Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Question
Chapter 23, Problem 110IL
Interpretation Introduction
Interpretation: The ester having molecular formula
Concept introduction:
Ester: One
Ester Hydrolysis: Ester hydrolysis can be caused by acid and base.
Acid-catalyzed hydrolysis: In presence of strong acid such as
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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
with full details solution please
Chapter 23 Solutions
Chemistry & Chemical Reactivity
Ch. 23.2 - (a) Draw the nine isomers having the formula...Ch. 23.2 - Prob. 23.2CYUCh. 23.2 - There are 17 possible alkene isomers with the...Ch. 23.2 - Prob. 23.4CYUCh. 23.2 - Aniline, C6H5NH2, is the common name for...Ch. 23.3 - Draw the structure of 1-butanol and alcohols that...Ch. 23.4 - (a) Name each of the following compounds and its...Ch. 23.5 - Kevlar is a well-known polymer that is now used to...Ch. 23.5 - Prob. 1.1ACPCh. 23.5 - Prob. 1.2ACP
Ch. 23.5 - Prob. 1.3ACPCh. 23.5 - Prob. 2.1ACPCh. 23.5 - Prob. 2.2ACPCh. 23.5 - Prob. 2.3ACPCh. 23.5 - What is the atom economy for the reaction of...Ch. 23.5 - Prob. 3.2ACPCh. 23.5 - If drinking from a polycarbonate bottle, does a 15...Ch. 23.5 - Assume you weigh 156 lb. How much BPA do you...Ch. 23.5 - Prob. 3.5ACPCh. 23 - Prob. 1PSCh. 23 - Prob. 2PSCh. 23 - Is violet light (with a wavelength of 400 nm)...Ch. 23 - Prob. 4PSCh. 23 - Prob. 5PSCh. 23 - Prob. 6PSCh. 23 - Prob. 7PSCh. 23 - Prob. 8PSCh. 23 - Prob. 9PSCh. 23 - What is the molecular formula for an alkane with...Ch. 23 - Prob. 11PSCh. 23 - Prob. 12PSCh. 23 - One of the structural isomers with the formula...Ch. 23 - Prob. 14PSCh. 23 - Prob. 15PSCh. 23 - Give the systematic name for the following alkane....Ch. 23 - Draw the structure of each of the following...Ch. 23 - Draw structures for the following compounds. (a)...Ch. 23 - Prob. 19PSCh. 23 - Prob. 20PSCh. 23 - Draw the structure of the chair form of...Ch. 23 - Prob. 22PSCh. 23 - Prob. 23PSCh. 23 - Prob. 24PSCh. 23 - Prob. 25PSCh. 23 - Prob. 26PSCh. 23 - Prob. 27PSCh. 23 - What structural requirement is necessary for an...Ch. 23 - A hydrocarbon with the formula C5H10, can be...Ch. 23 - Prob. 30PSCh. 23 - Prob. 31PSCh. 23 - Prob. 32PSCh. 23 - The compound 2-bromobutane is a product of...Ch. 23 - The compound 2,3-dibromo-2-methylhexane is formed...Ch. 23 - Prob. 35PSCh. 23 - Prob. 36PSCh. 23 - Prob. 37PSCh. 23 - Prob. 38PSCh. 23 - Prob. 39PSCh. 23 - Give the systematic name for each of the following...Ch. 23 - Prob. 41PSCh. 23 - Write an equation for the preparation of...Ch. 23 - Prob. 43PSCh. 23 - Prob. 44PSCh. 23 - Prob. 45PSCh. 23 - Prob. 46PSCh. 23 - Prob. 47PSCh. 23 - Name the following amines: (a) CH3CH2CH2NH2 (b)...Ch. 23 - Draw structural formulas for the four possible...Ch. 23 - Prob. 50PSCh. 23 - Prob. 51PSCh. 23 - Prob. 52PSCh. 23 - Prob. 53PSCh. 23 - Prob. 54PSCh. 23 - Prob. 55PSCh. 23 - Prob. 56PSCh. 23 - Prob. 57PSCh. 23 - Prob. 58PSCh. 23 - Give the structural formula and systematic name...Ch. 23 - Prob. 60PSCh. 23 - Prob. 61PSCh. 23 - Prob. 62PSCh. 23 - Prob. 63PSCh. 23 - Prob. 64PSCh. 23 - Prob. 65PSCh. 23 - Prob. 66PSCh. 23 - Prob. 67PSCh. 23 - Prob. 68PSCh. 23 - Identify the functional groups in the following...Ch. 23 - Prob. 70PSCh. 23 - Prob. 71PSCh. 23 - Prob. 72PSCh. 23 - Prob. 73PSCh. 23 - Prob. 74PSCh. 23 - Prob. 75GQCh. 23 - Prob. 76GQCh. 23 - Prob. 77GQCh. 23 - Prob. 78GQCh. 23 - Prob. 79GQCh. 23 - Prob. 80GQCh. 23 - Prob. 81GQCh. 23 - Write equations for the following reactions,...Ch. 23 - Prob. 83GQCh. 23 - Prob. 84GQCh. 23 - Draw the structure of each of the following...Ch. 23 - Prob. 86GQCh. 23 - Prob. 87GQCh. 23 - Draw structural formulas for possible isomers with...Ch. 23 - Prob. 89GQCh. 23 - Prob. 90GQCh. 23 - Prob. 91GQCh. 23 - Prob. 92GQCh. 23 - Prob. 93GQCh. 23 - Prob. 94GQCh. 23 - Draw the structure of glyceryl trilaurate, a fat....Ch. 23 - Prob. 96GQCh. 23 - Prob. 97GQCh. 23 - Prob. 98GQCh. 23 - Prob. 99GQCh. 23 - There are three ethers with the formula C4H10O....Ch. 23 - Review the opening photograph about chocolate...Ch. 23 - Prob. 102GQCh. 23 - Prob. 103ILCh. 23 - Prob. 104ILCh. 23 - Prob. 105ILCh. 23 - Prob. 106ILCh. 23 - Prob. 107ILCh. 23 - Prob. 108ILCh. 23 - Prob. 109ILCh. 23 - Prob. 110ILCh. 23 - Prob. 111ILCh. 23 - Prob. 112ILCh. 23 - Prob. 113ILCh. 23 - Prob. 114ILCh. 23 - Prob. 115SCQCh. 23 - Prob. 116SCQCh. 23 - Prob. 117SCQCh. 23 - Prob. 118SCQCh. 23 - Prob. 119SCQCh. 23 - Prob. 120SCQCh. 23 - Prob. 121SCQ
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