EPCh. 4 - Prob. 4.117EPCh. 4 - Write formulas for the following compounds, all of...Ch. 4 - Write chemical formulas for the following...Ch. 4 - Write chemical formulas for the following...Ch. 4 - Prob. 4.121EPCh. 4 - Prob. 4.122EPCh. 4 - Prob. 4.123EPCh. 4 - Prob. 4.124EP
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