Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 23, Problem 54PS

(a)

Interpretation Introduction

Interpretation: The name and structure of the alcohols which on oxidation gives following product CH3CH2CH2CHO

Concept introduction:

Alcohols are the hydrocarbons which have OH group attached to one of the carbon atom of the linear chain

Alcohols can be of three types on the basis of degree of carbon atom to which the OH group is attached.

Primary alcohol: The OH group is attached to primary carbon atom.

Secondary alcohol: The OH group is attached to secondary carbon atom

Tertiary alcohol: The OH group is attached to tertiary carbon atom

Chemistry & Chemical Reactivity, Chapter 23, Problem 54PS , additional homework tip  1

If a strong oxidizing agent is used, the oxidation of primary alcohol gives carboxylic acid.

A weaker oxidizing or partial oxidation of primary alcohol gives aldehydes.

While secondary alcohols always give ketones on oxidation.

 (b)

Interpretation Introduction

Interpretation: The name and structure of the alcohols which on oxidation gives following product 2-hexanone

Concept introduction:

Alcohols are the hydrocarbons which have OH group attached to one of the carbon atom of the linear chain

Alcohols can be of three types on the basis of degree of carbon atom to which the OH group is attached.

Primary alcohol: The OH group is attached to primary carbon atom.

Secondary alcohol: The OH group is attached to secondary carbon atom

Tertiary alcohol: The OH group is attached to tertiary carbon atom

Chemistry & Chemical Reactivity, Chapter 23, Problem 54PS , additional homework tip  2

If a strong oxidizing agent is used, the oxidation of primary alcohol gives carboxylic acid.

A weaker oxidizing or partial oxidation of primary alcohol gives aldehydes.

While secondary alcohols always give ketones on oxidation.

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Chapter 23 Solutions

Chemistry & Chemical Reactivity

Ch. 23.5 - Prob. 1.3ACPCh. 23.5 - Prob. 2.1ACPCh. 23.5 - Prob. 2.2ACPCh. 23.5 - Prob. 2.3ACPCh. 23.5 - What is the atom economy for the reaction of...Ch. 23.5 - Prob. 3.2ACPCh. 23.5 - If drinking from a polycarbonate bottle, does a 15...Ch. 23.5 - Assume you weigh 156 lb. How much BPA do you...Ch. 23.5 - Prob. 3.5ACPCh. 23 - Prob. 1PSCh. 23 - Prob. 2PSCh. 23 - Is violet light (with a wavelength of 400 nm)...Ch. 23 - Prob. 4PSCh. 23 - Prob. 5PSCh. 23 - Prob. 6PSCh. 23 - Prob. 7PSCh. 23 - Prob. 8PSCh. 23 - Prob. 9PSCh. 23 - What is the molecular formula for an alkane with...Ch. 23 - Prob. 11PSCh. 23 - Prob. 12PSCh. 23 - One of the structural isomers with the formula...Ch. 23 - Prob. 14PSCh. 23 - Prob. 15PSCh. 23 - Give the systematic name for the following alkane....Ch. 23 - Draw the structure of each of the following...Ch. 23 - Draw structures for the following compounds. (a)...Ch. 23 - Prob. 19PSCh. 23 - Prob. 20PSCh. 23 - Draw the structure of the chair form of...Ch. 23 - Prob. 22PSCh. 23 - Prob. 23PSCh. 23 - Prob. 24PSCh. 23 - Prob. 25PSCh. 23 - Prob. 26PSCh. 23 - Prob. 27PSCh. 23 - What structural requirement is necessary for an...Ch. 23 - A hydrocarbon with the formula C5H10, can be...Ch. 23 - Prob. 30PSCh. 23 - Prob. 31PSCh. 23 - Prob. 32PSCh. 23 - The compound 2-bromobutane is a product of...Ch. 23 - The compound 2,3-dibromo-2-methylhexane is formed...Ch. 23 - Prob. 35PSCh. 23 - Prob. 36PSCh. 23 - Prob. 37PSCh. 23 - Prob. 38PSCh. 23 - Prob. 39PSCh. 23 - Give the systematic name for each of the following...Ch. 23 - Prob. 41PSCh. 23 - Write an equation for the preparation of...Ch. 23 - Prob. 43PSCh. 23 - Prob. 44PSCh. 23 - Prob. 45PSCh. 23 - Prob. 46PSCh. 23 - Prob. 47PSCh. 23 - Name the following amines: (a) CH3CH2CH2NH2 (b)...Ch. 23 - Draw structural formulas for the four possible...Ch. 23 - Prob. 50PSCh. 23 - Prob. 51PSCh. 23 - Prob. 52PSCh. 23 - Prob. 53PSCh. 23 - Prob. 54PSCh. 23 - Prob. 55PSCh. 23 - Prob. 56PSCh. 23 - Prob. 57PSCh. 23 - Prob. 58PSCh. 23 - Give the structural formula and systematic name...Ch. 23 - Prob. 60PSCh. 23 - Prob. 61PSCh. 23 - Prob. 62PSCh. 23 - Prob. 63PSCh. 23 - Prob. 64PSCh. 23 - Prob. 65PSCh. 23 - Prob. 66PSCh. 23 - Prob. 67PSCh. 23 - Prob. 68PSCh. 23 - Identify the functional groups in the following...Ch. 23 - Prob. 70PSCh. 23 - Prob. 71PSCh. 23 - Prob. 72PSCh. 23 - Prob. 73PSCh. 23 - Prob. 74PSCh. 23 - Prob. 75GQCh. 23 - Prob. 76GQCh. 23 - Prob. 77GQCh. 23 - Prob. 78GQCh. 23 - Prob. 79GQCh. 23 - Prob. 80GQCh. 23 - Prob. 81GQCh. 23 - Write equations for the following reactions,...Ch. 23 - Prob. 83GQCh. 23 - Prob. 84GQCh. 23 - Draw the structure of each of the following...Ch. 23 - Prob. 86GQCh. 23 - Prob. 87GQCh. 23 - Draw structural formulas for possible isomers with...Ch. 23 - Prob. 89GQCh. 23 - Prob. 90GQCh. 23 - Prob. 91GQCh. 23 - Prob. 92GQCh. 23 - Prob. 93GQCh. 23 - Prob. 94GQCh. 23 - Draw the structure of glyceryl trilaurate, a fat....Ch. 23 - Prob. 96GQCh. 23 - Prob. 97GQCh. 23 - Prob. 98GQCh. 23 - Prob. 99GQCh. 23 - There are three ethers with the formula C4H10O....Ch. 23 - Review the opening photograph about chocolate...Ch. 23 - Prob. 102GQCh. 23 - Prob. 103ILCh. 23 - Prob. 104ILCh. 23 - Prob. 105ILCh. 23 - Prob. 106ILCh. 23 - Prob. 107ILCh. 23 - Prob. 108ILCh. 23 - Prob. 109ILCh. 23 - Prob. 110ILCh. 23 - Prob. 111ILCh. 23 - Prob. 112ILCh. 23 - Prob. 113ILCh. 23 - Prob. 114ILCh. 23 - Prob. 115SCQCh. 23 - Prob. 116SCQCh. 23 - Prob. 117SCQCh. 23 - Prob. 118SCQCh. 23 - Prob. 119SCQCh. 23 - Prob. 120SCQCh. 23 - Prob. 121SCQ
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