Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 23, Problem 93GQ
(a)
Interpretation Introduction
Interpretation:
The structure and systematic name has to be given for the product and the obtained product is chiral or not has to be determined.
Concept Introduction:
An
Chiral:
The carbon atom which attached to the four different atoms is called as chiral. A molecule is non superimposable on its mirror image is called chiral molecule.
The molecule is called as chiral molecule, the carbon is called as chiral carbon.
Chiral molecule
(b)
Interpretation Introduction
Interpretation:
Isomer of the reaction product has to be drawn.
Concept Introduction:
Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.
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14:40 A
Candidate Identification
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13. The compound 1-bromo-hex-2-ene
reacts with methanol to form two
products. About this reaction, mark the
correct statement:
OCH3
CH3OH
Br
OCH3 +
+ HBr
A
B
A) The two products formed will have
the same percentage of formation.
B) Product B will be formed by SN1
substitution reaction with the formation
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C) Product A will be formed by SN1
substitution reaction with the formation
of a more stable carbocation than
product B.
D) Product A will be formed by an SN2
substitution reaction occurring in two
stages, the first with slow kinetics and
the second with fast kinetics.
E) The two compounds were obtained
by addition reaction, with compound B
having the highest percentage of
formation.
57
--
☑
14:30 A
Candidate Identification
docs.google.com
10. Amoxicillin (figure X) is one of the
most widely used antibiotics in the
penicillin family. The discovery and
synthesis of these antibiotics in the 20th
century made the treatment of infections
that were previously fatal routine.
About amoxicillin, mark the correct one:
HO
NH2 H
S
-N.
HO
Figura X. Amoxicilina
A) It has the organic functions amide,
ester, phenol and amine.
B) It has four chiral carbons and 8
stereoisomers.
C) The substitution of the aromatic ring
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D) If amoxicillin reacts with an alcohol it
can form an ester.
E) The structure has two tertiary
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62
The environmental police of a Brazilian state received a report of contamination of a river by inorganic arsenic, due to the excessive use of pesticides on a plantation on the riverbanks. Arsenic (As) is extremely toxic in its many forms and oxidation states. In nature, especially in groundwater, it is found in the form of arsenate (AsO ₄ ³ ⁻ ), which can be electrochemically reduced to As ⁰ and collected at the cathode of a coulometric cell. In this case, Potentiostatic Coulometry (at 25°C) was performed in an alkaline medium (pH = 7.5 throughout the analysis) to quantify the species. What potential (E) should have been selected/applied to perform the analysis, considering that this is an exhaustive electrolysis technique (until 99.99% of all AsO ₄ ³ ⁻ has been reduced to As ⁰ at the electrode, or n( final) = 0.01% n( initial )) and that the concentration of AsO ₄ ³ ⁻ found in the initial sample was 0.15 mmol/L ?
Data:
AsO ₄ 3 ⁻ (aq) + 2 H ₂ O ( l ) + 2 e ⁻ → A s O ₂ ⁻ ( a…
Chapter 23 Solutions
Chemistry & Chemical Reactivity
Ch. 23.2 - (a) Draw the nine isomers having the formula...Ch. 23.2 - Prob. 23.2CYUCh. 23.2 - There are 17 possible alkene isomers with the...Ch. 23.2 - Prob. 23.4CYUCh. 23.2 - Aniline, C6H5NH2, is the common name for...Ch. 23.3 - Draw the structure of 1-butanol and alcohols that...Ch. 23.4 - (a) Name each of the following compounds and its...Ch. 23.5 - Kevlar is a well-known polymer that is now used to...Ch. 23.5 - Prob. 1.1ACPCh. 23.5 - Prob. 1.2ACP
Ch. 23.5 - Prob. 1.3ACPCh. 23.5 - Prob. 2.1ACPCh. 23.5 - Prob. 2.2ACPCh. 23.5 - Prob. 2.3ACPCh. 23.5 - What is the atom economy for the reaction of...Ch. 23.5 - Prob. 3.2ACPCh. 23.5 - If drinking from a polycarbonate bottle, does a 15...Ch. 23.5 - Assume you weigh 156 lb. How much BPA do you...Ch. 23.5 - Prob. 3.5ACPCh. 23 - Prob. 1PSCh. 23 - Prob. 2PSCh. 23 - Is violet light (with a wavelength of 400 nm)...Ch. 23 - Prob. 4PSCh. 23 - Prob. 5PSCh. 23 - Prob. 6PSCh. 23 - Prob. 7PSCh. 23 - Prob. 8PSCh. 23 - Prob. 9PSCh. 23 - What is the molecular formula for an alkane with...Ch. 23 - Prob. 11PSCh. 23 - Prob. 12PSCh. 23 - One of the structural isomers with the formula...Ch. 23 - Prob. 14PSCh. 23 - Prob. 15PSCh. 23 - Give the systematic name for the following alkane....Ch. 23 - Draw the structure of each of the following...Ch. 23 - Draw structures for the following compounds. (a)...Ch. 23 - Prob. 19PSCh. 23 - Prob. 20PSCh. 23 - Draw the structure of the chair form of...Ch. 23 - Prob. 22PSCh. 23 - Prob. 23PSCh. 23 - Prob. 24PSCh. 23 - Prob. 25PSCh. 23 - Prob. 26PSCh. 23 - Prob. 27PSCh. 23 - What structural requirement is necessary for an...Ch. 23 - A hydrocarbon with the formula C5H10, can be...Ch. 23 - Prob. 30PSCh. 23 - Prob. 31PSCh. 23 - Prob. 32PSCh. 23 - The compound 2-bromobutane is a product of...Ch. 23 - The compound 2,3-dibromo-2-methylhexane is formed...Ch. 23 - Prob. 35PSCh. 23 - Prob. 36PSCh. 23 - Prob. 37PSCh. 23 - Prob. 38PSCh. 23 - Prob. 39PSCh. 23 - Give the systematic name for each of the following...Ch. 23 - Prob. 41PSCh. 23 - Write an equation for the preparation of...Ch. 23 - Prob. 43PSCh. 23 - Prob. 44PSCh. 23 - Prob. 45PSCh. 23 - Prob. 46PSCh. 23 - Prob. 47PSCh. 23 - Name the following amines: (a) CH3CH2CH2NH2 (b)...Ch. 23 - Draw structural formulas for the four possible...Ch. 23 - Prob. 50PSCh. 23 - Prob. 51PSCh. 23 - Prob. 52PSCh. 23 - Prob. 53PSCh. 23 - Prob. 54PSCh. 23 - Prob. 55PSCh. 23 - Prob. 56PSCh. 23 - Prob. 57PSCh. 23 - Prob. 58PSCh. 23 - Give the structural formula and systematic name...Ch. 23 - Prob. 60PSCh. 23 - Prob. 61PSCh. 23 - Prob. 62PSCh. 23 - Prob. 63PSCh. 23 - Prob. 64PSCh. 23 - Prob. 65PSCh. 23 - Prob. 66PSCh. 23 - Prob. 67PSCh. 23 - Prob. 68PSCh. 23 - Identify the functional groups in the following...Ch. 23 - Prob. 70PSCh. 23 - Prob. 71PSCh. 23 - Prob. 72PSCh. 23 - Prob. 73PSCh. 23 - Prob. 74PSCh. 23 - Prob. 75GQCh. 23 - Prob. 76GQCh. 23 - Prob. 77GQCh. 23 - Prob. 78GQCh. 23 - Prob. 79GQCh. 23 - Prob. 80GQCh. 23 - Prob. 81GQCh. 23 - Write equations for the following reactions,...Ch. 23 - Prob. 83GQCh. 23 - Prob. 84GQCh. 23 - Draw the structure of each of the following...Ch. 23 - Prob. 86GQCh. 23 - Prob. 87GQCh. 23 - Draw structural formulas for possible isomers with...Ch. 23 - Prob. 89GQCh. 23 - Prob. 90GQCh. 23 - Prob. 91GQCh. 23 - Prob. 92GQCh. 23 - Prob. 93GQCh. 23 - Prob. 94GQCh. 23 - Draw the structure of glyceryl trilaurate, a fat....Ch. 23 - Prob. 96GQCh. 23 - Prob. 97GQCh. 23 - Prob. 98GQCh. 23 - Prob. 99GQCh. 23 - There are three ethers with the formula C4H10O....Ch. 23 - Review the opening photograph about chocolate...Ch. 23 - Prob. 102GQCh. 23 - Prob. 103ILCh. 23 - Prob. 104ILCh. 23 - Prob. 105ILCh. 23 - Prob. 106ILCh. 23 - Prob. 107ILCh. 23 - Prob. 108ILCh. 23 - Prob. 109ILCh. 23 - Prob. 110ILCh. 23 - Prob. 111ILCh. 23 - Prob. 112ILCh. 23 - Prob. 113ILCh. 23 - Prob. 114ILCh. 23 - Prob. 115SCQCh. 23 - Prob. 116SCQCh. 23 - Prob. 117SCQCh. 23 - Prob. 118SCQCh. 23 - Prob. 119SCQCh. 23 - Prob. 120SCQCh. 23 - Prob. 121SCQ
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