Introductory Chemistry: A Foundation
8th Edition
ISBN: 9781285199030
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 4, Problem 81QAP
Interpretation Introduction
Interpretation:
The reason why ionic compounds in melted state conducts electricity but not when in solid state should be determined.
Concept Introduction:
A chemical compound which is composed of ions (formed by transfer of electrons) which are held together by electrostatic force of attraction is said to be an ionic compound.
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Examine the reaction below. Highlight all bonds that have broken in the reactant.
Br H
H₂C-C-
-H
5
H-C-H
H-C-H
BIE
们
OH
H H
H₂C-C=
H-C-H
H-C-H
Classify each of the following as either a substitution, elimination, or addition reaction.
CH3
CH3
CH2=CH₂
CH2=C-CH2-OH + Br₂
Br-CH2-C
-CH₂-OH
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CH3-C-CH-CH2-CH3
он
° CH₂
HO
C-C-CH3 + NH3
CH₂
он
CH3-CH-O-CH3
O-CH3
CH3-C-CH3 + H₂O
O-CH3
CH3CH₂
H
+ H₂O
CH3-C=C-CH2-CH3
• CHI
Δ
Å CH
CH3
H+
CH3
C-H + HO-CH3
H"
Q-CH₂
CH3-C-CH3 + HO-CH3
OH
O substitution
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substitution
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elimination
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Search 5:45 PM Sun Dec 15
Quiz 9
...
ล 25%0
A
Done
Quiz #9 =
Name:
Draw the major products of the following. Show Stereochemistry when applicable:
1. OsO4
A
2. NaHSO 3, H 20
Cl₂
➤ C
H2, Pd/C
E
HBr
1. Hg(OAc) 2, H₂O
2. NaBH 4
Ꭰ
KI, H3PO4
F
KMnO4, H3O+
KMnO4, H2O
G
H
HBr
Br2
J
CH2N2
➤
K
CH2I2, Zn(Cu)
Cl2, CH3OH
C
1. 03
2. Zn, H3O+
HCI
1. BH 3
N
M
2. NaOH, H 202
KMnO4, NaOH
H₂O
P
Br2, H2O
R
1. BH 3
2. NaOH, H 202
Cl2, CH3CH2OH T
Chapter 4 Solutions
Introductory Chemistry: A Foundation
Ch. 4.4 - Exercise 4.1 Write the formula for each of the...Ch. 4.5 - The average diameter of an atom ¡s1.31010 m. What...Ch. 4.5 - You have learned about three different models of...Ch. 4.7 - Exercise 4.2 Give the number of protons, neutrons,...Ch. 4.7 - Exercise 4.3 Give the number of protons, neutrons,...Ch. 4.7 - Exercise 4.4 Give the symbol for the phosphorus...Ch. 4.8 - Exercise 4.5 Give the symbol and atomic number for...Ch. 4.11 - Thomson and Rutherford helped to show that atoms...Ch. 4.11 - Prob. 4.6SCCh. 4 - Knowing the number of protons in the atom of a...
Ch. 4 - The average mass of a carbon atom is 12.011....Ch. 4 - Prob. 3ALQCh. 4 - Prob. 4ALQCh. 4 - The vitamin niacin (nicotinic acid,C6H5NO2 ) can...Ch. 4 - One of the best indications of a useful theory is...Ch. 4 - Prob. 7ALQCh. 4 - How does Dalton’s atomic theory account for the...Ch. 4 - Prob. 9ALQCh. 4 - These questions concern the work of J. J. Thomson:...Ch. 4 - Heat is applied to an ice cube until only steam is...Ch. 4 - What makes a carbon atom different from a nitrogen...Ch. 4 - Hundreds of years ago, alchemists tried to turn...Ch. 4 - Chlorine has two prominent isotopes,37Cl and35Cl ....Ch. 4 - Prob. 15ALQCh. 4 - Prob. 16ALQCh. 4 - Rutherford was surprised when some of theparticles...Ch. 4 - It is good practice to actively read the textbook...Ch. 4 - Why is the term “sodium chloride molecule”...Ch. 4 - Both atomic elements and molecular elements exist....Ch. 4 - Now that you have gone through Chapter 4, go back...Ch. 4 - Write the formula for each of the following...Ch. 4 - Prob. 23ALQCh. 4 - What were the four fundamental substances...Ch. 4 - Prob. 2QAPCh. 4 - Prob. 3QAPCh. 4 - Prob. 4QAPCh. 4 - What are the live most abundant elements (by mass)...Ch. 4 - Read the “Chemistry in Focus” segment Trace...Ch. 4 - Prob. 7QAPCh. 4 - The symbols for most elements are based on the...Ch. 4 - Find the symbol in Column 2 for each name in...Ch. 4 - Prob. 10QAPCh. 4 - Use the periodic table shown in Fig. 4.9 to find...Ch. 4 - Prob. 12QAPCh. 4 - Prob. 13QAPCh. 4 - Prob. 14QAPCh. 4 - A given compound always contains the same...Ch. 4 - Correct each of the following misstatements from...Ch. 4 - Prob. 17QAPCh. 4 - A given compound always contains the same relative...Ch. 4 - Based on the following word descriptions, write...Ch. 4 - Based on the following word descriptions, write...Ch. 4 - Scientists J. J. Thomson and William Thomson (Lord...Ch. 4 - True or false? Rutherford’s bombardment...Ch. 4 - Where are neutrons found in an atom? Are neutrons...Ch. 4 - What are the positively charged particles found in...Ch. 4 - Do the proton and the neutron have exactly the...Ch. 4 - The proton and the (electron/neutron) have almost...Ch. 4 - An average atomic nucleus has a diameter of about...Ch. 4 - Prob. 28QAPCh. 4 - Prob. 29QAPCh. 4 - True or false? The mass number of a nucleus...Ch. 4 - For an isolated atom, why do we expect the number...Ch. 4 - Why do we not necessarily expect the number of...Ch. 4 - Dalton’s original atomic theory proposed that all...Ch. 4 - Prob. 34QAPCh. 4 - For each of the following elements, use the...Ch. 4 - Prob. 36QAPCh. 4 - Write the atomic symbol(ZAX) for each of the...Ch. 4 - Write the atomic symbol(ZAX) for each of the...Ch. 4 - How many protons and neutrons are contained in the...Ch. 4 - Read the Chemistry in Focus” segment “Whair”Do You...Ch. 4 - Read the “Chemistry in Focus” segmentIsotope...Ch. 4 - Complete the following table. Name Symbol Atomic...Ch. 4 - True or false? The elements are arranged in the...Ch. 4 - Prob. 44QAPCh. 4 - List the characteristic physical properties that...Ch. 4 - Where are the metallic elements found on the...Ch. 4 - Prob. 47QAPCh. 4 - List five nonmetallic elements that exist as...Ch. 4 - Under ordinary conditions, only a few pure...Ch. 4 - The elements that lie close to the “stair-step”...Ch. 4 - Prob. 51QAPCh. 4 - Without looking at your textbook or the periodic...Ch. 4 - Prob. 53QAPCh. 4 - Prob. 54QAPCh. 4 - Most substances are composed of _________ rather...Ch. 4 - Prob. 56QAPCh. 4 - Prob. 57QAPCh. 4 - Prob. 58QAPCh. 4 - Molecules of nitrogen gas and oxygen gas are said...Ch. 4 - Give three examples of gaseous elements that exist...Ch. 4 - Prob. 61QAPCh. 4 - If sodium chloride (table salt) is melted and then...Ch. 4 - Prob. 63QAPCh. 4 - The two most common elemental forms of carbon are...Ch. 4 - An isolated atom has a net charge of ________ .Ch. 4 - Prob. 66QAPCh. 4 - A simple ion with a 3+ charge (for example, A13+)...Ch. 4 - An ion that has two more electrons outside the...Ch. 4 - Prob. 69QAPCh. 4 - Prob. 70QAPCh. 4 - Prob. 71QAPCh. 4 - True or false?N3 andP3 contain a different number...Ch. 4 - How many electrons are present in each of the...Ch. 4 - Prob. 74QAPCh. 4 - For the following processes that show the...Ch. 4 - For the following ions, indicate whether electrons...Ch. 4 - For each of the following atomic numbers, use the...Ch. 4 - On the basis of the element’s location in the...Ch. 4 - List some properties of a substance that would...Ch. 4 - Prob. 80QAPCh. 4 - Prob. 81QAPCh. 4 - Prob. 82QAPCh. 4 - For each of the following positive ions, use the...Ch. 4 - For each of the following negative ions, use the...Ch. 4 - Prob. 85APCh. 4 - Prob. 86APCh. 4 - Prob. 87APCh. 4 - Which of the following is/are true regarding the...Ch. 4 - Prob. 89APCh. 4 - Which subatomic particles contribute most to the...Ch. 4 - Is it possible for the same Iwo elements to form...Ch. 4 - Carbohydrates, a class of compounds containing the...Ch. 4 - Prob. 93APCh. 4 - How many protons and neutrons are contained in the...Ch. 4 - Though the common isotope of aluminum has a mass...Ch. 4 - Prob. 96APCh. 4 - Prob. 97APCh. 4 - What is the symbol for an ion with a 1 — charge....Ch. 4 - Prob. 99APCh. 4 - Prob. 100APCh. 4 - Prob. 101APCh. 4 - A metal ion with a 2+ charge contains 34 neutrons...Ch. 4 - Prob. 103APCh. 4 - Write the simplest formula for each of the...Ch. 4 - Prob. 105APCh. 4 - Write the atomic symbol(ZAX) for each of the...Ch. 4 - How many protons and neutrons are contained in the...Ch. 4 - Prob. 108APCh. 4 - Prob. 109APCh. 4 - Prob. 110APCh. 4 - Prob. 111CPCh. 4 - Prob. 112CPCh. 4 - Complete the following table. 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- Select the stronger base: H-CEN equally basic H H H H-C-N H Select the stronger acid: Select the stronger base: Select the stronger base: H -H equally acidic о equally basic NH equally basic оarrow_forwardClassify each of the following as either a substitution, elimination, or addition reaction. CH3 CH3 CH3-CH-CH2-C-CH3 + Br₂ CH3 CH3 CH3 CH3-C-CH2-C-CH3 + HBr substitution ○ elimination Br CH3 CHI CHO CHA HO CH он Cl CH3-CH2-CH-CH2-CH3 CH₂ DBU H* - CHI CHO CH3 + H2O Ӧ CH3 CH3-CH2-CH=CH-CH3 + HCI OH Pd/C CH3 CH3-CH-CH2-C-CH3 CH3 H C-CH2-CH3 + HO-CH3 addition substitution elimination ○ addition ○ substitution ○ elimination O addition substitution O elimination addition substitution O elimination addition CH3 C-CH3 + H2 CH3 CH3-O-CH-CH2-CH3 Онarrow_forward=> (8 pts) Use retrosynthetic analysis (that is, use retrosynthetic arrows as was done in class) to suggest a synthesis route for the transformation shown below. Sear bonsarrow_forward
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