Among the given compounds, dimethyl ketone is functional group isomer of which compound has to be chosen. Concept Introduction: Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism. If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule. Aldehydes and ketones have constitutional isomers. Functional group isomerism exists between aldehyde and ketones. Aldehydes and ketones that have same degree of saturation and same number of carbon atoms are functional group isomers. In aldehyde, skeletal isomerism is possible where the group attached to the carbonyl carbon atom connectivity is changed. In ketones positional isomerism is possible where the carbonyl group is moved within the carbon chain.

Question

(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

Answer 1

Question

Chapter 4.6, Problem 3QQ

Interpretation Introduction

Interpretation:

Among the given compounds, dimethyl ketone is functional group isomer of which compound has to be chosen.

Concept Introduction:

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

Aldehydes and ketones have constitutional isomers. Functional group isomerism exists between aldehyde and ketones. Aldehydes and ketones that have same degree of saturation and same number of carbon atoms are functional group isomers. In aldehyde, skeletal isomerism is possible where the group attached to the carbonyl carbon atom connectivity is changed. In ketones positional isomerism is possible where the carbonyl group is moved within the carbon chain.

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