Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
8th Edition
ISBN: 9780134421377
Author: Charles H Corwin
Publisher: PEARSON
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Chapter 4, Problem 3E
Interpretation Introduction
Interpretation:
The name of three scientists whose work was used by Dalton to support the atomic theory is to be stated.
Concept introduction:
Every material present in this universe has mass, even air, which seems to be invisible has mass. The mass of the material depends upon the number of small particles present in it. This shows that matter is made up of a number of small particles.
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 4 Solutions
Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
Ch. 4 - Prob. 1CECh. 4 - Prob. 2CECh. 4 - Prob. 3CECh. 4 - Prob. 4CECh. 4 - Prob. 5CECh. 4 - Prob. 6CECh. 4 - Prob. 7CECh. 4 - Prob. 8CECh. 4 - Prob. 9CECh. 4 - Prob. 10CE
Ch. 4 - Prob. 11CECh. 4 - Prob. 12CECh. 4 - Prob. 1KTCh. 4 - Prob. 2KTCh. 4 - Prob. 3KTCh. 4 - Prob. 4KTCh. 4 - Prob. 5KTCh. 4 - Prob. 6KTCh. 4 - Prob. 7KTCh. 4 - Prob. 8KTCh. 4 - Prob. 9KTCh. 4 - Prob. 10KTCh. 4 - Prob. 11KTCh. 4 - Prob. 12KTCh. 4 - Prob. 13KTCh. 4 - Prob. 14KTCh. 4 - Prob. 15KTCh. 4 - Prob. 16KTCh. 4 - Prob. 17KTCh. 4 - Prob. 18KTCh. 4 - Prob. 19KTCh. 4 - Prob. 20KTCh. 4 - Prob. 21KTCh. 4 - Prob. 22KTCh. 4 - Prob. 23KTCh. 4 - Prob. 24KTCh. 4 - Prob. 25KTCh. 4 - Prob. 1ECh. 4 - Prob. 2ECh. 4 - Prob. 3ECh. 4 - Prob. 4ECh. 4 - Prob. 5ECh. 4 - Prob. 6ECh. 4 - Prob. 7ECh. 4 - Prob. 8ECh. 4 - Prob. 9ECh. 4 - Prob. 10ECh. 4 - Prob. 11ECh. 4 - Prob. 12ECh. 4 - Prob. 13ECh. 4 - Prob. 14ECh. 4 - Prob. 15ECh. 4 - Prob. 16ECh. 4 - Prob. 17ECh. 4 - Prob. 18ECh. 4 - Prob. 19ECh. 4 - Prob. 20ECh. 4 - Prob. 21ECh. 4 - Prob. 22ECh. 4 - Prob. 23ECh. 4 - Prob. 24ECh. 4 - Prob. 25ECh. 4 - Prob. 26ECh. 4 - Prob. 27ECh. 4 - Prob. 28ECh. 4 - Prob. 29ECh. 4 - Prob. 30ECh. 4 - Prob. 31ECh. 4 - Prob. 32ECh. 4 - Prob. 33ECh. 4 - Prob. 34ECh. 4 - Prob. 35ECh. 4 - Prob. 36ECh. 4 - Prob. 37ECh. 4 - Prob. 38ECh. 4 - Prob. 39ECh. 4 - Prob. 40ECh. 4 - Prob. 41ECh. 4 - Prob. 42ECh. 4 - Prob. 43ECh. 4 - Prob. 44ECh. 4 - Prob. 45ECh. 4 - Prob. 46ECh. 4 - Prob. 47ECh. 4 - Prob. 48ECh. 4 - Prob. 49ECh. 4 - Prob. 50ECh. 4 - Prob. 51ECh. 4 - Prob. 52ECh. 4 - Prob. 53ECh. 4 - Prob. 54ECh. 4 - Prob. 55ECh. 4 - Prob. 56ECh. 4 - Prob. 57ECh. 4 - Prob. 58ECh. 4 - Prob. 59ECh. 4 - Prob. 60ECh. 4 - Prob. 61ECh. 4 - Prob. 62ECh. 4 - Prob. 63ECh. 4 - Prob. 64ECh. 4 - Prob. 65ECh. 4 - Prob. 66ECh. 4 - Prob. 67ECh. 4 - Prob. 68ECh. 4 - Prob. 69ECh. 4 - Prob. 70ECh. 4 - Prob. 71ECh. 4 - Prob. 72ECh. 4 - Prob. 73ECh. 4 - Prob. 74ECh. 4 - Prob. 75ECh. 4 - Prob. 76ECh. 4 - Prob. 77ECh. 4 - Prob. 78ECh. 4 - Prob. 79ECh. 4 - Prob. 80ECh. 4 - Prob. 81ECh. 4 - Prob. 82ECh. 4 - Prob. 83ECh. 4 - Prob. 84ECh. 4 - Prob. 85ECh. 4 - Prob. 86ECh. 4 - Prob. 87ECh. 4 - Prob. 88ECh. 4 - Prob. 89ECh. 4 - Prob. 90ECh. 4 - Prob. 91ECh. 4 - Prob. 92ECh. 4 - Prob. 93ECh. 4 - Prob. 94ECh. 4 - Prob. 95ECh. 4 - Prob. 96ECh. 4 - Prob. 97ECh. 4 - Prob. 98ECh. 4 - Prob. 1STCh. 4 - Prob. 2STCh. 4 - Prob. 3STCh. 4 - Prob. 4STCh. 4 - Prob. 5STCh. 4 - Prob. 6STCh. 4 - Prob. 7STCh. 4 - Prob. 8STCh. 4 - Prob. 9STCh. 4 - Prob. 10STCh. 4 - Prob. 11STCh. 4 - Prob. 12STCh. 4 - Prob. 13STCh. 4 - Prob. 14STCh. 4 - Prob. 15STCh. 4 - Prob. 16STCh. 4 - Prob. 17STCh. 4 - Prob. 18ST
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