EBK ORGANIC AND BIOLOGICAL CHEMISTRY
7th Edition
ISBN: 9780100547742
Author: STOKER
Publisher: YUZU
expand_more
expand_more
format_list_bulleted
Question
Chapter 4, Problem 4.116EP
Interpretation Introduction
Interpretation:
The type of compound that is obtained by replacement of the carbonyl carbon atom by a sulfur atom has to be given.
Concept Introduction:
Carbonyl groups are the one which contain a double bond between carbon and oxygen atom.
If either of the carbon atom or the oxygen atom present in the carbonyl group is substituted by sulfur atom means it is known as sulfur-containing carbonyl compounds.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
5. Propose a Synthesis for the molecule below. You may use any starting materials containing 6
carbons or less (reagents that aren't incorporated into the final molecule such as PhзP do not
count towards this total, and the starting material can have whatever non-carbon functional
groups you want), and any of the reactions you have learned so far in organic chemistry I, II, and
III. Your final answer should show each step separately, with intermediates and conditions clearly
drawn.
H3C
CH3
State the name and condensed formula of isooxazole obtained by reacting acetylacetone and hydroxylamine.
State the name and condensed formula of the isothiazole obtained by reacting acetylacetone and thiosemicarbazide.
Chapter 4 Solutions
EBK ORGANIC AND BIOLOGICAL CHEMISTRY
Ch. 4.1 - Prob. 1QQCh. 4.1 - Prob. 2QQCh. 4.2 - Prob. 1QQCh. 4.2 - Prob. 2QQCh. 4.2 - Prob. 3QQCh. 4.3 - Prob. 1QQCh. 4.3 - Prob. 2QQCh. 4.3 - Prob. 3QQCh. 4.4 - Prob. 1QQCh. 4.4 - Prob. 2QQ
Ch. 4.4 - Prob. 3QQCh. 4.4 - Prob. 4QQCh. 4.4 - Prob. 5QQCh. 4.5 - Prob. 1QQCh. 4.5 - Prob. 2QQCh. 4.5 - Prob. 3QQCh. 4.5 - Prob. 4QQCh. 4.5 - Prob. 5QQCh. 4.6 - Prob. 1QQCh. 4.6 - Prob. 2QQCh. 4.6 - Prob. 3QQCh. 4.7 - Prob. 1QQCh. 4.7 - Prob. 2QQCh. 4.8 - Prob. 1QQCh. 4.8 - Prob. 2QQCh. 4.9 - Prob. 1QQCh. 4.9 - Prob. 2QQCh. 4.10 - Prob. 1QQCh. 4.10 - Prob. 2QQCh. 4.10 - Prob. 3QQCh. 4.10 - Prob. 4QQCh. 4.11 - Prob. 1QQCh. 4.11 - Prob. 2QQCh. 4.11 - Prob. 3QQCh. 4.11 - Prob. 4QQCh. 4.11 - Prob. 5QQCh. 4.12 - Prob. 1QQCh. 4.12 - Prob. 2QQCh. 4 - Prob. 4.1EPCh. 4 - Prob. 4.2EPCh. 4 - Prob. 4.3EPCh. 4 - In terms of polarity, which carbonyl group atom...Ch. 4 - Prob. 4.5EPCh. 4 - Prob. 4.6EPCh. 4 - Prob. 4.7EPCh. 4 - Prob. 4.8EPCh. 4 - Prob. 4.9EPCh. 4 - Prob. 4.10EPCh. 4 - Prob. 4.11EPCh. 4 - Classify each of the following structures as an...Ch. 4 - Prob. 4.13EPCh. 4 - Prob. 4.14EPCh. 4 - Prob. 4.15EPCh. 4 - Prob. 4.16EPCh. 4 - Prob. 4.17EPCh. 4 - Prob. 4.18EPCh. 4 - Prob. 4.19EPCh. 4 - Prob. 4.20EPCh. 4 - Prob. 4.21EPCh. 4 - Prob. 4.22EPCh. 4 - Prob. 4.23EPCh. 4 - Prob. 4.24EPCh. 4 - Prob. 4.25EPCh. 4 - Prob. 4.26EPCh. 4 - Prob. 4.27EPCh. 4 - Prob. 4.28EPCh. 4 - Name the functional group(s) present in each of...Ch. 4 - Prob. 4.30EPCh. 4 - Prob. 4.31EPCh. 4 - Prob. 4.32EPCh. 4 - Prob. 4.33EPCh. 4 - Prob. 4.34EPCh. 4 - Prob. 4.35EPCh. 4 - Prob. 4.36EPCh. 4 - Draw a structural formula for each of the...Ch. 4 - Prob. 4.38EPCh. 4 - Prob. 4.39EPCh. 4 - Prob. 4.40EPCh. 4 - Draw a structural formula for each of the...Ch. 4 - Prob. 4.42EPCh. 4 - Prob. 4.43EPCh. 4 - Name the functional group(s) present in each of...Ch. 4 - Prob. 4.45EPCh. 4 - Prob. 4.46EPCh. 4 - Prob. 4.47EPCh. 4 - Prob. 4.48EPCh. 4 - Prob. 4.49EPCh. 4 - Give IUPAC names for all saturated...Ch. 4 - Prob. 4.51EPCh. 4 - Prob. 4.52EPCh. 4 - Prob. 4.53EPCh. 4 - Prob. 4.54EPCh. 4 - Prob. 4.55EPCh. 4 - Prob. 4.56EPCh. 4 - Prob. 4.57EPCh. 4 - Prob. 4.58EPCh. 4 - Prob. 4.59EPCh. 4 - Prob. 4.60EPCh. 4 - Prob. 4.61EPCh. 4 - Prob. 4.62EPCh. 4 - Prob. 4.63EPCh. 4 - Prob. 4.64EPCh. 4 - Which member in each of the following pairs of...Ch. 4 - Prob. 4.66EPCh. 4 - Which member in each of the following pairs of...Ch. 4 - Prob. 4.68EPCh. 4 - Prob. 4.69EPCh. 4 - How many hydrogen bonds can form between an...Ch. 4 - Prob. 4.71EPCh. 4 - Prob. 4.72EPCh. 4 - Draw the structure of the alcohol needed to...Ch. 4 - Prob. 4.74EPCh. 4 - Prob. 4.75EPCh. 4 - Prob. 4.76EPCh. 4 - Prob. 4.77EPCh. 4 - Prob. 4.78EPCh. 4 - Prob. 4.79EPCh. 4 - Prob. 4.80EPCh. 4 - Prob. 4.81EPCh. 4 - Which of the following compounds would react with...Ch. 4 - Prob. 4.83EPCh. 4 - Prob. 4.84EPCh. 4 - Which of the three compounds pentanal,...Ch. 4 - Prob. 4.86EPCh. 4 - Prob. 4.87EPCh. 4 - Prob. 4.88EPCh. 4 - Prob. 4.89EPCh. 4 - Prob. 4.90EPCh. 4 - Prob. 4.91EPCh. 4 - Indicate whether each of the following compounds...Ch. 4 - Which carbon atom is the hemiacetal carbon atom in...Ch. 4 - Which carbon atom is the hemiacetal carbon atom in...Ch. 4 - Prob. 4.95EPCh. 4 - Prob. 4.96EPCh. 4 - Prob. 4.97EPCh. 4 - Prob. 4.98EPCh. 4 - Prob. 4.99EPCh. 4 - Indicate whether each of the following compounds...Ch. 4 - Prob. 4.101EPCh. 4 - Prob. 4.102EPCh. 4 - Prob. 4.103EPCh. 4 - Prob. 4.104EPCh. 4 - Prob. 4.105EPCh. 4 - Prob. 4.106EPCh. 4 - Prob. 4.107EPCh. 4 - Name each of the compounds in Problem 15-106 in...Ch. 4 - Prob. 4.109EPCh. 4 - Prob. 4.110EPCh. 4 - Prob. 4.111EPCh. 4 - Prob. 4.112EPCh. 4 - Prob. 4.113EPCh. 4 - Prob. 4.114EPCh. 4 - Prob. 4.115EPCh. 4 - Prob. 4.116EPCh. 4 - Prob. 4.117EPCh. 4 - Prob. 4.118EP
Knowledge Booster
Similar questions
- Provide the semi-developed formula of isooxazole obtained by reacting acetylacetone and hydroxylamine.arrow_forwardGiven a 1,3-dicarbonyl compound (R1-CO-CH2-CO-R2), indicate the formula of the compound obtaineda) if I add hydroxylamine (NH2OH) to give an isooxazole.b) if I add thiosemicarbazide (NH2-CO-NH-NH2) to give an isothiazole.arrow_forwardAn orange laser has a wavelength of 610 nm. What is the energy of this light?arrow_forward
- The molar absorptivity of a protein in water at 280 nm can be estimated within ~5-10% from its content of the amino acids tyrosine and tryptophan and from the number of disulfide linkages (R-S-S-R) between cysteine residues: Ε280 nm (M-1 cm-1) ≈ 5500 nTrp + 1490 nTyr + 125 nS-S where nTrp is the number of tryptophans, nTyr is the number of tyrosines, and nS-S is the number of disulfide linkages. The protein human serum transferrin has 678 amino acids including 8 tryptophans, 26 tyrosines, and 19 disulfide linkages. The molecular mass of the most dominant for is 79550. Predict the molar absorptivity of transferrin. Predict the absorbance of a solution that’s 1.000 g/L transferrin in a 1.000-cm-pathlength cuvet. Estimate the g/L of a transferrin solution with an absorbance of 1.50 at 280 nm.arrow_forwardIn GC, what order will the following molecules elute from the column? CH3OCH3, CH3CH2OH, C3H8, C4H10arrow_forwardBeer’s Law is A = εbc, where A is absorbance, ε is the molar absorptivity (which is specific to the compound and wavelength in the measurement), and c is concentration. The absorbance of a 2.31 × 10-5 M solution of a compound is 0.822 at a wavelength of 266 nm in a 1.00-cm cell. Calculate the molar absorptivity at 266 nm.arrow_forward
- How to calculate % of unknown solution using line of best fit y=0.1227x + 0.0292 (y=2.244)arrow_forwardGiven a 1,3-dicarbonyl compound, state the (condensed) formula of the compound obtaineda) if I add hydroxylamine (NH2OH) to give an isooxazole.b) if I add thiosemicarbazide (NH2-CO-NH-NH2) to give an isothiazole.arrow_forwardComplete the following acid-base reactions and predict the direction of equilibrium for each. Justify your prediction by citing pK values for the acid and conjugate acid in each equilibrium. (a) (b) NHs (c) O₂N NH NH OH H₁PO₁arrow_forward
- 23.34 Show how to convert each starting material into isobutylamine in good yield. ཅ ནད ཀྱི (b) Br OEt (c) (d) (e) (f) Harrow_forwardPlease help me Please use https://app.molview.com/ to draw this. I tried, but I couldn't figure out how to do it.arrow_forwardPropose a synthesis of 1-butanamine from the following: (a) a chloroalkane of three carbons (b) a chloroalkane of four carbonsarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,
General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
World of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage Learning
Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
World of Chemistry, 3rd edition
Chemistry
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Brooks / Cole / Cengage Learning