![Organic Chemistry, Binder Ready Version](https://www.bartleby.com/isbn_cover_images/9781118454312/9781118454312_largeCoverImage.gif)
(a)
Interpretation: The structures of 3 and 4 with diastereomeric centers have to be drawn
Concept Introduction:
Sodium cyanoborohydride is a strong reducing agent than sodium borohydride. It reduces the carbonyl group into amine group in a rapid way. So, it is called as reductive amination reactions.
If a carbon is attached with four different groups without any elements of symmetry, then that center has a chirality center. Diastereomers (sometimes called diastereoisomers) are a type of a stereoisomer. Diastereomerism occurs when two or more stereoisomers of a compound have different configurations at one or more stereocenters and are not mirror images of each other. When two diastereoisomers differ from each other at only one stereocenter, they are epimers. Each stereocenter gives rise to two different configurations and thus increases the number of stereoisomers by a factor of two.
To find: Draw the structure of 3 and the reason for its production as a diastereomeric mixture
Do reductive amination in compound 2
(b)
Interpretation: The structures of 3 and 4 with diastereomeric centers have to be drawn
Concept Introduction:
An amide group is formed from an amine compound and the ester group.
If a carbon is attached with four different groups without any elements of symmetry, then that center has a chirality center. Diastereomers (sometimes called diastereoisomers) are a type of a stereoisomer. Diastereomerism occurs when two or more stereoisomers of a compound have different configurations at one or more stereocenters and are not mirror images of each other. When two diastereoisomers differ from each other at only one stereocenter, they are epimers. Each stereocenter gives rise to two different configurations and thus increases the number of stereoisomers by a factor of two.
To find: Draw the structure of 4 and determine the possibility of its production as a diastereomeric mixture
Decide the nature of the
![Check Mark](/static/check-mark.png)
Want to see the full answer?
Check out a sample textbook solution![Blurred answer](/static/blurred-answer.jpg)
Chapter 23 Solutions
Organic Chemistry, Binder Ready Version
- Question 2 show work. don't Compound give Ai generated solution So (J K-1 mol-1) A 26 B 54 C 39 D 49 At 298 K, AG° is 375 kJ for the reaction 1A + 1B → 4C + 2D Calculate AH° for this reaction in kJ.arrow_forward1. Provide a complete IUPAC name for each of the following compounds. a) b) c) OH OH OH a) b) c) 2. Provide a complete IUPAC name for each of the following compounds. a) b) a) OH b) он c) OB >=arrow_forwardc) 3. Provide a common name for each of the following alcohols. a) a) OH b) OH c) HO b) c) 4. Provide a common name for each of the following compounds. b) OH a) 5 a) Y OH c) OHarrow_forward
- Using the critical constants for water (refer to the table in the lecture slides), calculate the second virial coefficient. Assume that the compression factor (Z) is expressed as an expansion series in terms of pressure.arrow_forward+3413 pts /4800 Question 38 of 48 > Write the full electron configuration for a Kion. © Macmillan Learning electron configuration: ↓ Resources Solution Penalized → Al Tutor Write the full electron configuration for an Fion. electron configuration: T G 6 & 7 Y H כ Y 00 8 hp 9 J K no L 144 P 112 | t KC 47°F Clear ins prt sc delete ] backspace erarrow_forwardHow to solve these types of problems step by step? I'm so confused.arrow_forward
- Identify the expected product of the following Claisen rearrangement. || = IV OV 00000 5 ОН Он Он Он Он || III IV Varrow_forwardCan you please color-code and explain how to solve this and any molecular orbital diagram given? I'm so confused; could you provide baby steps regardless of which problem type they gave me?arrow_forwardConsider the following structure. OH Esmolol The synthesis of this compound uses a building block derived from either ethylene oxide or epichlorohydrin. 1) Determine which building block was used: | 2) Draw the structure of the nucleophiles that were used along with this building block in the synthesis of the molecule. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. You do not have to consider stereochemistry. Θε {n [arrow_forward
- < 10:44 5GW 10 Question 7/8 Show Answer Convert 46.0 mm to inches (1 inch = 2.54 cm) 46.0 DAM STARTING AMOUNT 1 cm 1 in 46.0 mm x ☑ 10 mm 10 cm ADD FACTOR DELETE x() X × = 1.81 in = 1 10 Dam ANSWER RESET ១ 2.54 0.0460 mm 10 1000 in 0.001 11.7 m 4.60 18.1 cm 100 1.81 0.394 1 0.1 46.0 0.01 Tap here for additional resourcesarrow_forward< 10:44 Question 6/8 5GW (10 Submit A cake recipe calls for 230.0 mL of buttermilk. How 230.0 many cups is this? DAL STARTING AMOUNT × 1 cups 230.0 mL x = 0.9722 cups 230.0 mL ADD FACTOR DELETE (( ) = 1 cups 230.0 DAE ANSWER RESET ១ 9.722 × 105 0.8706 cups 8.706 × 104 1 L 8.706 × 105 0.9722 quart 10 100 mL 0.001 0.1 6.076 × 103 0.01 9.722 × 104 230.0 0.06076 4 1.0567 1000 6.076 × 104 Tap here for additional resourcesarrow_forward< 10:44 Question 6/8 5GW (10 Submit A cake recipe calls for 230.0 mL of buttermilk. How 230.0 many cups is this? DAL STARTING AMOUNT × 1 cups 230.0 mL x = 0.9722 cups 230.0 mL ADD FACTOR DELETE (( ) = 1 cups 230.0 DAE ANSWER RESET ១ 9.722 × 105 0.8706 cups 8.706 × 104 1 L 8.706 × 105 0.9722 quart 10 100 mL 0.001 0.1 6.076 × 103 0.01 9.722 × 104 230.0 0.06076 4 1.0567 1000 6.076 × 104 Tap here for additional resourcesarrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9780078021558/9780078021558_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305079373/9781305079373_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781118431221/9781118431221_smallCoverImage.gif)