
Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 23, Problem 43PS
Interpretation Introduction
Interpretation: The equation for the nitartion reaction of 1,2-dimethylbenzene should be written. The structures with name of the two organic product formed should be drawn.
Concept introduction:
Nitration reaction: The reaction where a nitro group is introduced to an organic compound which reacts with
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34. Give the expected major product of each of the following reactions.
Conc. HI
a. CH3CH2CH2OH
b. (CH3)2CHCH2CH2OH
Conc. HBr
H
Conc. HI
C.
OH
Conc.HCI
d. (CH3CH2)3COH
42. Which of the following halogenated compounds can be used successfully to prepare a Grignard reagent for
alcohol synthesis by subsequent reaction with an aldehyde or ketone? Which ones cannot and why?
H3C CH3
a.
Br
H OH
b.
Cl
C.
I H
H
d. Cl
e.
H
OCH3
Br
H
For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check
the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions
- just focus on the first stable product you expect to form in solution.
?
Will the first
MgBr
product that forms in this reaction
create a new CC bond?
olo
?
OH
جمله
O Yes
Ⓒ No
MgCl
?
Will the first product that forms in this reaction
create a new CC bond?
Click and drag to start drawing a
structure.
Yes
No
X
☐ :
☐
टे
PH
Chapter 23 Solutions
Chemistry & Chemical Reactivity
Ch. 23.2 - (a) Draw the nine isomers having the formula...Ch. 23.2 - Prob. 23.2CYUCh. 23.2 - There are 17 possible alkene isomers with the...Ch. 23.2 - Prob. 23.4CYUCh. 23.2 - Aniline, C6H5NH2, is the common name for...Ch. 23.3 - Draw the structure of 1-butanol and alcohols that...Ch. 23.4 - (a) Name each of the following compounds and its...Ch. 23.5 - Kevlar is a well-known polymer that is now used to...Ch. 23.5 - Prob. 1.1ACPCh. 23.5 - Prob. 1.2ACP
Ch. 23.5 - Prob. 1.3ACPCh. 23.5 - Prob. 2.1ACPCh. 23.5 - Prob. 2.2ACPCh. 23.5 - Prob. 2.3ACPCh. 23.5 - What is the atom economy for the reaction of...Ch. 23.5 - Prob. 3.2ACPCh. 23.5 - If drinking from a polycarbonate bottle, does a 15...Ch. 23.5 - Assume you weigh 156 lb. How much BPA do you...Ch. 23.5 - Prob. 3.5ACPCh. 23 - Prob. 1PSCh. 23 - Prob. 2PSCh. 23 - Is violet light (with a wavelength of 400 nm)...Ch. 23 - Prob. 4PSCh. 23 - Prob. 5PSCh. 23 - Prob. 6PSCh. 23 - Prob. 7PSCh. 23 - Prob. 8PSCh. 23 - Prob. 9PSCh. 23 - What is the molecular formula for an alkane with...Ch. 23 - Prob. 11PSCh. 23 - Prob. 12PSCh. 23 - One of the structural isomers with the formula...Ch. 23 - Prob. 14PSCh. 23 - Prob. 15PSCh. 23 - Give the systematic name for the following alkane....Ch. 23 - Draw the structure of each of the following...Ch. 23 - Draw structures for the following compounds. (a)...Ch. 23 - Prob. 19PSCh. 23 - Prob. 20PSCh. 23 - Draw the structure of the chair form of...Ch. 23 - Prob. 22PSCh. 23 - Prob. 23PSCh. 23 - Prob. 24PSCh. 23 - Prob. 25PSCh. 23 - Prob. 26PSCh. 23 - Prob. 27PSCh. 23 - What structural requirement is necessary for an...Ch. 23 - A hydrocarbon with the formula C5H10, can be...Ch. 23 - Prob. 30PSCh. 23 - Prob. 31PSCh. 23 - Prob. 32PSCh. 23 - The compound 2-bromobutane is a product of...Ch. 23 - The compound 2,3-dibromo-2-methylhexane is formed...Ch. 23 - Prob. 35PSCh. 23 - Prob. 36PSCh. 23 - Prob. 37PSCh. 23 - Prob. 38PSCh. 23 - Prob. 39PSCh. 23 - Give the systematic name for each of the following...Ch. 23 - Prob. 41PSCh. 23 - Write an equation for the preparation of...Ch. 23 - Prob. 43PSCh. 23 - Prob. 44PSCh. 23 - Prob. 45PSCh. 23 - Prob. 46PSCh. 23 - Prob. 47PSCh. 23 - Name the following amines: (a) CH3CH2CH2NH2 (b)...Ch. 23 - Draw structural formulas for the four possible...Ch. 23 - Prob. 50PSCh. 23 - Prob. 51PSCh. 23 - Prob. 52PSCh. 23 - Prob. 53PSCh. 23 - Prob. 54PSCh. 23 - Prob. 55PSCh. 23 - Prob. 56PSCh. 23 - Prob. 57PSCh. 23 - Prob. 58PSCh. 23 - Give the structural formula and systematic name...Ch. 23 - Prob. 60PSCh. 23 - Prob. 61PSCh. 23 - Prob. 62PSCh. 23 - Prob. 63PSCh. 23 - Prob. 64PSCh. 23 - Prob. 65PSCh. 23 - Prob. 66PSCh. 23 - Prob. 67PSCh. 23 - Prob. 68PSCh. 23 - Identify the functional groups in the following...Ch. 23 - Prob. 70PSCh. 23 - Prob. 71PSCh. 23 - Prob. 72PSCh. 23 - Prob. 73PSCh. 23 - Prob. 74PSCh. 23 - Prob. 75GQCh. 23 - Prob. 76GQCh. 23 - Prob. 77GQCh. 23 - Prob. 78GQCh. 23 - Prob. 79GQCh. 23 - Prob. 80GQCh. 23 - Prob. 81GQCh. 23 - Write equations for the following reactions,...Ch. 23 - Prob. 83GQCh. 23 - Prob. 84GQCh. 23 - Draw the structure of each of the following...Ch. 23 - Prob. 86GQCh. 23 - Prob. 87GQCh. 23 - Draw structural formulas for possible isomers with...Ch. 23 - Prob. 89GQCh. 23 - Prob. 90GQCh. 23 - Prob. 91GQCh. 23 - Prob. 92GQCh. 23 - Prob. 93GQCh. 23 - Prob. 94GQCh. 23 - Draw the structure of glyceryl trilaurate, a fat....Ch. 23 - Prob. 96GQCh. 23 - Prob. 97GQCh. 23 - Prob. 98GQCh. 23 - Prob. 99GQCh. 23 - There are three ethers with the formula C4H10O....Ch. 23 - Review the opening photograph about chocolate...Ch. 23 - Prob. 102GQCh. 23 - Prob. 103ILCh. 23 - Prob. 104ILCh. 23 - Prob. 105ILCh. 23 - Prob. 106ILCh. 23 - Prob. 107ILCh. 23 - Prob. 108ILCh. 23 - Prob. 109ILCh. 23 - Prob. 110ILCh. 23 - Prob. 111ILCh. 23 - Prob. 112ILCh. 23 - Prob. 113ILCh. 23 - Prob. 114ILCh. 23 - Prob. 115SCQCh. 23 - Prob. 116SCQCh. 23 - Prob. 117SCQCh. 23 - Prob. 118SCQCh. 23 - Prob. 119SCQCh. 23 - Prob. 120SCQCh. 23 - Prob. 121SCQ
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- Assign all the carbonsarrow_forward9 7 8 C 9 8 200 190 B 5 A -197.72 9 8 7 15 4 3 0: ང་ 200 190 180 147.52 134.98 170 160 150 140 130 120 110 100 90 90 OH 10 4 3 1 2 -143.04 140. 180 170 160 150 140 130 120 110 100 90 CI 3 5 1 2 141.89 140.07 200 190 180 170 160 150 140 130 120 110 100 ៖- 90 129. 126.25 80 70 60 -60 50 40 10 125.19 -129.21 80 70 3.0 20 20 -8 60 50 10 ppm -20 40 128.31 80 80 70 60 50 40 40 -70.27 3.0 20 10 ppm 00˚0-- 77.17 30 20 20 -45.36 10 ppm -0.00 26.48 22.32 ―30.10 ―-0.00arrow_forwardAssign all the carbonsarrow_forward
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